Role of Liquid Immiscibility in the Formation of the Rare Metal Granites of the Katugin Massif, Aldan Shield

The paper discusses possible immiscibility between fluoride salt (“cryolite”) and silicate liquids into which the parental melt of the Katugin massif exsolves, and the petrological implications of this phenomenon. Results of a detailed study of the cryolite and zircon are presented. Liquid immiscibi...

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Veröffentlicht in:Petrology 2024-08, Vol.32 (4), p.551-568
Hauptverfasser: Tolmacheva, E. V., Velikoslavinskii, S. D., Kotov, A. B., Larin, A. M., Sklyarov, E. V., Gladkochub, D. P., Donskaya, T. V., Skovitina, T. M., Kovach, V. P., Galankina, O. L.
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container_end_page 568
container_issue 4
container_start_page 551
container_title Petrology
container_volume 32
creator Tolmacheva, E. V.
Velikoslavinskii, S. D.
Kotov, A. B.
Larin, A. M.
Sklyarov, E. V.
Gladkochub, D. P.
Donskaya, T. V.
Skovitina, T. M.
Kovach, V. P.
Galankina, O. L.
description The paper discusses possible immiscibility between fluoride salt (“cryolite”) and silicate liquids into which the parental melt of the Katugin massif exsolves, and the petrological implications of this phenomenon. Results of a detailed study of the cryolite and zircon are presented. Liquid immiscibility is demonstrated to have triggered the massive crystallization of zircon and, together with the processes of subsequent evolution of the cryolite melt, contributed to the formation of the large cryolite bodies. Data on mineral-hosted inclusions were used to estimate the crystallization temperatures of fluoride salt and silicate melts and outline the pathways of their evolution during the formation of the massif. It is shown that the granites of the Katugin and West Katugin massifs were most likely derived from distinct sources, that differed mainly in fluorine content. Data on the chemical composition of three zircon generations identified in the granites of the Katugin massif are presented.
doi_str_mv 10.1134/S0869591124700127
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subjects Chemical composition
Cryolite
Crystallization
Earth and Environmental Science
Earth Sciences
Evolution
Fluorides
Fluorine
Fluorine content
Geochemistry
Granite
Immiscibility
Inclusions
Liquids
Massifs
Melts (crystal growth)
Mineralogy
Miscibility
Silicates
Zircon
title Role of Liquid Immiscibility in the Formation of the Rare Metal Granites of the Katugin Massif, Aldan Shield
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