Synthesis, optical and electrical conduction mechanisms of Tetrametylammonium-nonachlorodiantimonate semi-conductor
Along with structural and optical studies, the temperature and frequency dependence of the electrical and dielectric properties of the [(CH 3 ) 4 N] 3 Sb 2 Cl 9 compound were investigated and analyzed. Rietveld's refinement of XRPD data confirmed hexagonal symmetry, belonging to the P63/mmc spa...
Gespeichert in:
| Veröffentlicht in: | Indian journal of physics 2024-07, Vol.98 (8), p.2947-2960 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2960 |
|---|---|
| container_issue | 8 |
| container_start_page | 2947 |
| container_title | Indian journal of physics |
| container_volume | 98 |
| creator | Ines, Mbarek Malika, Ben Gzaiel Abderrazek, Oueslati Hajer, Guermazi Mohamed, Gargouri |
| description | Along with structural and optical studies, the temperature and frequency dependence of the electrical and dielectric properties of the [(CH
3
)
4
N]
3
Sb
2
Cl
9
compound were investigated and analyzed. Rietveld's refinement of XRPD data confirmed hexagonal symmetry, belonging to the P63/mmc space group. Optical absorption measurement confirmed the semiconductor characteristic with a band gap around 3.4 eV. The differential scanning calorimetry (DSC) analysis showed an endothermic peak at 435 K upon heating which is ascribed to a second-order phase transition. The Nyquist plots (− Z’’ vs Z’) revealed the contribution of grains and grain boundaries in the electrical study, confirming a non-Debye type relaxation. The ac conductivity measures confirmed the presence of the phase transition around 435 K. The conductivity obeys the Arrhenius law with activation energies of 0.8 eV in regime I and 1.13 eV in regime II. The AC conductivity follows Jonscher’s law, The Correlated Barrier Hopping model (CBH) was developed to elucidate the conduction mechanism.
Graphical abstract |
| doi_str_mv | 10.1007/s12648-023-03060-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3068587321</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3068587321</sourcerecordid><originalsourceid>FETCH-LOGICAL-c270t-78b1150238b8a1b845840ad2c3d2dff63c6edcd74703a8179d873d5715a1f8063</originalsourceid><addsrcrecordid>eNp9UMtOAyEUJUYT6-MHXE3iVvQyzAzM0jS-kiYurGtCgbE0A1RgFv17sW3iztV95Jxz7zkI3RC4JwDsIZG6aziGmmKg0AHuT9AMetbgnjft6b6nmDQtP0cXKW0Aup6wdobSx87ntUk23VVhm62SYyW9rsxoVI77UQWvJ5Vt8JUzai29TS5VYaiWJkfpTN6N0rng7eSwD16q9Rhi0Fb6bMtaZlMl4yw-6oR4hc4GOSZzfayX6PP5aTl_xYv3l7f54wKrmkHGjK8IaYslvuKSrIoP3oDUtaK61sPQUdUZrTRrGFDJCes1Z1S3jLSSDBw6eoluD7rbGL4nk7LYhCn6clKUjHhb4DUpqPqAUjGkFM0gttE6GXeCgPgNVxzCFeUTsQ9X9IVED6RUwP7LxD_pf1g_j9t_kQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3068587321</pqid></control><display><type>article</type><title>Synthesis, optical and electrical conduction mechanisms of Tetrametylammonium-nonachlorodiantimonate semi-conductor</title><source>SpringerLink Journals</source><creator>Ines, Mbarek ; Malika, Ben Gzaiel ; Abderrazek, Oueslati ; Hajer, Guermazi ; Mohamed, Gargouri</creator><creatorcontrib>Ines, Mbarek ; Malika, Ben Gzaiel ; Abderrazek, Oueslati ; Hajer, Guermazi ; Mohamed, Gargouri</creatorcontrib><description>Along with structural and optical studies, the temperature and frequency dependence of the electrical and dielectric properties of the [(CH
3
)
4
N]
3
Sb
2
Cl
9
compound were investigated and analyzed. Rietveld's refinement of XRPD data confirmed hexagonal symmetry, belonging to the P63/mmc space group. Optical absorption measurement confirmed the semiconductor characteristic with a band gap around 3.4 eV. The differential scanning calorimetry (DSC) analysis showed an endothermic peak at 435 K upon heating which is ascribed to a second-order phase transition. The Nyquist plots (− Z’’ vs Z’) revealed the contribution of grains and grain boundaries in the electrical study, confirming a non-Debye type relaxation. The ac conductivity measures confirmed the presence of the phase transition around 435 K. The conductivity obeys the Arrhenius law with activation energies of 0.8 eV in regime I and 1.13 eV in regime II. The AC conductivity follows Jonscher’s law, The Correlated Barrier Hopping model (CBH) was developed to elucidate the conduction mechanism.
