Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements

A series of substituted ferrocenyl boron derivatives was synthesized. The oxidation of the ferrocenyl unit resulted in a significant increase of the boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized by NMR spectroscopy, crystal structure analysis and by computatio...

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Veröffentlicht in:	European journal of inorganic chemistry 2024-06, Vol.27 (18), p.n/a
Hauptverfasser:	Köring, Laura, Birenheide, Bernhard, Krämer, Felix, Wenzel, Jonas O., Schoch, Roland, Brehm, Martin, Breher, Frank, Paradies, Jan
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes borane Boron Crystal structure ferrocene Lewis acid Lewis acidity NMR spectroscopy Oxidation sigmatropic rearrangement Structural analysis
Online-Zugang:	Volltext
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