Sustainable epoxidation of expired palm oil–derived oleic acid via in situ peracid mechanism with applied ion resin Amberlite IR-120H: from waste to wealth
Over the last decade, there has been growing interest/global concern in synthesizing products from renewable energy sources. Epoxides are intermediate products that can be used to produce other materials such as polyols through the epoxidation of vegetable oils. In this study, expired palm oil was u...
Gespeichert in:
| Veröffentlicht in: | Biomass conversion and biorefinery 2024, Vol.14 (15), p.17395-17403 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 17403 |
|---|---|
| container_issue | 15 |
| container_start_page | 17395 |
| container_title | Biomass conversion and biorefinery |
| container_volume | 14 |
| creator | Mahadi, Mahazmi Burhanuddin Azmi, Intan Suhada Kadir, Mohd Zulkipli Ab Mohamed, Noorfazlida Rahman, Mariam A. Jalil, Mohd Jumain |
| description | Over the last decade, there has been growing interest/global concern in synthesizing products from renewable energy sources. Epoxides are intermediate products that can be used to produce other materials such as polyols through the epoxidation of vegetable oils. In this study, expired palm oil was used to synthesize epoxides via in situ peracid mechanism utilizing an ion exchange resin catalyst. Based on the results, the relative conversion to oxirane (RCO) is 63%. The following optimum process parameters were used for the epoxidation process: (1) stirring speed: 600 rpm, (2) reaction temperature: 90 °C, and (3) formic acid/unsaturated fatty acid molar ratio: 1:1. Besides that, a mathematical model was developed by using the numerical integration Runge Kutta 4th Order method using MATLAB software. Based on the results of the kinetic study, the summation of error is smaller, and therefore, the kinetic model is validated. |
| doi_str_mv | 10.1007/s13399-023-04019-w |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3082954750</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3082954750</sourcerecordid><originalsourceid>FETCH-LOGICAL-c249t-228cb538b29e83ca82a567d4ceeff133473b446293d28833a5a079a47d3bf46d3</originalsourceid><addsrcrecordid>eNp9kc1KxDAUhYsoOKgv4Crgupom6TRxJ4M6woDgzzrctrdOpG1qkvlx5zu49uV8EuOM6M7VvRy-cy7ckyTHGT3NKC3OfMa5UillPKWCZipd7SQjlimajiXju797lu8nR94_UxrRgktOR8nH_cIHMD2ULRIc7NrUEIztiW0IrgfjsCYDtB2xpv18e6_RmWWUbIumIlCZmiwNENMTb8KCDOg2WofVHHrjO7IyYU5gGFoTXd-5Dn2kL7oSXWsCkpu7NGN0ek4aZyMOPmrBkhVCG-aHyV4Drcejn3mQPF5dPkym6ez2-mZyMUsrJlRIGZNVmXNZMoWSVyAZ5OOiFhVi08TniIKXQoyZ4jWTknPIgRYKRFHzshHjmh8kJ9vcwdmXBfqgn-3C9fGk5lQylYsip5FiW6py1nuHjR6c6cC96ozq7yb0tgkd36s3TehVNPGtyUe4f0L3F_2P6wu9iY56</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3082954750</pqid></control><display><type>article</type><title>Sustainable epoxidation of expired palm oil–derived oleic acid via in situ peracid mechanism with applied ion resin Amberlite IR-120H: from waste to wealth</title><source>SpringerLink Journals</source><creator>Mahadi, Mahazmi Burhanuddin ; Azmi, Intan Suhada ; Kadir, Mohd Zulkipli Ab ; Mohamed, Noorfazlida ; Rahman, Mariam A. ; Jalil, Mohd Jumain</creator><creatorcontrib>Mahadi, Mahazmi Burhanuddin ; Azmi, Intan Suhada ; Kadir, Mohd Zulkipli Ab ; Mohamed, Noorfazlida ; Rahman, Mariam A. ; Jalil, Mohd Jumain</creatorcontrib><description>Over the last decade, there has been growing interest/global concern in synthesizing products from renewable energy sources. Epoxides are intermediate products that can be used to produce other materials such as polyols through the epoxidation of vegetable oils. In this study, expired palm oil was used to synthesize epoxides via in situ peracid mechanism utilizing an ion exchange resin catalyst. Based on the results, the relative conversion to oxirane (RCO) is 63%. The following optimum process parameters were used for the epoxidation process: (1) stirring speed: 600 rpm, (2) reaction temperature: 90 °C, and (3) formic acid/unsaturated fatty acid molar ratio: 1:1. Besides that, a mathematical model was developed by using the numerical integration Runge Kutta 4th Order method using MATLAB software. Based on the results of the kinetic study, the summation of error is smaller, and therefore, the kinetic model is validated.