Crystal Chemistry of Minerals with Spinel Modules and New Data on the Symmetry, Structure, and Cation Distribution Features in Tashelgite, CaMgFe2+Al9O16(OH)
Rerefinement of the crystal structure of the mineral tashelgite with the idealized formula CaMgFe 2+ Al 9 O 16 (OH) (orthorhombic Pbam space group; a = 17.1823(1), b = 23.5718(4), c = 5.6973(5) Å) is performed using the earlier obtained diffraction data. Fine crystal structure details and distrib...
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| Veröffentlicht in: | Journal of structural chemistry 2024-06, Vol.65 (6), p.1129-1148 |
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| creator | Zarubina, E. S. Rastsvetaeva, R. K. Rusakov, V. S. Nikolaev, A. G. Vagizov, F. G. Bakhtin, A. I. Varlamov, D. A. Chukanov, N. V. Ananyev, S. A. Aksenov, S. M. |
| description | Rerefinement of the crystal structure of the mineral tashelgite with the idealized formula CaMgFe
2+
Al
9
O
16
(OH) (orthorhombic
Pbam
space group;
a
= 17.1823(1),
b
= 23.5718(4),
c
= 5.6973(5) Å) is performed using the earlier obtained diffraction data. Fine crystal structure details and distribution features of cation positions are retrieved from precision Mössbauer and optical spectroscopy data. It is shown that the main motif and the pattern of cation distribution over octahedral and tetrahedral positions are preserved, despite the symmetry increase. However, due to a smaller number of independent positions, the distribution in the
Pbam
model becomes less ordered than in the
Pc
model. The appearance of tashelgite, having a complex structure based on spinel modules, agrees well with the presence of associated minerals such as spinel-like magnetite and hercynite, as well as hibonite, also containing spinel modules in its structure. A comparative crystal chemical and modular analysis of natural and synthetic compounds containing spinel modules is performed. |
| doi_str_mv | 10.1134/S0022476624060064 |
| format | Article |
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2+
Al
9
O
16
(OH) (orthorhombic
Pbam
space group;
a
= 17.1823(1),
b
= 23.5718(4),
c
= 5.6973(5) Å) is performed using the earlier obtained diffraction data. Fine crystal structure details and distribution features of cation positions are retrieved from precision Mössbauer and optical spectroscopy data. It is shown that the main motif and the pattern of cation distribution over octahedral and tetrahedral positions are preserved, despite the symmetry increase. However, due to a smaller number of independent positions, the distribution in the
Pbam
model becomes less ordered than in the
Pc
model. The appearance of tashelgite, having a complex structure based on spinel modules, agrees well with the presence of associated minerals such as spinel-like magnetite and hercynite, as well as hibonite, also containing spinel modules in its structure. A comparative crystal chemical and modular analysis of natural and synthetic compounds containing spinel modules is performed.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476624060064</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Cations ; Chemical compounds ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Diffraction patterns ; Hercynite ; Inorganic Chemistry ; Minerals ; Modular structures ; Modules ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics ; Spinel ; Symmetry</subject><ispartof>Journal of structural chemistry, 2024-06, Vol.65 (6), p.1129-1148</ispartof><rights>Pleiades Publishing, Ltd. 2024</rights><rights>Pleiades Publishing, Ltd. 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-94bcaacde640470f8e90d19f67651e29f44a32e3022e39cb6f12be872c9e74d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476624060064$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476624060064$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Zarubina, E. S.</creatorcontrib><creatorcontrib>Rastsvetaeva, R. K.</creatorcontrib><creatorcontrib>Rusakov, V. S.</creatorcontrib><creatorcontrib>Nikolaev, A. G.</creatorcontrib><creatorcontrib>Vagizov, F. G.</creatorcontrib><creatorcontrib>Bakhtin, A. I.</creatorcontrib><creatorcontrib>Varlamov, D. A.</creatorcontrib><creatorcontrib>Chukanov, N. V.</creatorcontrib><creatorcontrib>Ananyev, S. A.</creatorcontrib><creatorcontrib>Aksenov, S. M.</creatorcontrib><title>Crystal Chemistry of Minerals with Spinel Modules and New Data on the Symmetry, Structure, and Cation Distribution Features in Tashelgite, CaMgFe2+Al9O16(OH)</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>Rerefinement of the crystal structure of the mineral tashelgite with the idealized formula CaMgFe
2+
Al
9
O
16
(OH) (orthorhombic
Pbam
space group;
a
= 17.1823(1),
b
= 23.5718(4),
c
= 5.6973(5) Å) is performed using the earlier obtained diffraction data. Fine crystal structure details and distribution features of cation positions are retrieved from precision Mössbauer and optical spectroscopy data. It is shown that the main motif and the pattern of cation distribution over octahedral and tetrahedral positions are preserved, despite the symmetry increase. However, due to a smaller number of independent positions, the distribution in the
Pbam
model becomes less ordered than in the
Pc
