Giant enhancement of anti-quenching upconversion luminescence in Sc2W3O12:Er3+/Yb3+ phosphors for temperature sensing
Although negative thermal expansion (NTE) materials provide a new strategy to overcome the thermal-quenching phenomenon among rare earth doped luminescent materials, the overall weak upconversion luminescence still restricts their application in the field of optical temperature sensing. Herein, gian...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2024-06, Vol.12 (24), p.8977-8986 |
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| container_end_page | 8986 |
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| container_issue | 24 |
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| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
| container_volume | 12 |
| creator | Wang, Xufang Zhang, Ping Xiao, Xianglong Ruoshan Lei Huang, Lihui Xu, Shiqing Zhao, Shilong Wang, Xiuli |
| description | Although negative thermal expansion (NTE) materials provide a new strategy to overcome the thermal-quenching phenomenon among rare earth doped luminescent materials, the overall weak upconversion luminescence still restricts their application in the field of optical temperature sensing. Herein, giant enhancement of anti-quenching upconversion luminescence is achieved in the NTE Sc2W3O12:Er3+/Yb3+ phosphors by (KMg)3+ impurity doping, and the phosphors are used for the construction of an all-fiber temperature sensing (AFTS) system. Compared to the upconversion luminescence of the Sc2W3O12:Er3+/Yb3+ phosphors at room temperature, the synergistic effect of impurity doping and NTE characterstics results in a 6000-fold enhancement of the upconversion luminescence of the (KMg)3+ doped Sc2W3O12:Er3+/Yb3+ phosphors at 573 K. A single-point tip temperature sensor was constructed based on the fluorescence luminescence intensity ratio (FIR) technology and the corresponding self-calibrated curves were obtained with a regression coefficient of 0.9996. The potential application of the constructed AFTS system was demonstrated in the real-time temperature monitoring of a CPU chip and a thermostat bath. |
| doi_str_mv | 10.1039/d4tc01673d |
| format | Article |
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Herein, giant enhancement of anti-quenching upconversion luminescence is achieved in the NTE Sc2W3O12:Er3+/Yb3+ phosphors by (KMg)3+ impurity doping, and the phosphors are used for the construction of an all-fiber temperature sensing (AFTS) system. Compared to the upconversion luminescence of the Sc2W3O12:Er3+/Yb3+ phosphors at room temperature, the synergistic effect of impurity doping and NTE characterstics results in a 6000-fold enhancement of the upconversion luminescence of the (KMg)3+ doped Sc2W3O12:Er3+/Yb3+ phosphors at 573 K. A single-point tip temperature sensor was constructed based on the fluorescence luminescence intensity ratio (FIR) technology and the corresponding self-calibrated curves were obtained with a regression coefficient of 0.9996. The potential application of the constructed AFTS system was demonstrated in the real-time temperature monitoring of a CPU chip and a thermostat bath.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/d4tc01673d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Doping ; Erbium ; Impurities ; Luminescence ; Phosphors ; Quenching ; Real time ; Regression coefficients ; Room temperature ; Synergistic effect ; Temperature sensors ; Thermal expansion ; Upconversion ; Ytterbium</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2024-06, Vol.12 (24), p.8977-8986</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Wang, Xufang</creatorcontrib><creatorcontrib>Zhang, Ping</creatorcontrib><creatorcontrib>Xiao, Xianglong</creatorcontrib><creatorcontrib>Ruoshan Lei</creatorcontrib><creatorcontrib>Huang, Lihui</creatorcontrib><creatorcontrib>Xu, Shiqing</creatorcontrib><creatorcontrib>Zhao, Shilong</creatorcontrib><creatorcontrib>Wang, Xiuli</creatorcontrib><title>Giant enhancement of anti-quenching upconversion luminescence in Sc2W3O12:Er3+/Yb3+ phosphors for temperature sensing</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>Although negative thermal expansion (NTE) materials provide a new strategy to overcome the thermal-quenching phenomenon among rare earth doped luminescent materials, the overall weak upconversion luminescence still restricts their application in the field of optical temperature sensing. Herein, giant enhancement of anti-quenching upconversion luminescence is achieved in the NTE Sc2W3O12:Er3+/Yb3+ phosphors by (KMg)3+ impurity doping, and the phosphors are used for the construction of an all-fiber temperature sensing (AFTS) system. Compared to the upconversion luminescence of the Sc2W3O12:Er3+/Yb3+ phosphors at room temperature, the synergistic effect of impurity doping and NTE characterstics results in a 6000-fold enhancement of the upconversion luminescence of the (KMg)3+ doped Sc2W3O12:Er3+/Yb3+ phosphors at 573 K. A single-point tip temperature sensor was constructed based on the fluorescence luminescence intensity ratio (FIR) technology and the corresponding self-calibrated curves were obtained with a regression coefficient of 0.9996. The potential application of the constructed AFTS system was demonstrated in the real-time temperature monitoring of a CPU chip and a thermostat bath.