</description><identifier>ISSN: 2190-6815</identifier><identifier>EISSN: 2190-6823</identifier><identifier>DOI: 10.1007/s13399-023-04019-w</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Amberlite (trademark) ; Biotechnology ; Chemical synthesis ; Energy ; Epoxidation ; Error analysis ; Ethylene oxide ; Formic acid ; Ion exchange ; Ion exchange resins ; Numerical integration ; Oleic acid ; Original Article ; Palm oil ; Peracids ; Polyols ; Process parameters ; Renewable and Green Energy ; Renewable energy sources ; Runge-Kutta method ; Vegetable oils</subject><ispartof>Biomass conversion and biorefinery, 2024, Vol.14 (15), p.17395-17403</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-228cb538b29e83ca82a567d4ceeff133473b446293d28833a5a079a47d3bf46d3</citedby><cites>FETCH-LOGICAL-c249t-228cb538b29e83ca82a567d4ceeff133473b446293d28833a5a079a47d3bf46d3</cites><orcidid>0000-0001-5205-4287</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13399-023-04019-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13399-023-04019-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Mahadi, Mahazmi Burhanuddin</creatorcontrib><creatorcontrib>Azmi, Intan Suhada</creatorcontrib><creatorcontrib>Kadir, Mohd Zulkipli Ab</creatorcontrib><creatorcontrib>Mohamed, Noorfazlida</creatorcontrib><creatorcontrib>Rahman, Mariam A.</creatorcontrib><creatorcontrib>Jalil, Mohd Jumain</creatorcontrib><title>Sustainable epoxidation of expired palm oil–derived oleic acid via in situ peracid mechanism with applied ion resin Amberlite IR-120H: from waste to wealth</title><title>Biomass conversion and biorefinery</title><addtitle>Biomass Conv. Bioref</addtitle><description>Over the last decade, there has been growing interest/global concern in synthesizing products from renewable energy sources. Epoxides are intermediate products that can be used to produce other materials such as polyols through the epoxidation of vegetable oils. In this study, expired palm oil was used to synthesize epoxides via in situ peracid mechanism utilizing an ion exchange resin catalyst. Based on the results, the relative conversion to oxirane (RCO) is 63%. The following optimum process parameters were used for the epoxidation process: (1) stirring speed: 600 rpm, (2) reaction temperature: 90 °C, and (3) formic acid/unsaturated fatty acid molar ratio: 1:1. Besides that, a mathematical model was developed by using the numerical integration Runge Kutta 4th Order method using MATLAB software. Based on the results of the kinetic study, the summation of error is smaller, and therefore, the kinetic model is validated.</description><subject>Amberlite (trademark)</subject><subject>Biotechnology</subject><subject>Chemical synthesis</subject><subject>Energy</subject><subject>Epoxidation</subject><subject>Error analysis</subject><subject>Ethylene oxide</subject><subject>Formic acid</subject><subject>Ion exchange</subject><subject>Ion exchange resins</subject><subject>Numerical integration</subject><subject>Oleic acid</subject><subject>Original Article</subject><subject>Palm oil</subject><subject>Peracids</subject><subject>Polyols</subject><subject>Process parameters</subject><subject>Renewable and Green Energy</subject><subject>Renewable energy sources</subject><subject>Runge-Kutta method</subject><subject>Vegetable oils</subject><issn>2190-6815</issn><issn>2190-6823</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kc1KxDAUhYsoOKgv4Crgupom6TRxJ4M6woDgzzrctrdOpG1qkvlx5zu49uV8EuOM6M7VvRy-cy7ckyTHGT3NKC3OfMa5UillPKWCZipd7SQjlimajiXju797lu8nR94_UxrRgktOR8nH_cIHMD2ULRIc7NrUEIztiW0IrgfjsCYDtB2xpv18e6_RmWWUbIumIlCZmiwNENMTb8KCDOg2WofVHHrjO7IyYU5gGFoTXd-5Dn2kL7oSXWsCkpu7NGN0ek4aZyMOPmrBkhVCG-aHyV4Drcejn3mQPF5dPkym6ez2-mZyMUsrJlRIGZNVmXNZMoWSVyAZ5OOiFhVi08TniIKXQoyZ4jWTknPIgRYKRFHzshHjmh8kJ9vcwdmXBfqgn-3C9fGk5lQylYsip5FiW6py1nuHjR6c6cC96ozq7yb0tgkd36s3TehVNPGtyUe4f0L3F_2P6wu9iY56</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Mahadi, Mahazmi Burhanuddin</creator><creator>Azmi, Intan Suhada</creator><creator>Kadir, Mohd Zulkipli Ab</creator><creator>Mohamed, Noorfazlida</creator><creator>Rahman, Mariam A.