Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene
An iron-based metal–organic framework, MIL-53(Fe), was synthesized and added as a synergist to high-density polyethylene (HDPE), and its flame-retardant effect with aluminum diethyl hypophosphite (ADP) and aluminum hypophosphite (AHP) in HDPE was investigated to further improve the flame-retardant e...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2024, Vol.149 (10), p.4505-4516 |
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| creator | Liu, Huimin Deng, Lisha Zhao, Ziheng Sun, Xiaoyan Zhou, Ru Shu, Chi-Min Jiang, Juncheng |
| description | An iron-based metal–organic framework, MIL-53(Fe), was synthesized and added as a synergist to high-density polyethylene (HDPE), and its flame-retardant effect with aluminum diethyl hypophosphite (ADP) and aluminum hypophosphite (AHP) in HDPE was investigated to further improve the flame-retardant efficiency. FTIR results showed that the ADP, AHP, and MIL-53(Fe) were successfully incorporated into the HDPE. The LOI of HDPE-3 and HDPE-7 with 0.75 mass% MIL-53(Fe) was 48.9% and 34.8% higher than that of the pure sample. The combustion grades reached V-0 and V-1. HDPE/MIL-53(Fe)/ADP exhibited more superior flame-retardant properties than HDPE/MIL-53(Fe)/AHP. A synergistic effect between ADP and both AHP and MIL-53(Fe) changes the decomposition process of HDPE. In addition, the FGI value of the composites decreased after the addition of MIL-53(Fe). MIL-53(Fe) enhances the thermal stability of HDPE composites, and improves the quality of the char residue. Experimental results show that MIL-53(Fe) can be used as a flame retardant and is a novel material in polymer flame-retardant research. The new synthetic material shown here may contribute to environmental safety. |
| doi_str_mv | 10.1007/s10973-024-13062-2 |
| format | Article |
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FTIR results showed that the ADP, AHP, and MIL-53(Fe) were successfully incorporated into the HDPE. The LOI of HDPE-3 and HDPE-7 with 0.75 mass% MIL-53(Fe) was 48.9% and 34.8% higher than that of the pure sample. The combustion grades reached V-0 and V-1. HDPE/MIL-53(Fe)/ADP exhibited more superior flame-retardant properties than HDPE/MIL-53(Fe)/AHP. A synergistic effect between ADP and both AHP and MIL-53(Fe) changes the decomposition process of HDPE. In addition, the FGI value of the composites decreased after the addition of MIL-53(Fe). MIL-53(Fe) enhances the thermal stability of HDPE composites, and improves the quality of the char residue. Experimental results show that MIL-53(Fe) can be used as a flame retardant and is a novel material in polymer flame-retardant research. The new synthetic material shown here may contribute to environmental safety.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-024-13062-2</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Aluminum ; Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Composite materials ; Flame retardants ; High density polyethylenes ; Inorganic Chemistry ; Iron ; Measurement Science and Instrumentation ; Metal-organic frameworks ; Physical Chemistry ; Polyethylene ; Polymer Sciences ; Synergistic effect ; Thermal stability</subject><ispartof>Journal of thermal analysis and calorimetry, 2024, Vol.149 (10), p.4505-4516</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-a4cb500e0489f38f6704a643f1c46df4034d751b7eb3d747e50487a4d43ed5b23</cites><orcidid>0000-0002-6851-4572</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-024-13062-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-024-13062-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27915,27916,41479,42548,51310</link.rule.ids></links><search><creatorcontrib>Liu, Huimin</creatorcontrib><creatorcontrib>Deng, Lisha</creatorcontrib><creatorcontrib>Zhao, Ziheng</creatorcontrib><creatorcontrib>Sun, Xiaoyan</creatorcontrib><creatorcontrib>Zhou, Ru</creatorcontrib><creatorcontrib>Shu, Chi-Min</creatorcontrib><creatorcontrib>Jiang, Juncheng</creatorcontrib><title>Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>An iron-based metal–organic framework, MIL-53(Fe), was synthesized and added as a synergist to high-density polyethylene (HDPE), and its flame-retardant effect with aluminum diethyl hypophosphite (ADP) and aluminum hypophosphite (AHP) in HDPE was investigated to further improve the flame-retardant efficiency. FTIR results showed that the ADP, AHP, and MIL-53(Fe) were successfully incorporated into the HDPE. The LOI of HDPE-3 and HDPE-7 with 0.75 mass% MIL-53(Fe) was 48.9% and 34.8% higher than that of the pure sample. The combustion grades reached V-0 and V-1. HDPE/MIL-53(Fe)/ADP exhibited more superior flame-retardant properties than HDPE/MIL-53(Fe)/AHP. A synergistic effect between ADP and both AHP and MIL-53(Fe) changes the decomposition process of HDPE. In addition, the FGI value of the composites decreased after the addition of MIL-53(Fe). MIL-53(Fe) enhances the thermal stability of HDPE composites, and improves the quality of the char residue. Experimental results show that MIL-53(Fe) can be used as a flame retardant and is a novel material in polymer flame-retardant research. The new synthetic material shown here may contribute to environmental safety.