Synthesis and Structural Study of New Gold(III) Complexes with 1,1-Dimethylbiguanide

Synthesis and Structural Study of New Gold(III) Complexes with 1,1-Dimethylbiguanide

The following new compounds of gold(III) with 1,1-dimethylbiguanide (NH 2 C(=NH)NHC(=NH)N(CH 3 ) 2 ) are prepared and studied by XRD: [Au(dmbgH)Cl 2 ]Cl . 0.5H 2 O, [Au(dmbgH)Cl 2 ]ClO 4 . H 2 O, [Au(dmbgH) Cl 2 ]ClO 4 , [Au(dmbg)Cl 2 ][Au(dmbgH)Cl 2 ]Cl . H 2 O (dmbgH = 1,1-dimethylbiguanide, dmbg ...

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Veröffentlicht in:Journal of structural chemistry 2024-06, Vol.65 (6), p.1083-1092
Hauptverfasser: Makotchenko, E. V., Baidina, I. A., Korolkov, I. V., Gushchin, A. L.
Format: Artikel
Sprache:eng
Schlagworte:
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Gold
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
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Zusammenfassung:The following new compounds of gold(III) with 1,1-dimethylbiguanide (NH 2 C(=NH)NHC(=NH)N(CH 3 ) 2 ) are prepared and studied by XRD: [Au(dmbgH)Cl 2 ]Cl . 0.5H 2 O, [Au(dmbgH)Cl 2 ]ClO 4 . H 2 O, [Au(dmbgH) Cl 2 ]ClO 4 , [Au(dmbg)Cl 2 ][Au(dmbgH)Cl 2 ]Cl . H 2 O (dmbgH = 1,1-dimethylbiguanide, dmbg = deprotonated 1,1-dimethylbiguanide).
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476624060027