Garnet-type double-layer solid electrolyte for dendrite-free solid-state Li batteries
Due to its high energy density and better safety performance, all-solid-state lithium batteries are regarded as important energy storage devices to replace the traditional liquid electrolyte Li-ion batteries. However, the problems of poor wettability of Li metal anode | solid-state electrolyte inter...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2024-07, Vol.28 (7), p.2001-2010 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Feng, Xingyi Zeng, Yingping Yan, Deen Zou, Hanbo Yang, Wei Chen, Shengzhou |
| description | Due to its high energy density and better safety performance, all-solid-state lithium batteries are regarded as important energy storage devices to replace the traditional liquid electrolyte Li-ion batteries. However, the problems of poor wettability of Li metal anode | solid-state electrolyte interface and easy growth of lithium dendrite have not been well solved. Here, we have constructed Fe-doped Li
7-3x
Fe
x
La
3
Zr
2
O
12
(Fe-LLZO) and Li
6.5
La
3
Zr
1.5
Ta
0.5
O
12
(LLZTO) garnet-type double-layer solid electrolyte. The high density of Li
7-3x
Fe
x
La
3
Zr
2
O
12
electrolyte and its interfacial wettability to Li metal not only effectively reduced the interface impedance between Li and solid electrolyte but also could stably cycle for more than 200 h without the growth of lithium dendrites at the rate of 0.1 mA cm
−2
. In addition, the all-solid-state lithium battery (Li|Fe
0.1
-LLZO|LLZTO|LFP) with LiFePO
4
as a cathode also showed excellent cycle stability and C-rate performance. |
| doi_str_mv | 10.1007/s10008-023-05719-z |
| format | Article |
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7-3x
Fe
x
La
3
Zr
2
O
12
(Fe-LLZO) and Li
6.5
La
3
Zr
1.5
Ta
0.5
O
12
(LLZTO) garnet-type double-layer solid electrolyte. The high density of Li
7-3x
Fe
x
La
3
Zr
2
O
12
electrolyte and its interfacial wettability to Li metal not only effectively reduced the interface impedance between Li and solid electrolyte but also could stably cycle for more than 200 h without the growth of lithium dendrites at the rate of 0.1 mA cm
−2
. In addition, the all-solid-state lithium battery (Li|Fe
0.1
-LLZO|LLZTO|LFP) with LiFePO
4
as a cathode also showed excellent cycle stability and C-rate performance.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-023-05719-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrochemistry ; Energy Storage ; Garnets ; Lithium batteries ; Lithium-ion batteries ; Original Paper ; Physical Chemistry ; Rechargeable batteries ; Solid electrolytes ; Solid state ; Wettability</subject><ispartof>Journal of solid state electrochemistry, 2024-07, Vol.28 (7), p.2001-2010</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-c90e3d744b2c4f3644868e631f3d5008820bd08bea50101df57cee2e514bb8fc3</cites><orcidid>0000-0001-7066-6412</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-023-05719-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-023-05719-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Feng, Xingyi</creatorcontrib><creatorcontrib>Zeng, Yingping</creatorcontrib><creatorcontrib>Yan, Deen</creatorcontrib><creatorcontrib>Zou, Hanbo</creatorcontrib><creatorcontrib>Yang, Wei</creatorcontrib><creatorcontrib>Chen, Shengzhou</creatorcontrib><title>Garnet-type double-layer solid electrolyte for dendrite-free solid-state Li batteries</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>Due to its high energy density and better safety performance, all-solid-state lithium batteries are regarded as important energy storage devices to replace the traditional liquid electrolyte Li-ion batteries. However, the problems of poor wettability of Li metal anode | solid-state electrolyte interface and easy growth of lithium dendrite have not been well solved. Here, we have constructed Fe-doped Li
7-3x
Fe
x
La
3
Zr
2
O
12
(Fe-LLZO) and Li
6.5
La
3
Zr
1.5
Ta
0.5
O
12
(LLZTO) garnet-type double-layer solid electrolyte. The high density of Li
7-3x
Fe
x
La
3
Zr
2
O
12
electrolyte and its interfacial wettability to Li metal not only effectively reduced the interface impedance between Li and solid electrolyte but also could stably cycle for more than 200 h without the growth of lithium dendrites at the rate of 0.1 mA cm
−2
. In addition, the all-solid-state lithium battery (Li|Fe
