Efficient carbene transfer reactivity mediated by Fe() complexes supported by bulky alkoxides

Herein we describe the stoichiometric and catalytic carbene-transfer reactivity of iron( ii ) alkoxide complexes with iodonium ylide precursors. Treatment of PhIC(CO 2 Me) 2 with styrene in the presence of catalytic amounts of several different Fe(OR) 2 (THF) 2 precursors results in efficient cyclop...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2024-07, Vol.6 (55), p.733-736
Hauptverfasser:	Kulathungage, Lakshani W, Kurup, Sudheer S, Browne, Edison A, Spalink, Gabriel H, Ward, Cassandra L, Lord, Richard L, Groysman, Stanislav
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkoxides Carbenes Effectiveness Iron Precursors Styrenes Vinyl radical
Online-Zugang:	Volltext
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