</description><subject>Aluminum</subject><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composite materials</subject><subject>Flame retardants</subject><subject>High density polyethylenes</subject><subject>Inorganic Chemistry</subject><subject>Iron</subject><subject>Measurement Science and Instrumentation</subject><subject>Metal-organic frameworks</subject><subject>Physical Chemistry</subject><subject>Polyethylene</subject><subject>Polymer Sciences</subject><subject>Synergistic effect</subject><subject>Thermal stability</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kMFq3DAQhk1JoJttXiAnQS_pQe3Iki37GEKSBrbkkpyFbI3W3nqljeQl-NZ3KH3BPknk7kIhhxyEhuH7_4Evyy4YfGUA8ltkUEtOIReUcShzmn_IFqyoKprXeXmSZp7mkhXwMTuLcQMAdQ1skf25sRbbMRJvSR-8o42OaMgWRz38_fXbh7V2fUts0Ft88eEn_XG_ogW_vMUvRDtDdp2P6YV9PCbtkEgSUj4Y7eZiR8YO3-zbaT7Y9euOGnSxHyey88OEYzcN6PBTdmr1EPH8-C-zp9ubx-vvdPVwd399taJtLmGkWrRNAYAgqtryypYShC4Ft6wVpbECuDCyYI3EhhspJBaJlFoYwdEUTc6X2edD7y745z3GUW38Prh0UiWLpRAgeZWo_EC1wccY0Kpd6Lc6TIqBmvWrg36V9Kt_-tVczQ-hmGC3xvC_-p3UKwxaioM</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Liu, Huimin</creator><creator>Deng, Lisha</creator><creator>Zhao, Ziheng</creator><creator>Sun, Xiaoyan</creator><creator>Zhou, Ru</creator><creator>Shu, Chi-Min</creator><creator>Jiang, Juncheng</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6851-4572</orcidid></search><sort><creationdate>2024</creationdate><title>Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene</title><author>Liu, Huimin ; Deng, Lisha ; Zhao, Ziheng ; Sun, Xiaoyan ; Zhou, Ru ; Shu, Chi-Min ; Jiang, Juncheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-a4cb500e0489f38f6704a643f1c46df4034d751b7eb3d747e50487a4d43ed5b23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aluminum</topic><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composite materials</topic><topic>Flame retardants</topic><topic>High density polyethylenes</topic><topic>Inorganic Chemistry</topic><topic>Iron</topic><topic>Measurement Science and Instrumentation</topic><topic>Metal-organic frameworks</topic><topic>Physical Chemistry</topic><topic>Polyethylene</topic><topic>Polymer Sciences</topic><topic>Synergistic effect</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Huimin</creatorcontrib><creatorcontrib>Deng, Lisha</creatorcontrib><creatorcontrib>Zhao, Ziheng</creatorcontrib><creatorcontrib>Sun, Xiaoyan</creatorcontrib><creatorcontrib>Zhou, Ru</creatorcontrib><creatorcontrib>Shu, Chi-Min</creatorcontrib><creatorcontrib>Jiang, Juncheng</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Huimin</au><au>Deng, Lisha</au><au>Zhao, Ziheng</au><au>Sun, Xiaoyan</au><au>Zhou, Ru</au><au>Shu, Chi-Min</au><au>Jiang, Juncheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2024</date><risdate>2024</risdate><volume>149</volume><issue>10</issue><spage>4505</spage><epage>4516</epage><pages>4505-4516</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>An iron-based metal–organic framework, MIL-53(Fe), was synthesized and added as a synergist to high-density polyethylene (HDPE), and its flame-retardant effect with aluminum diethyl hypophosphite (ADP) and aluminum hypophosphite (AHP) in HDPE was investigated to further improve the flame-retardant efficiency. FTIR results showed that the ADP, AHP, and MIL-53(Fe) were successfully incorporated into the HDPE. The LOI of HDPE-3 and HDPE-7 with 0.75 mass% MIL-53(Fe) was 48.9% and 34.8% higher than that of the pure sample. The combustion grades reached V-0 and V-1. HDPE/MIL-53(Fe)/ADP exhibited more superior flame-retardant properties than HDPE/MIL-53(Fe)/AHP. A synergistic effect between ADP and both AHP and MIL-53(Fe) changes the decomposition process of HDPE. In addition, the FGI value of the composites decreased after the addition of MIL-53(Fe). MIL-53(Fe) enhances the thermal stability of HDPE composites, and improves the quality of the char residue. Experimental results show that MIL-53(Fe) can be used as a flame retardant and is a novel material in polymer flame-retardant research. The new synthetic material shown here may contribute to environmental safety.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10973-024-13062-2</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-6851-4572</orcidid></addata></record> |
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| subjects | Aluminum Analytical Chemistry Chemistry Chemistry and Materials Science Composite materials Flame retardants High density polyethylenes Inorganic Chemistry Iron Measurement Science and Instrumentation Metal-organic frameworks Physical Chemistry Polyethylene Polymer Sciences Synergistic effect Thermal stability |
| title | Effects of iron-based metal–organic framework-MIL-53(Fe) and phosphorus-based flame retardants on the flame retardancy of high-density polyethylene |
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