In Situ Geochemical Evaluation of Retrograde Hydration Effects in the Peri-Siberian Forearc Mantle (Khara-Nur and Alag-Khadny Peridotite Complexes)
In order to assess the geochemical effects of retrograde metamorphic rehydration, fluid metasomatism, and the fluid-mobile elements (FMEs) budget in the case of oceanic and continental subduction, we report the petrography, bulk, and in situ LA-ICP-MS trace-element data for the two poorly studied op...
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| creator | Karimov, Anas A. Gornova, Marina A. Belyaev, Vasiliy A. Skuzovatov, Sergei Yu Medvedev, Alexander Ya Bryanskiy, Nikolay V. |
| description | In order to assess the geochemical effects of retrograde metamorphic rehydration, fluid metasomatism, and the fluid-mobile elements (FMEs) budget in the case of oceanic and continental subduction, we report the petrography, bulk, and in situ LA-ICP-MS trace-element data for the two poorly studied ophiolites in the northern (Khara-Nur, Eastern Sayan, Russia) and central (Alag-Khadny accretionary wedge, SW Mongolia) parts of the peri-Siberian orogenic framing. Both complexes are relics of the ancient oceanic mantle, which was subjected to processes of partial melting, metasomatism, and retrograde metamorphism. Typical mineral assemblages include olivine + orthopyroxene + chlorite + tremolite ± secondary olivine (640–800 °C), olivine + antigorite ± secondary clinopyroxene ( |
| doi_str_mv | 10.3390/min14050457 |
| format | Article |
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Both complexes are relics of the ancient oceanic mantle, which was subjected to processes of partial melting, metasomatism, and retrograde metamorphism. Typical mineral assemblages include olivine + orthopyroxene + chlorite + tremolite ± secondary olivine (640–800 °C), olivine + antigorite ± secondary clinopyroxene (<640 °C), and olivine + chrysotile ± secondary clinopyroxene (<250 °C) and are stable at pressures up to 2 GPa. Hydration and partial serpentinization of mantle peridotites lead to tremolite formation after orthopyroxene, followed by olivine replacement by antigorite. Serpentine-group minerals (antigorite and chrysotile) were distinguished by Raman spectroscopy, and the contents of incompatible elements (mobile and immobile in fluids) in metamorphic minerals (tremolite, antigorite, and chrysotile) were examined in situ by LA-ICP-MS. The behavior of conservative HFSE (Zr, Nb, Ta, and Ti) and—in part—HREE does not distinguish between the two types (oceanic and continental) of subduction environments. Different patterns of FMEs (Cs, Rb, Ba, U, Sb, Pb, Sr, and LREE) enrichment in metaperidotites reflect variations in the slab fluid composition, which was primarily governed by the contrasting nature of subducted lithologies. The affinity of Alag-Khadny to the subduction of a continental margin is recorded by increased FME contents and selective enrichment by some moderately mobile elements, such as U, Th, and LREE, with respect to the oceanic-type subduction environment of Khara-Nur. Distinct patterns of FME enrichment in tremolite and antigorite from two complexes indicate different sequences of fluid-induced replacement, which was controlled by Opx composition. We demonstrate that evaluation of the initial composition of precursor minerals affected by multi-stage melting and melt metasomatism should be considered with care to estimate the differential fluid overprint and associated elemental uptake from subduction fluids.</description><identifier>ISSN: 2075-163X</identifier><identifier>EISSN: 2075-163X</identifier><identifier>DOI: 10.3390/min14050457</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Accretion ; Chlorite ; Chrysotile ; Composition ; Continental margins ; Enrichment ; Evaluation ; Fluids ; Geochemistry ; Geology ; Hydration ; Lithosphere ; Melting ; Metamorphism ; Metamorphism (Geology) ; Mineral assemblages ; Minerals ; Olivine ; Ophiolites ; Orogeny ; Peridotite ; Petrography ; Petrology ; Raman spectroscopy ; Rehydration ; Sediments ; Serpentine ; Serpentinite ; Serpentinization ; Subduction ; Trace elements ; Tremolite ; Zirconium</subject><ispartof>Minerals (Basel), 2024-05, Vol.14 (5), p.457</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c295t-e294bdabe2d2ee1a4443b2b8e103f26b3d9da7be6fac97b398d62c7308c7df833</cites><orcidid>0000-0002-9132-5446 ; 0000-0002-8227-1941 ; 0000-0002-1669-9309 ; 0000-0002-2253-6020</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Karimov, Anas A.