Structure of 2,3,5,6-Tetraiodo-1,4-Benzenedicarboxylic Acid and Features of the Thermolysis of Iodinated Terephthalic Acids
The crystal structure of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid dihydrate is described and the following structural features are established by XRD: C 8 H 6 I 4 O 6 , M 705.73; monoclinic crystal system, P 2 1 / n space group; unit cell parameters: a = 5.78160(10) Å, b = 15.0976(2) Å, c =...
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| Veröffentlicht in: | Journal of structural chemistry 2024-07, Vol.65 (7), p.1346-1356 |
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| container_title | Journal of structural chemistry |
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| creator | Polozov, M. A. Zherebtsov, D. A. Osipov, A. A. Radzhakumar, K. Naifert, S. A. Spiridonova, D. V. Zaguzin, A. S. Vinnik, D. A. |
| description | The crystal structure of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid dihydrate is described and the following structural features are established by XRD: C
8
H
6
I
4
O
6
,
M
705.73; monoclinic crystal system,
P
2
1
/
n
space group; unit cell parameters:
a
= 5.78160(10) Å,
b
= 15.0976(2) Å,
c
= 17.3437(3) Å; α = 90°, β = 94.602(2)°, γ = 90°;
V
= 1509.02(4) Å
3
,
Z
= 4, ρ
calc
= 3.106 g/cm
3
. Some features of the thermolysis of terephthalic acid and its iodine derivatives are described. Diiodoterephthalic acid is the least thermally stable, tetraiodoterephthalic acid is the most stable. The iodinated terephthalic acids have similar heats of fusion. The largest amount of carbon residue is formed during the decomposition of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid. |
| doi_str_mv | 10.1134/S0022476624070060 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3085103634</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3085103634</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-42c0824b90b22cca7a28d34e2e74881470695f834fc6f3e01213cdde21d8149e3</originalsourceid><addsrcrecordid>eNp1kE9Lw0AUxBdRsFY_gLeA10Tf_slmc6zFqlDw0HgO290Xk9Jm624KVr-8iVU8iKcHM_ObB0PIJYVrSrm4WQAwJjIpmYAMQMIRGdE044nKsvyYjAY7GfxTchbCCgBylcsR-Vh0fme6ncfIVRGLeZzGMimw87px1iU0Fskttu_Yom2M9kv3tl83JpqYxka6tdEM9UCHAe9qjIoa_cat96H5kh6dbVrdoY0K9Litu1r_4OGcnFR6HfDi-47J8-yumD4k86f7x-lknhgmVZcIZkAxscxhyZgxOtNMWS6QYSaUoiIDmaeV4qIysuIIlFFurEVGbe_myMfk6tC79e51h6ErV27n2_5lyUGlFLjkok_RQ8p4F4LHqtz6ZqP9vqRQDhuXfzbuGXZgQp9tX9D_Nv8PfQJvJHxb</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3085103634</pqid></control><display><type>article</type><title>Structure of 2,3,5,6-Tetraiodo-1,4-Benzenedicarboxylic Acid and Features of the Thermolysis of Iodinated Terephthalic Acids</title><source>Springer Nature - Complete Springer Journals</source><creator>Polozov, M. A. ; Zherebtsov, D. A. ; Osipov, A. A. ; Radzhakumar, K. ; Naifert, S. A. ; Spiridonova, D. V. ; Zaguzin, A. S. ; Vinnik, D. A.</creator><creatorcontrib>Polozov, M. A. ; Zherebtsov, D. A. ; Osipov, A. A. ; Radzhakumar, K. ; Naifert, S. A. ; Spiridonova, D. V. ; Zaguzin, A. S. ; Vinnik, D. A.</creatorcontrib><description>The crystal structure of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid dihydrate is described and the following structural features are established by XRD: C
8
H
6
I
4
O
6
,
M
705.73; monoclinic crystal system,
P
2
1
/
n
space group; unit cell parameters:
a
= 5.78160(10) Å,
b
= 15.0976(2) Å,
c
= 17.3437(3) Å; α = 90°, β = 94.602(2)°, γ = 90°;
V
= 1509.02(4) Å
3
,
Z
= 4, ρ
calc
= 3.106 g/cm
3
. Some features of the thermolysis of terephthalic acid and its iodine derivatives are described. Diiodoterephthalic acid is the least thermally stable, tetraiodoterephthalic acid is the most stable. The iodinated terephthalic acids have similar heats of fusion. The largest amount of carbon residue is formed during the decomposition of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476624070060</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Heat of fusion ; Inorganic Chemistry ; Iodine ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics ; Terephthalic acid ; Thermal stability ; Unit cell</subject><ispartof>Journal of structural chemistry, 2024-07, Vol.65 (7), p.1346-1356</ispartof><rights>Pleiades Publishing, Ltd. 2024</rights><rights>Pleiades Publishing, Ltd. 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-42c0824b90b22cca7a28d34e2e74881470695f834fc6f3e01213cdde21d8149e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476624070060$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476624070060$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Polozov, M. A.</creatorcontrib><creatorcontrib>Zherebtsov, D. A.</creatorcontrib><creatorcontrib>Osipov, A. A.</creatorcontrib><creatorcontrib>Radzhakumar, K.</creatorcontrib><creatorcontrib>Naifert, S. A.</creatorcontrib><creatorcontrib>Spiridonova, D. V.</creatorcontrib><creatorcontrib>Zaguzin, A. S.</creatorcontrib><creatorcontrib>Vinnik, D. A.</creatorcontrib><title>Structure of 2,3,5,6-Tetraiodo-1,4-Benzenedicarboxylic Acid and Features of the Thermolysis of Iodinated Terephthalic Acids</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The crystal structure of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid dihydrate is described and the following structural features are established by XRD: C
