Halogen Promoted Desulfurative Cleavage of Cyclopropylmethyl Thioethers and Amination of the Formed Cyclopropylcarbinyl Cations

Cyclopropylmethyl sulfides react with N‐fluorosulfonimide (NFSI) or molecular iodine, enabling C−S cleavage to generate cyclopropylcarbinyl cations, which evolve through cyclopropane ring‐opening reactions into homoallyl cations suitable to react with nucleophiles present in the reaction media. This...

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Veröffentlicht in:	European journal of organic chemistry 2024-05, Vol.27 (20), p.n/a
Hauptverfasser:	Marín‐Díaz, Pablo, Martínez‐Núñez, Clara, Sanz, Roberto, Suárez‐Pantiga, Samuel
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines carbocations Cations Cleavage Cyclopropane C−S bond cleavage halogen Iodine Nucleophiles Organosulfur compounds
Online-Zugang:	Volltext
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