model. The appearance of tashelgite, having a complex structure based on spinel modules, agrees well with the presence of associated minerals such as spinel-like magnetite and hercynite, as well as hibonite, also containing spinel modules in its structure. A comparative crystal chemical and modular analysis of natural and synthetic compounds containing spinel modules is performed.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Cations</subject><subject>Chemical compounds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Diffraction patterns</subject><subject>Hercynite</subject><subject>Inorganic Chemistry</subject><subject>Minerals</subject><subject>Modular structures</subject><subject>Modules</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><subject>Spinel</subject><subject>Symmetry</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kcFOwkAQhjdGExF9AG-beNFIdXe7bLtHUkRMQA7gudm2U1pSWtzdhvAwvqtbMPFgPE3-zPf_M5lB6JaSJ0p9_rwkhDEeCME4EYQIfoZ6dBj4XhgE8hz1urbX9S_RlTEbQogMpeihr0gfjFUVjgrYlsbqA25yPC9r0KoyeF_aAi93TlZ43mRtBQarOsPvsMdjZRVuamwLwMvDdgvOPMBLq9vUthoGRzBStnTMuIsuk_YoJqA6wOCyxitlCqjWpXV8pObrCbDHUSUXVNwvpg_X6CJ3a8DNT-2jj8nLKpp6s8XrWzSaeSmVofUkT1Kl0gwEJzwgeQiSZFTmIhBDCkzmnCufge9uAL5ME5FTlkAYsFRCwDPi99HdKXenm88WjI03TatrNzL2iTsg59IfOoqeqFQ3xmjI450ut0ofYkri7gvxny84Dzt5jGPrNejf5P9N32TMiOY</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Zarubina, E. S.</creator><creator>Rastsvetaeva, R. K.</creator><creator>Rusakov, V. S.</creator><creator>Nikolaev, A. G.</creator><creator>Vagizov, F. G.</creator><creator>Bakhtin, A. I.</creator><creator>Varlamov, D. A.</creator><creator>Chukanov, N. V.</creator><creator>Ananyev, S. A.</creator><creator>Aksenov, S. M.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240601</creationdate><title>Crystal Chemistry of Minerals with Spinel Modules and New Data on the Symmetry, Structure, and Cation Distribution Features in Tashelgite, CaMgFe2+Al9O16(OH)</title><author>Zarubina, E. S. ; Rastsvetaeva, R. K. ; Rusakov, V. S. ; Nikolaev, A. G. ; Vagizov, F. G. ; Bakhtin, A. I. ; Varlamov, D. A. ; Chukanov, N. V. ; Ananyev, S. A. ; Aksenov, S. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-94bcaacde640470f8e90d19f67651e29f44a32e3022e39cb6f12be872c9e74d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Cations</topic><topic>Chemical compounds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Diffraction patterns</topic><topic>Hercynite</topic><topic>Inorganic Chemistry</topic><topic>Minerals</topic><topic>Modular structures</topic><topic>Modules</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><topic>Spinel</topic><topic>Symmetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zarubina, E. S.</creatorcontrib><creatorcontrib>Rastsvetaeva, R. K.</creatorcontrib><creatorcontrib>Rusakov, V. S.</creatorcontrib><creatorcontrib>Nikolaev, A. G.</creatorcontrib><creatorcontrib>Vagizov, F. G.</creatorcontrib><creatorcontrib>Bakhtin, A. I.</creatorcontrib><creatorcontrib>Varlamov, D. A.</creatorcontrib><creatorcontrib>Chukanov, N. V.</creatorcontrib><creatorcontrib>Ananyev, S. A.</creatorcontrib><creatorcontrib>Aksenov, S. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zarubina, E. S.</au><au>Rastsvetaeva, R. K.</au><au>Rusakov, V. S.</au><au>Nikolaev, A. G.</au><au>Vagizov, F. G.</au><au>Bakhtin, A. I.</au><au>Varlamov, D. A.</au><au>Chukanov, N. V.</au><au>Ananyev, S. A.</au><au>Aksenov, S. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal Chemistry of Minerals with Spinel Modules and New Data on the Symmetry, Structure, and Cation Distribution Features in Tashelgite, CaMgFe2+Al9O16(OH)</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>65</volume><issue>6</issue><spage>1129</spage><epage>1148</epage><pages>1129-1148</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>Rerefinement of the crystal structure of the mineral tashelgite with the idealized formula CaMgFe
2+
Al
9
O
16
(OH) (orthorhombic
Pbam
space group;
a
= 17.1823(1),
b
= 23.5718(4),
c
= 5.6973(5) Å) is performed using the earlier obtained diffraction data. Fine crystal structure details and distribution features of cation positions are retrieved from precision Mössbauer and optical spectroscopy data. It is shown that the main motif and the pattern of cation distribution over octahedral and tetrahedral positions are preserved, despite the symmetry increase. However, due to a smaller number of independent positions, the distribution in the
Pbam
model becomes less ordered than in the
Pc
model. The appearance of tashelgite, having a complex structure based on spinel modules, agrees well with the presence of associated minerals such as spinel-like magnetite and hercynite, as well as hibonite, also containing spinel modules in its structure. A comparative crystal chemical and modular analysis of natural and synthetic compounds containing spinel modules is performed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476624060064</doi><tpages>20</tpages></addata></record> |
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| subjects | Atomic Atomic/Molecular Structure and Spectra Cations Chemical compounds Chemistry Chemistry and Materials Science Crystal structure Diffraction patterns Hercynite Inorganic Chemistry Minerals Modular structures Modules Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics Spinel Symmetry |
| title | Crystal Chemistry of Minerals with Spinel Modules and New Data on the Symmetry, Structure, and Cation Distribution Features in Tashelgite, CaMgFe2+Al9O16(OH) |
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