8
H
6
I
4
O
6
,
M
705.73; monoclinic crystal system,
P
2
1
/
n
space group; unit cell parameters:
a
= 5.78160(10) Å,
b
= 15.0976(2) Å,
c
= 17.3437(3) Å; α = 90°, β = 94.602(2)°, γ = 90°;
V
= 1509.02(4) Å
3
,
Z
= 4, ρ
calc
= 3.106 g/cm
3
. Some features of the thermolysis of terephthalic acid and its iodine derivatives are described. Diiodoterephthalic acid is the least thermally stable, tetraiodoterephthalic acid is the most stable. The iodinated terephthalic acids have similar heats of fusion. The largest amount of carbon residue is formed during the decomposition of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Heat of fusion</subject><subject>Inorganic Chemistry</subject><subject>Iodine</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><subject>Terephthalic acid</subject><subject>Thermal stability</subject><subject>Unit cell</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AUxBdRsFY_gLeA10Tf_slmc6zFqlDw0HgO290Xk9Jm624KVr-8iVU8iKcHM_ObB0PIJYVrSrm4WQAwJjIpmYAMQMIRGdE044nKsvyYjAY7GfxTchbCCgBylcsR-Vh0fme6ncfIVRGLeZzGMimw87px1iU0Fskttu_Yom2M9kv3tl83JpqYxka6tdEM9UCHAe9qjIoa_cat96H5kh6dbVrdoY0K9Litu1r_4OGcnFR6HfDi-47J8-yumD4k86f7x-lknhgmVZcIZkAxscxhyZgxOtNMWS6QYSaUoiIDmaeV4qIysuIIlFFurEVGbe_myMfk6tC79e51h6ErV27n2_5lyUGlFLjkok_RQ8p4F4LHqtz6ZqP9vqRQDhuXfzbuGXZgQp9tX9D_Nv8PfQJvJHxb</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>Polozov, M. A.</creator><creator>Zherebtsov, D. A.</creator><creator>Osipov, A. A.</creator><creator>Radzhakumar, K.</creator><creator>Naifert, S. A.</creator><creator>Spiridonova, D. V.</creator><creator>Zaguzin, A. S.</creator><creator>Vinnik, D. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240701</creationdate><title>Structure of 2,3,5,6-Tetraiodo-1,4-Benzenedicarboxylic Acid and Features of the Thermolysis of Iodinated Terephthalic Acids</title><author>Polozov, M. A. ; Zherebtsov, D. A. ; Osipov, A. A. ; Radzhakumar, K. ; Naifert, S. A. ; Spiridonova, D. V. ; Zaguzin, A. S. ; Vinnik, D. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-42c0824b90b22cca7a28d34e2e74881470695f834fc6f3e01213cdde21d8149e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Heat of fusion</topic><topic>Inorganic Chemistry</topic><topic>Iodine</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><topic>Terephthalic acid</topic><topic>Thermal stability</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Polozov, M. A.</creatorcontrib><creatorcontrib>Zherebtsov, D. A.</creatorcontrib><creatorcontrib>Osipov, A. A.</creatorcontrib><creatorcontrib>Radzhakumar, K.</creatorcontrib><creatorcontrib>Naifert, S. A.</creatorcontrib><creatorcontrib>Spiridonova, D. V.</creatorcontrib><creatorcontrib>Zaguzin, A. S.</creatorcontrib><creatorcontrib>Vinnik, D. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Polozov, M. A.</au><au>Zherebtsov, D. A.</au><au>Osipov, A. A.</au><au>Radzhakumar, K.</au><au>Naifert, S. A.</au><au>Spiridonova, D. V.</au><au>Zaguzin, A. S.</au><au>Vinnik, D. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of 2,3,5,6-Tetraiodo-1,4-Benzenedicarboxylic Acid and Features of the Thermolysis of Iodinated Terephthalic Acids</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2024-07-01</date><risdate>2024</risdate><volume>65</volume><issue>7</issue><spage>1346</spage><epage>1356</epage><pages>1346-1356</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The crystal structure of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid dihydrate is described and the following structural features are established by XRD: C
8
H
6
I
4
O
6
,
M
705.73; monoclinic crystal system,
P
2
1
/
n
space group; unit cell parameters:
a
= 5.78160(10) Å,
b
= 15.0976(2) Å,
c
= 17.3437(3) Å; α = 90°, β = 94.602(2)°, γ = 90°;
V
= 1509.02(4) Å
3
,
Z
= 4, ρ
calc
= 3.106 g/cm
3
. Some features of the thermolysis of terephthalic acid and its iodine derivatives are described. Diiodoterephthalic acid is the least thermally stable, tetraiodoterephthalic acid is the most stable. The iodinated terephthalic acids have similar heats of fusion. The largest amount of carbon residue is formed during the decomposition of 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476624070060</doi><tpages>11</tpages></addata></record> |
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| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Crystal structure Heat of fusion Inorganic Chemistry Iodine Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics Terephthalic acid Thermal stability Unit cell |
| title | Structure of 2,3,5,6-Tetraiodo-1,4-Benzenedicarboxylic Acid and Features of the Thermolysis of Iodinated Terephthalic Acids |
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