</creatorcontrib><creatorcontrib>Gornova, Marina A.</creatorcontrib><creatorcontrib>Belyaev, Vasiliy A.</creatorcontrib><creatorcontrib>Skuzovatov, Sergei Yu</creatorcontrib><creatorcontrib>Medvedev, Alexander Ya</creatorcontrib><creatorcontrib>Bryanskiy, Nikolay V.</creatorcontrib><title>In Situ Geochemical Evaluation of Retrograde Hydration Effects in the Peri-Siberian Forearc Mantle (Khara-Nur and Alag-Khadny Peridotite Complexes)</title><title>Minerals (Basel)</title><description>In order to assess the geochemical effects of retrograde metamorphic rehydration, fluid metasomatism, and the fluid-mobile elements (FMEs) budget in the case of oceanic and continental subduction, we report the petrography, bulk, and in situ LA-ICP-MS trace-element data for the two poorly studied ophiolites in the northern (Khara-Nur, Eastern Sayan, Russia) and central (Alag-Khadny accretionary wedge, SW Mongolia) parts of the peri-Siberian orogenic framing. Both complexes are relics of the ancient oceanic mantle, which was subjected to processes of partial melting, metasomatism, and retrograde metamorphism. Typical mineral assemblages include olivine + orthopyroxene + chlorite + tremolite ± secondary olivine (640–800 °C), olivine + antigorite ± secondary clinopyroxene (<640 °C), and olivine + chrysotile ± secondary clinopyroxene (<250 °C) and are stable at pressures up to 2 GPa. Hydration and partial serpentinization of mantle peridotites lead to tremolite formation after orthopyroxene, followed by olivine replacement by antigorite. Serpentine-group minerals (antigorite and chrysotile) were distinguished by Raman spectroscopy, and the contents of incompatible elements (mobile and immobile in fluids) in metamorphic minerals (tremolite, antigorite, and chrysotile) were examined in situ by LA-ICP-MS. The behavior of conservative HFSE (Zr, Nb, Ta, and Ti) and—in part—HREE does not distinguish between the two types (oceanic and continental) of subduction environments. Different patterns of FMEs (Cs, Rb, Ba, U, Sb, Pb, Sr, and LREE) enrichment in metaperidotites reflect variations in the slab fluid composition, which was primarily governed by the contrasting nature of subducted lithologies. The affinity of Alag-Khadny to the subduction of a continental margin is recorded by increased FME contents and selective enrichment by some moderately mobile elements, such as U, Th, and LREE, with respect to the oceanic-type subduction environment of Khara-Nur. Distinct patterns of FME enrichment in tremolite and antigorite from two complexes indicate different sequences of fluid-induced replacement, which was controlled by Opx composition. We demonstrate that evaluation of the initial composition of precursor minerals affected by multi-stage melting and melt metasomatism should be considered with care to estimate the differential fluid overprint and associated elemental uptake from subduction fluids.</description><subject>Accretion</subject><subject>Chlorite</subject><subject>Chrysotile</subject><subject>Composition</subject><subject>Continental margins</subject><subject>Enrichment</subject><subject>Evaluation</subject><subject>Fluids</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Hydration</subject><subject>Lithosphere</subject><subject>Melting</subject><subject>Metamorphism</subject><subject>Metamorphism (Geology)</subject><subject>Mineral assemblages</subject><subject>Minerals</subject><subject>Olivine</subject><subject>Ophiolites</subject><subject>Orogeny</subject><subject>Peridotite</subject><subject>Petrography</subject><subject>Petrology</subject><subject>Raman 