</description><subject>Doping</subject><subject>Erbium</subject><subject>Impurities</subject><subject>Luminescence</subject><subject>Phosphors</subject><subject>Quenching</subject><subject>Real time</subject><subject>Regression coefficients</subject><subject>Room temperature</subject><subject>Synergistic effect</subject><subject>Temperature sensors</subject><subject>Thermal expansion</subject><subject>Upconversion</subject><subject>Ytterbium</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo9T9FKAzEQDKJgqX3xCwI-lrPJ7SWX-CalVqHQBxXxqeSSPXulTc7kzu9vQHFhmWEGZmcJueXsnjPQC1cNlnFZg7sgk5IJVtQCqst_XsprMkvpwPIoLpXUEzKuO-MHin5vvMUTZh5amqWu-B7R233nv-jY2-B_MKYueHocT53HZLOJtPP01ZYfsOXlwyrCfPHZwJz2-5DyxkTbEOmApx6jGcaINKFPOfGGXLXmmHD2h1Py_rR6Wz4Xm-36Zfm4KXrOYShQ1AaVcBWUTWN0rl2q2ikjpHYSVQPYtK6VzKJrrTYMeaW5M6YRrnYOHUzJ3W9uH0N-Jw27Qxijzyd3wKRWQlQg4AxLCF_z</recordid><startdate>20240620</startdate><enddate>20240620</enddate><creator>Wang, Xufang</creator><creator>Zhang, Ping</creator><creator>Xiao, Xianglong</creator><creator>Ruoshan Lei</creator><creator>Huang, Lihui</creator><creator>Xu, Shiqing</creator><creator>Zhao, Shilong</creator><creator>Wang, Xiuli</creator><general>Royal Society of Chemistry</general><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20240620</creationdate><title>Giant enhancement of anti-quenching upconversion luminescence in Sc2W3O12:Er3+/Yb3+ phosphors for temperature sensing</title><author>Wang, Xufang ; Zhang, Ping ; Xiao, Xianglong ; Ruoshan Lei ; Huang, Lihui ; Xu, Shiqing ; Zhao, Shilong ; Wang, Xiuli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p113t-e57ae85d432bba9000287d8a569d6e8b3ebfdf60cedfc9a0e1491daab5d7dded3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Doping</topic><topic>Erbium</topic><topic>Impurities</topic><topic>Luminescence</topic><topic>Phosphors</topic><topic>Quenching</topic><topic>Real time</topic><topic>Regression coefficients</topic><topic>Room temperature</topic><topic>Synergistic effect</topic><topic>Temperature sensors</topic><topic>Thermal expansion</topic><topic>Upconversion</topic><topic>Ytterbium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xufang</creatorcontrib><creatorcontrib>Zhang, Ping</creatorcontrib><creatorcontrib>Xiao, Xianglong</creatorcontrib><creatorcontrib>Ruoshan Lei</creatorcontrib><creatorcontrib>Huang, Lihui</creatorcontrib><creatorcontrib>Xu, Shiqing</creatorcontrib><creatorcontrib>Zhao, Shilong</creatorcontrib><creatorcontrib>Wang, Xiuli</creatorcontrib><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xufang</au><au>Zhang, Ping</au><au>Xiao, Xianglong</au><au>Ruoshan Lei</au><au>Huang, Lihui</au><au>Xu, Shiqing</au><au>Zhao, Shilong</au><au>Wang, Xiuli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Giant enhancement of anti-quenching upconversion luminescence in Sc2W3O12:Er3+/Yb3+ phosphors for temperature sensing</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2024-06-20</date><risdate>2024</risdate><volume>12</volume><issue>24</issue><spage>8977</spage><epage>8986</epage><pages>8977-8986</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>Although negative thermal expansion (NTE) materials provide a new strategy to overcome the thermal-quenching phenomenon among rare earth doped luminescent materials, the overall weak upconversion luminescence still restricts their application in the field of optical temperature sensing. Herein, giant enhancement of anti-quenching upconversion luminescence is achieved in the NTE Sc2W3O12:Er3+/Yb3+ phosphors by (KMg)3+ impurity doping, and the phosphors are used for the construction of an all-fiber temperature sensing (AFTS) system. Compared to the upconversion luminescence of the Sc2W3O12:Er3+/Yb3+ phosphors at room temperature, the synergistic effect of impurity doping and NTE characterstics results in a 6000-fold enhancement of the upconversion luminescence of the (KMg)3+ doped Sc2W3O12:Er3+/Yb3+ phosphors at 573 K. A single-point tip temperature sensor was constructed based on the fluorescence luminescence intensity ratio (FIR) technology and the corresponding self-calibrated curves were obtained with a regression coefficient of 0.9996. The potential application of the constructed AFTS system was demonstrated in the real-time temperature monitoring of a CPU chip and a thermostat bath.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4tc01673d</doi><tpages>10</tpages></addata></record> |
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| identifier | ISSN: 2050-7526 |
| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2024-06, Vol.12 (24), p.8977-8986 |
| issn | 2050-7526 2050-7534 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Doping Erbium Impurities Luminescence Phosphors Quenching Real time Regression coefficients Room temperature Synergistic effect Temperature sensors Thermal expansion Upconversion Ytterbium |
| title | Giant enhancement of anti-quenching upconversion luminescence in Sc2W3O12:Er3+/Yb3+ phosphors for temperature sensing |
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