0.1
-LLZO|LLZTO|LFP) with LiFePO
4
as a cathode also showed excellent cycle stability and C-rate performance.</description><subject>Analytical Chemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Garnets</subject><subject>Lithium batteries</subject><subject>Lithium-ion batteries</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Solid electrolytes</subject><subject>Solid state</subject><subject>Wettability</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOwzAQtBBIlMIPcIrE2bB-JHaPqIKCVIkLPVtxvEapQlJs55B-PaZB4sZlH9qZWc0QcsvgngGoh5graApcUCgVW9HjGVkwKfKqKn1-mjnVUutLchXjHoCpisGC7DZ16DHRNB2wcMNoO6RdPWEo4tC1rsAOmxSGbkpY-CEUDnsX2oTUB8QZQ2Oq83XbFrZOCUOL8Zpc-LqLePPbl2T3_PS-fqHbt83r-nFLG64g0WYFKJyS0vJGelFJqSuNlWBeuDL70RysA22xLoEBc75UDSLHkklrtW_EktzNuocwfI0Yk9kPY-jzSyOyca5KWZUZxWdUE4YYA3pzCO1nHSbDwPzEZ-b4TI7PnOIzx0wSMylmcP-B4U_6H9Y3aYVzzg</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>Feng, Xingyi</creator><creator>Zeng, Yingping</creator><creator>Yan, Deen</creator><creator>Zou, Hanbo</creator><creator>Yang, Wei</creator><creator>Chen, Shengzhou</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-7066-6412</orcidid></search><sort><creationdate>20240701</creationdate><title>Garnet-type double-layer solid electrolyte for dendrite-free solid-state Li batteries</title><author>Feng, Xingyi ; Zeng, Yingping ; Yan, Deen ; Zou, Hanbo ; Yang, Wei ; Chen, Shengzhou</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-c90e3d744b2c4f3644868e631f3d5008820bd08bea50101df57cee2e514bb8fc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Analytical Chemistry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Garnets</topic><topic>Lithium batteries</topic><topic>Lithium-ion batteries</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Solid electrolytes</topic><topic>Solid state</topic><topic>Wettability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feng, Xingyi</creatorcontrib><creatorcontrib>Zeng, Yingping</creatorcontrib><creatorcontrib>Yan, Deen</creatorcontrib><creatorcontrib>Zou, Hanbo</creatorcontrib><creatorcontrib>Yang, Wei</creatorcontrib><creatorcontrib>Chen, Shengzhou</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feng, Xingyi</au><au>Zeng, Yingping</au><au>Yan, Deen</au><au>Zou, Hanbo</au><au>Yang, Wei</au><au>Chen, Shengzhou</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Garnet-type double-layer solid electrolyte for dendrite-free solid-state Li batteries</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2024-07-01</date><risdate>2024</risdate><volume>28</volume><issue>7</issue><spage>2001</spage><epage>2010</epage><pages>2001-2010</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Due to its high energy density and better safety performance, all-solid-state lithium batteries are regarded as important energy storage devices to replace the traditional liquid electrolyte Li-ion batteries. However, the problems of poor wettability of Li metal anode | solid-state electrolyte interface and easy growth of lithium dendrite have not been well solved. Here, we have constructed Fe-doped Li
7-3x
Fe
x
La
3
Zr
2
O
12
(Fe-LLZO) and Li
6.5
La
3
Zr
1.5
Ta
0.5
O
12
(LLZTO) garnet-type double-layer solid electrolyte. The high density of Li
7-3x
Fe
x
La
3
Zr
2
O
12
electrolyte and its interfacial wettability to Li metal not only effectively reduced the interface impedance between Li and solid electrolyte but also could stably cycle for more than 200 h without the growth of lithium dendrites at the rate of 0.1 mA cm
−2
. In addition, the all-solid-state lithium battery (Li|Fe
0.1
-LLZO|LLZTO|LFP) with LiFePO
4
as a cathode also showed excellent cycle stability and C-rate performance.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-023-05719-z</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-7066-6412</orcidid></addata></record> |
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| language | eng |
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| subjects | Analytical Chemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemistry Energy Storage Garnets Lithium batteries Lithium-ion batteries Original Paper Physical Chemistry Rechargeable batteries Solid electrolytes Solid state Wettability |
| title | Garnet-type double-layer solid electrolyte for dendrite-free solid-state Li batteries |
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