Synthesis, characterization and stability of phosphonium phenolate zwitterions derived from a (diphenylphosphino)phenol derivative and oxiranes

Phosphonium phenolate zwitterions have been synthesized from 2,4-di- tert -butyl-6-(diphenylphosphino)phenol and five different oxirane derivatives. The reaction does not proceed at a detectable rate when the two reactants are combined in dichloromethane at room temperature. Despite the substantial...

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Veröffentlicht in:	Monatshefte für Chemie 2024, Vol.155 (7), p.715-723
Hauptverfasser:	Steiner, Matthias R., Marschner, Christoph, Baumgartner, Judith, Hlina, Johann A., Slugovc, Christian
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic alcohols Analytical Chemistry Chemistry Chemistry and Materials Science Chemistry/Food Science Crystallography Decomposition reactions Dichloromethane Ethers Ethylene oxide Inorganic Chemistry Organic Chemistry Original Paper Phosphine oxide Physical Chemistry Room temperature Single crystals Theoretical and Computational Chemistry Thermal stability Zwitterions
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