Low‐temperature co‐fired ceramic application of SmTaO4 and YTaO4 with ZnO‐B2O3‐SiO2 additive

In this study, ZnO‐B2O3‐SiO2 (ZBS) glass was employed as a sintering facilitator, enabling low‐temperature sintering of SmTaO4 and YTaO4 ceramics. The influence of varying quantities of ZBS glass on sintering behavior and phase composition was investigated to reveal the low‐temperature sintering mec...

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Veröffentlicht in:Journal of the American Ceramic Society 2024-09, Vol.107 (9), p.6164-6171
Hauptverfasser: Yang, Hongcheng, Huang, Xier, Zhang, Jin, Li, Enzhu
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creator Yang, Hongcheng
Huang, Xier
Zhang, Jin
Li, Enzhu
description In this study, ZnO‐B2O3‐SiO2 (ZBS) glass was employed as a sintering facilitator, enabling low‐temperature sintering of SmTaO4 and YTaO4 ceramics. The influence of varying quantities of ZBS glass on sintering behavior and phase composition was investigated to reveal the low‐temperature sintering mechanism. ZBS glass exhibits favorable wetting behavior on the SmTaO4 and YTaO4 ceramic matrices and dramatically decreases the initial shrinkage temperature of ceramics throughout the sintering process. Composited with 20 wt. % ZBS and sintered at their optimal sintering temperature, the composite ceramics of SmTaO4 and YTaO4 possess favorable microwave dielectric properties: εr = 8.46, Q×f = 15,723 GHz, and τf = –6.68 ppm/°C (at 14.339 GHz), and εr = 4.21, Q×f = 18,939 GHz, and τf = –18.92 ppm/°C (at 15.512 GHz), respectively.
doi_str_mv 10.1111/jace.19896
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source Wiley Online Library Journals Frontfile Complete
subjects Boron oxides
Ceramics
Dielectric properties
LTCC
Phase composition
Silicon dioxide
Sintering
SmTaO4
YTaO4
Zinc oxide
ZnO‐B2O3‐SiO2
title Low‐temperature co‐fired ceramic application of SmTaO4 and YTaO4 with ZnO‐B2O3‐SiO2 additive
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