</creator><creator>Jalil, Mohd Jumain</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5205-4287</orcidid></search><sort><creationdate>2024</creationdate><title>Sustainable epoxidation of expired palm oil–derived oleic acid via in situ peracid mechanism with applied ion resin Amberlite IR-120H: from waste to wealth</title><author>Mahadi, Mahazmi Burhanuddin ; Azmi, Intan Suhada ; Kadir, Mohd Zulkipli Ab ; Mohamed, Noorfazlida ; Rahman, Mariam A. ; Jalil, Mohd Jumain</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-228cb538b29e83ca82a567d4ceeff133473b446293d28833a5a079a47d3bf46d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Amberlite (trademark)</topic><topic>Biotechnology</topic><topic>Chemical synthesis</topic><topic>Energy</topic><topic>Epoxidation</topic><topic>Error analysis</topic><topic>Ethylene oxide</topic><topic>Formic acid</topic><topic>Ion exchange</topic><topic>Ion exchange resins</topic><topic>Numerical integration</topic><topic>Oleic acid</topic><topic>Original Article</topic><topic>Palm oil</topic><topic>Peracids</topic><topic>Polyols</topic><topic>Process parameters</topic><topic>Renewable and Green Energy</topic><topic>Renewable energy sources</topic><topic>Runge-Kutta method</topic><topic>Vegetable oils</topic><toplevel>online_resources</toplevel><creatorcontrib>Mahadi, Mahazmi Burhanuddin</creatorcontrib><creatorcontrib>Azmi, Intan Suhada</creatorcontrib><creatorcontrib>Kadir, Mohd Zulkipli Ab</creatorcontrib><creatorcontrib>Mohamed, Noorfazlida</creatorcontrib><creatorcontrib>Rahman, Mariam A.</creatorcontrib><creatorcontrib>Jalil, Mohd Jumain</creatorcontrib><collection>CrossRef</collection><jtitle>Biomass conversion and biorefinery</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mahadi, Mahazmi Burhanuddin</au><au>Azmi, Intan Suhada</au><au>Kadir, Mohd Zulkipli Ab</au><au>Mohamed, Noorfazlida</au><au>Rahman, Mariam A.</au><au>Jalil, Mohd Jumain</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sustainable epoxidation of expired palm oil–derived oleic acid via in situ peracid mechanism with applied ion resin Amberlite IR-120H: from waste to wealth</atitle><jtitle>Biomass conversion and biorefinery</jtitle><stitle>Biomass Conv. Bioref</stitle><date>2024</date><risdate>2024</risdate><volume>14</volume><issue>15</issue><spage>17395</spage><epage>17403</epage><pages>17395-17403</pages><issn>2190-6815</issn><eissn>2190-6823</eissn><abstract>Over the last decade, there has been growing interest/global concern in synthesizing products from renewable energy sources. Epoxides are intermediate products that can be used to produce other materials such as polyols through the epoxidation of vegetable oils. In this study, expired palm oil was used to synthesize epoxides via in situ peracid mechanism utilizing an ion exchange resin catalyst. Based on the results, the relative conversion to oxirane (RCO) is 63%. The following optimum process parameters were used for the epoxidation process: (1) stirring speed: 600 rpm, (2) reaction temperature: 90 °C, and (3) formic acid/unsaturated fatty acid molar ratio: 1:1. Besides that, a mathematical model was developed by using the numerical integration Runge Kutta 4th Order method using MATLAB software. Based on the results of the kinetic study, the summation of error is smaller, and therefore, the kinetic model is validated.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13399-023-04019-w</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-5205-4287</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2190-6815 |
| ispartof | Biomass conversion and biorefinery, 2024, Vol.14 (15), p.17395-17403 |
| issn | 2190-6815 2190-6823 |
| language | eng |
| recordid | cdi_proquest_journals_3082954750 |
| source | SpringerLink Journals |
| subjects | Amberlite (trademark) Biotechnology Chemical synthesis Energy Epoxidation Error analysis Ethylene oxide Formic acid Ion exchange Ion exchange resins Numerical integration Oleic acid Original Article Palm oil Peracids Polyols Process parameters Renewable and Green Energy Renewable energy sources Runge-Kutta method Vegetable oils |
| title | Sustainable epoxidation of expired palm oil–derived oleic acid via in situ peracid mechanism with applied ion resin Amberlite IR-120H: from waste to wealth |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T07%3A58%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Sustainable%20epoxidation%20of%20expired%20palm%20oil%E2%80%93derived%20oleic%20acid%20via%20in%20situ%20peracid%20mechanism%20with%20applied%20ion%20resin%20Amberlite%20IR-120H:%20from%20waste%20to%20wealth&rft.jtitle=Biomass%20conversion%20and%20biorefinery&rft.au=Mahadi,%20Mahazmi%20Burhanuddin&rft.date=2024&rft.volume=14&rft.issue=15&rft.spage=17395&rft.epage=17403&rft.pages=17395-17403&rft.issn=2190-6815&rft.eissn=2190-6823&rft_id=info:doi/10.1007/s13399-023-04019-w&rft_dat=%3Cproquest_cross%3E3082954750%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3082954750&rft_id=info:pmid/&rfr_iscdi=true |