Graphical abstract</description><identifier>ISSN: 0973-1458</identifier><identifier>EISSN: 0974-9845</identifier><identifier>DOI: 10.1007/s12648-023-03060-9</identifier><language>eng</language><publisher>New Delhi: Springer India</publisher><subject>Astrophysics and Astroparticles ; Dielectric properties ; Electrical conduction ; Grain boundaries ; Nyquist plots ; Original Paper ; Phase transitions ; Physics ; Physics and Astronomy ; Temperature dependence</subject><ispartof>Indian journal of physics, 2024-07, Vol.98 (8), p.2947-2960</ispartof><rights>Indian Association for the Cultivation of Science 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-78b1150238b8a1b845840ad2c3d2dff63c6edcd74703a8179d873d5715a1f8063</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12648-023-03060-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12648-023-03060-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Ines, Mbarek</creatorcontrib><creatorcontrib>Malika, Ben Gzaiel</creatorcontrib><creatorcontrib>Abderrazek, Oueslati</creatorcontrib><creatorcontrib>Hajer, Guermazi</creatorcontrib><creatorcontrib>Mohamed, Gargouri</creatorcontrib><title>Synthesis, optical and electrical conduction mechanisms of Tetrametylammonium-nonachlorodiantimonate semi-conductor</title><title>Indian journal of physics</title><addtitle>Indian J Phys</addtitle><description>Along with structural and optical studies, the temperature and frequency dependence of the electrical and dielectric properties of the [(CH
3
)
4
N]
3
Sb
2
Cl
9
compound were investigated and analyzed. Rietveld's refinement of XRPD data confirmed hexagonal symmetry, belonging to the P63/mmc space group. Optical absorption measurement confirmed the semiconductor characteristic with a band gap around 3.4 eV. The differential scanning calorimetry (DSC) analysis showed an endothermic peak at 435 K upon heating which is ascribed to a second-order phase transition. The Nyquist plots (− Z’’ vs Z’) revealed the contribution of grains and grain boundaries in the electrical study, confirming a non-Debye type relaxation. The ac conductivity measures confirmed the presence of the phase transition around 435 K. The conductivity obeys the Arrhenius law with activation energies of 0.8 eV in regime I and 1.13 eV in regime II. The AC conductivity follows Jonscher’s law, The Correlated Barrier Hopping model (CBH) was developed to elucidate the conduction mechanism.
Graphical abstract</description><subject>Astrophysics and Astroparticles</subject><subject>Dielectric properties</subject><subject>Electrical conduction</subject><subject>Grain boundaries</subject><subject>Nyquist plots</subject><subject>Original Paper</subject><subject>Phase transitions</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Temperature dependence</subject><issn>0973-1458</issn><issn>0974-9845</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOAyEUJUYT6-MHXE3iVvQyzAzM0jS-kiYurGtCgbE0A1RgFv17sW3iztV95Jxz7zkI3RC4JwDsIZG6aziGmmKg0AHuT9AMetbgnjft6b6nmDQtP0cXKW0Aup6wdobSx87ntUk23VVhm62SYyW9rsxoVI77UQWvJ5Vt8JUzai29TS5VYaiWJkfpTN6N0rng7eSwD16q9Rhi0Fb6bMtaZlMl4yw-6oR4hc4GOSZzfayX6PP5aTl_xYv3l7f54wKrmkHGjK8IaYslvuKSrIoP3oDUtaK61sPQUdUZrTRrGFDJCes1Z1S3jLSSDBw6eoluD7rbGL4nk7LYhCn6clKUjHhb4DUpqPqAUjGkFM0gttE6GXeCgPgNVxzCFeUTsQ9X9IVED6RUwP7LxD_pf1g_j9t_kQ</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>Ines, Mbarek</creator><creator>Malika, Ben Gzaiel</creator><creator>Abderrazek, Oueslati</creator><creator>Hajer, Guermazi</creator><creator>Mohamed, Gargouri</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20240701</creationdate><title>Synthesis, optical and electrical conduction mechanisms of Tetrametylammonium-nonachlorodiantimonate semi-conductor</title><author>Ines, Mbarek ; Malika, Ben Gzaiel ; Abderrazek, Oueslati ; Hajer, Guermazi ; Mohamed, Gargouri</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-78b1150238b8a1b845840ad2c3d2dff63c6edcd74703a8179d873d5715a1f8063</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Astrophysics and Astroparticles</topic><topic>Dielectric properties</topic><topic>Electrical conduction</topic><topic>Grain boundaries</topic><topic>Nyquist plots</topic><topic>Original Paper</topic><topic>Phase transitions</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Temperature dependence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ines, Mbarek</creatorcontrib><creatorcontrib>Malika, Ben Gzaiel</creatorcontrib><creatorcontrib>Abderrazek, Oueslati</creatorcontrib><creatorcontrib>Hajer, Guermazi</creatorcontrib><creatorcontrib>Mohamed, Gargouri</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Indian journal of physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ines, Mbarek</au><au>Malika, Ben Gzaiel</au><au>Abderrazek, Oueslati</au><au>Hajer, Guermazi</au><au>Mohamed, Gargouri</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, optical and electrical conduction mechanisms of Tetrametylammonium-nonachlorodiantimonate semi-conductor</atitle><jtitle>Indian journal of physics</jtitle><stitle>Indian J Phys</stitle><date>2024-07-01</date><risdate>2024</risdate><volume>98</volume><issue>8</issue><spage>2947</spage><epage>2960</epage><pages>2947-2960</pages><issn>0973-1458</issn><eissn>0974-9845</eissn><abstract>Along with structural and optical studies, the temperature and frequency dependence of the electrical and dielectric properties of the [(CH
3
)
4
N]
3
Sb
2
Cl
9
compound were investigated and analyzed. Rietveld's refinement of XRPD data confirmed hexagonal symmetry, belonging to the P63/mmc space group. Optical absorption measurement confirmed the semiconductor characteristic with a band gap around 3.4 eV. The differential scanning calorimetry (DSC) analysis showed an endothermic peak at 435 K upon heating which is ascribed to a second-order phase transition. The Nyquist plots (− Z’’ vs Z’) revealed the contribution of grains and grain boundaries in the electrical study, confirming a non-Debye type relaxation. The ac conductivity measures confirmed the presence of the phase transition around 435 K. The conductivity obeys the Arrhenius law with activation energies of 0.8 eV in regime I and 1.13 eV in regime II. The AC conductivity follows Jonscher’s law, The Correlated Barrier Hopping model (CBH) was developed to elucidate the conduction mechanism.
Graphical abstract</abstract><cop>New Delhi</cop><pub>Springer India</pub><doi>10.1007/s12648-023-03060-9</doi><tpages>14</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0973-1458 |
| ispartof | Indian journal of physics, 2024-07, Vol.98 (8), p.2947-2960 |
| issn | 0973-1458 0974-9845 |
| language | eng |
| recordid | cdi_proquest_journals_3068587321 |
| source | SpringerLink Journals |
| subjects | Astrophysics and Astroparticles Dielectric properties Electrical conduction Grain boundaries Nyquist plots Original Paper Phase transitions Physics Physics and Astronomy Temperature dependence |
| title | Synthesis, optical and electrical conduction mechanisms of Tetrametylammonium-nonachlorodiantimonate semi-conductor |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T10%3A27%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20optical%20and%20electrical%20conduction%20mechanisms%20of%20Tetrametylammonium-nonachlorodiantimonate%20semi-conductor&rft.jtitle=Indian%20journal%20of%20physics&rft.au=Ines,%20Mbarek&rft.date=2024-07-01&rft.volume=98&rft.issue=8&rft.spage=2947&rft.epage=2960&rft.pages=2947-2960&rft.issn=0973-1458&rft.eissn=0974-9845&rft_id=info:doi/10.1007/s12648-023-03060-9&rft_dat=%3Cproquest_cross%3E3068587321%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3068587321&rft_id=info:pmid/&rfr_iscdi=true |