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Ya</au><au>Bryanskiy, Nikolay V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In Situ Geochemical Evaluation of Retrograde Hydration Effects in the Peri-Siberian Forearc Mantle (Khara-Nur and Alag-Khadny Peridotite Complexes)</atitle><jtitle>Minerals (Basel)</jtitle><date>2024-05-01</date><risdate>2024</risdate><volume>14</volume><issue>5</issue><spage>457</spage><pages>457-</pages><issn>2075-163X</issn><eissn>2075-163X</eissn><abstract>In order to assess the geochemical effects of retrograde metamorphic rehydration, fluid metasomatism, and the fluid-mobile elements (FMEs) budget in the case of oceanic and continental subduction, we report the petrography, bulk, and in situ LA-ICP-MS trace-element data for the two poorly studied ophiolites in the northern (Khara-Nur, Eastern Sayan, Russia) and central (Alag-Khadny accretionary wedge, SW Mongolia) parts of the peri-Siberian orogenic framing. Both complexes are relics of the ancient oceanic mantle, which was subjected to processes of partial melting, metasomatism, and retrograde metamorphism. Typical mineral assemblages include olivine + orthopyroxene + chlorite + tremolite ± secondary olivine (640–800 °C), olivine + antigorite ± secondary clinopyroxene (<640 °C), and olivine + chrysotile ± secondary clinopyroxene (<250 °C) and are stable at pressures up to 2 GPa. Hydration and partial serpentinization of mantle peridotites lead to tremolite formation after orthopyroxene, followed by olivine replacement by antigorite. Serpentine-group minerals (antigorite and chrysotile) were distinguished by Raman spectroscopy, and the contents of incompatible elements (mobile and immobile in fluids) in metamorphic minerals (tremolite, antigorite, and chrysotile) were examined in situ by LA-ICP-MS. The behavior of conservative HFSE (Zr, Nb, Ta, and Ti) and—in part—HREE does not distinguish between the two types (oceanic and continental) of subduction environments. Different patterns of FMEs (Cs, Rb, Ba, U, Sb, Pb, Sr, and LREE) enrichment in metaperidotites reflect variations in the slab fluid composition, which was primarily governed by the contrasting nature of subducted lithologies. The affinity of Alag-Khadny to the subduction of a continental margin is recorded by increased FME contents and selective enrichment by some moderately mobile elements, such as U, Th, and LREE, with respect to the oceanic-type subduction environment of Khara-Nur. Distinct patterns of FME enrichment in tremolite and antigorite from two complexes indicate different sequences of fluid-induced replacement, which was controlled by Opx composition. We demonstrate that evaluation of the initial composition of precursor minerals affected by multi-stage melting and melt metasomatism should be considered with care to estimate the differential fluid overprint and associated elemental uptake from subduction fluids.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/min14050457</doi><orcidid>https://orcid.org/0000-0002-9132-5446</orcidid><orcidid>https://orcid.org/0000-0002-8227-1941</orcidid><orcidid>https://orcid.org/0000-0002-1669-9309</orcidid><orcidid>https://orcid.org/0000-0002-2253-6020</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Minerals (Basel), 2024-05, Vol.14 (5), p.457 |
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| subjects | Accretion Chlorite Chrysotile Composition Continental margins Enrichment Evaluation Fluids Geochemistry Geology Hydration Lithosphere Melting Metamorphism Metamorphism (Geology) Mineral assemblages Minerals Olivine Ophiolites Orogeny Peridotite Petrography Petrology Raman spectroscopy Rehydration Sediments Serpentine Serpentinite Serpentinization Subduction Trace elements Tremolite Zirconium |
| title | In Situ Geochemical Evaluation of Retrograde Hydration Effects in the Peri-Siberian Forearc Mantle (Khara-Nur and Alag-Khadny Peridotite Complexes) |
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