Experimental study on indirect mineral carbonation using five types of slag for production of high-purity calcium carbonate

Mineral carbonation is one of the known methods for carbon capture, utilization, and storage (CCUS). Slag from the steel industry is studied as a common source of CaCO 3 via mineral carbonation owing to its high Ca content. Despite numerous preliminary studies, the optimal factors governing the mine...

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Veröffentlicht in:Journal of material cycles and waste management 2024-07, Vol.26 (4), p.2366-2377
Hauptverfasser: Son, Juhee, Kang, Jo Hong, Kim, Kwanghwi, Song, Hojun, Park, Hyun Sic
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container_issue 4
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container_title Journal of material cycles and waste management
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creator Son, Juhee
Kang, Jo Hong
Kim, Kwanghwi
Song, Hojun
Park, Hyun Sic
description Mineral carbonation is one of the known methods for carbon capture, utilization, and storage (CCUS). Slag from the steel industry is studied as a common source of CaCO 3 via mineral carbonation owing to its high Ca content. Despite numerous preliminary studies, the optimal factors governing the mineral carbonation of steelmaking slag, such as extraction and carbonation remain unexplored. In this study, we optimized the factors for Ca extraction and carbonation, as CaCO 3 produced under these optimized factors possesses commercial value due to its high purity. The extraction and carbonation experiments were performed on two types of slag samples, specifically non-magnetic steelmaking and pig iron slag, utilizing the chosen factors for each procedure. NH 4 Cl was chosen as the extractant because of its high calcium selectivity and inhibition of gel formation. Precipitates with Ca content ≥ 98% were obtained by extracting and carbonating them. The crystalline form and particle size of CaCO 3 in the precipitates were determined by the pH control. The findings of this study will be used to improve the design of precipitated calcium carbonate (PCC) production processes and increase the economic value of their output.
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subjects Acids
Ammonium chloride
Calcium carbonate
Carbon sequestration
Carbonation
Chemical precipitation
Civil Engineering
Climate change
Efficiency
Energy consumption
Engineering
Environmental Management
Iron and steel industry
Iron compounds
Original Article
Particle size
pH control
Pig iron
Precipitates
Purity
Slag
Steel industry
Steel making
Waste management
Waste Management/Waste Technology
title Experimental study on indirect mineral carbonation using five types of slag for production of high-purity calcium carbonate
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