Influence of a-site rare earth cation substitution on the structural and magnetic properties of nano-crystalline Ln2CoMnO6 (Ln = Pr, Sm, Gd, Ho, Yb)
A-site rare earth cation substitution in double perovskite (DPOs) Ln2CoMnO6 (Ln=Pr, Sm, Gd, Ho, and Yb) and its effect on their structural and magnetic properties is investigated in this paper. A comprehensive investigation of the structural and magnetic properties is conducted, and a rare earth ion...
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| creator | Bhatti, Ilyas Noor Mansuri, Amantulla Bhatti, Imtiaz Noor |
| description | A-site rare earth cation substitution in double perovskite (DPOs) Ln2CoMnO6 (Ln=Pr, Sm, Gd, Ho, and Yb) and its effect on their structural and magnetic properties is investigated in this paper. A comprehensive investigation of the structural and magnetic properties is conducted, and a rare earth ionic radii dependent comparative analysis is presented. In our observations, we noted a reduction in lattice parameters by approximately 6% along with a decrease in the magnetic phase transition as the ionic radii of A-site cation decreased from Pr to Yb. Specifically, we observed a decline in TC from 172 K for the largest Pr cation (1.13 Å) to 48 K for the smallest Yb cation (0.99 Å) in our study. These findings demonstrate the significant influence of rare earth cation substitution on the physical properties of the DOPs. |
| doi_str_mv | 10.1063/5.0216139 |
| format | Conference Proceeding |
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A comprehensive investigation of the structural and magnetic properties is conducted, and a rare earth ionic radii dependent comparative analysis is presented. In our observations, we noted a reduction in lattice parameters by approximately 6% along with a decrease in the magnetic phase transition as the ionic radii of A-site cation decreased from Pr to Yb. Specifically, we observed a decline in TC from 172 K for the largest Pr cation (1.13 Å) to 48 K for the smallest Yb cation (0.99 Å) in our study. 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A comprehensive investigation of the structural and magnetic properties is conducted, and a rare earth ionic radii dependent comparative analysis is presented. In our observations, we noted a reduction in lattice parameters by approximately 6% along with a decrease in the magnetic phase transition as the ionic radii of A-site cation decreased from Pr to Yb. Specifically, we observed a decline in TC from 172 K for the largest Pr cation (1.13 Å) to 48 K for the smallest Yb cation (0.99 Å) in our study. These findings demonstrate the significant influence of rare earth cation substitution on the physical properties of the DOPs.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0216139</doi><tpages>4</tpages></addata></record> |
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| ispartof | AIP conference proceedings, 2024, Vol.3122 (1) |
| issn | 0094-243X 1551-7616 |
| language | eng |
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| source | AIP Journals Complete |
| subjects | Cations Earth Gadolinium Lattice parameters Magnetic properties Perovskites Phase transitions Physical properties Praseodymium Substitutes Ytterbium |
| title | Influence of a-site rare earth cation substitution on the structural and magnetic properties of nano-crystalline Ln2CoMnO6 (Ln = Pr, Sm, Gd, Ho, Yb) |
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