Gallium Selenide Thin Films Grown on Silicon by Plasma-Enhanced Chemical Vapor Deposition
Gallium selenide (GaSe) thin films on silicon(111) have been first grown by plasma-enhanced chemical vapor deposition (PECVD) using high-purity elemental gallium and selenium as the precursors. The reactive plasma components formed in the gas phase have been studied by optical emission spectroscopy....
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Veröffentlicht in: | High energy chemistry 2024-08, Vol.58 (4), p.440-445 |
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creator | Kudryashov, M. A. Mochalov, L. A. Kudryashova, Yu. P. Slapovskaya, E. A. |
description | Gallium selenide (GaSe) thin films on silicon(111) have been first grown by plasma-enhanced chemical vapor deposition (PECVD) using high-purity elemental gallium and selenium as the precursors. The reactive plasma components formed in the gas phase have been studied by optical emission spectroscopy. All grown films have a stoichiometry similar to that of GaSe. An increase in the plasma discharge power to 50 W and higher leads to the formation of an ε-GaSe phase, an improvement in the structural quality of the films, and an increase in the grain sizes with simultaneous grain compaction. |
doi_str_mv | 10.1134/S0018143924700309 |
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A. ; Mochalov, L. A. ; Kudryashova, Yu. P. ; Slapovskaya, E. A.</creator><creatorcontrib>Kudryashov, M. A. ; Mochalov, L. A. ; Kudryashova, Yu. P. ; Slapovskaya, E. A.</creatorcontrib><description>Gallium selenide (GaSe) thin films on silicon(111) have been first grown by plasma-enhanced chemical vapor deposition (PECVD) using high-purity elemental gallium and selenium as the precursors. The reactive plasma components formed in the gas phase have been studied by optical emission spectroscopy. All grown films have a stoichiometry similar to that of GaSe. An increase in the plasma discharge power to 50 W and higher leads to the formation of an ε-GaSe phase, an improvement in the structural quality of the films, and an increase in the grain sizes with simultaneous grain compaction.</description><identifier>ISSN: 0018-1439</identifier><identifier>EISSN: 1608-3148</identifier><identifier>DOI: 10.1134/S0018143924700309</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Gallium selenides ; Grain size ; Optical emission spectroscopy ; Physical Chemistry ; Plasma Chemistry ; Plasma enhanced chemical vapor deposition ; Plasma jets ; Silicon substrates ; Stoichiometry ; Thin films ; Vapor phases</subject><ispartof>High energy chemistry, 2024-08, Vol.58 (4), p.440-445</ispartof><rights>Pleiades Publishing, Ltd. 2024. 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An increase in the plasma discharge power to 50 W and higher leads to the formation of an ε-GaSe phase, an improvement in the structural quality of the films, and an increase in the grain sizes with simultaneous grain compaction.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Gallium selenides</subject><subject>Grain size</subject><subject>Optical emission spectroscopy</subject><subject>Physical Chemistry</subject><subject>Plasma Chemistry</subject><subject>Plasma enhanced chemical vapor deposition</subject><subject>Plasma jets</subject><subject>Silicon substrates</subject><subject>Stoichiometry</subject><subject>Thin films</subject><subject>Vapor phases</subject><issn>0018-1439</issn><issn>1608-3148</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kF9LwzAUxYMoOKcfwLeAz9WkSdv0UeZWhYHCpuBTSdNbl5EmNdmQfXtTJvgg3pfzcH_n_jkIXVNySynjdytCqKCclSkvCGGkPEETmhORMMrFKZqM7WTsn6OLELaEkCxSE_ReSWP0vscrMGB1C3i90RYvtOkDrrz7sthZvNJGq6jNAb8YGXqZzO1GWgUtnm2g10oa_CYH5_EDDC7onXb2Ep110gS4-tEpel3M17PHZPlcPc3ul4mipdglPGdNvLyVnYQ0pXwswqRqm0ZEIr4jeNOWqoSU0awD6ESRUymKNh1NwKbo5jh38O5zD2FXb93e27iyZkTEQAqeZ5GiR0p5F4KHrh687qU_1JTUY4L1nwSjJz16QmTtB_jfyf-bvgFaLnGw</recordid><startdate>20240801</startdate><enddate>20240801</enddate><creator>Kudryashov, M. 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A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-463b181dafae2214444403acdbb8c1924784bd9c9e2315feef8761a87d21dafe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Gallium selenides</topic><topic>Grain size</topic><topic>Optical emission spectroscopy</topic><topic>Physical Chemistry</topic><topic>Plasma Chemistry</topic><topic>Plasma enhanced chemical vapor deposition</topic><topic>Plasma jets</topic><topic>Silicon substrates</topic><topic>Stoichiometry</topic><topic>Thin films</topic><topic>Vapor phases</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kudryashov, M. A.</creatorcontrib><creatorcontrib>Mochalov, L. A.</creatorcontrib><creatorcontrib>Kudryashova, Yu. P.</creatorcontrib><creatorcontrib>Slapovskaya, E. 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The reactive plasma components formed in the gas phase have been studied by optical emission spectroscopy. All grown films have a stoichiometry similar to that of GaSe. An increase in the plasma discharge power to 50 W and higher leads to the formation of an ε-GaSe phase, an improvement in the structural quality of the films, and an increase in the grain sizes with simultaneous grain compaction.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0018143924700309</doi><tpages>6</tpages></addata></record> |
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subjects | Chemistry Chemistry and Materials Science Gallium selenides Grain size Optical emission spectroscopy Physical Chemistry Plasma Chemistry Plasma enhanced chemical vapor deposition Plasma jets Silicon substrates Stoichiometry Thin films Vapor phases |
title | Gallium Selenide Thin Films Grown on Silicon by Plasma-Enhanced Chemical Vapor Deposition |
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