Synthetic Studies and Structural Aspects of Dinuclear Sulfur Titanium Compounds

A series of dinuclear sulfur‐bridged titanium derivatives [Ti(η5‐C5Me5)R(μ‐S)]2 (R=NMe2 (1), Ph (2), CH2Ph (3), CH2SiMe3 (4)) has been synthesized from the reaction of [Ti(η5‐C5Me5)Cl(μ‐S)]2 with the corresponding lithium salt or Grignard reagent. Formulation of 1–4 as symmetric dimers has been conf...

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Veröffentlicht in:	European journal of inorganic chemistry 2024-05, Vol.27 (15), p.n/a
Hauptverfasser:	Álvarez‐Ruiz, Elena, González‐Pérez, Juan Ignacio, Hernán‐Gómez, Alberto, Martín, Avelino, Mena, Miguel, Santamaría, Cristina
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes Chemical synthesis Crystallography hydrogenation Lithium mixed-valence compounds Reagents reduction Sulfur sulfur-bridged compounds Titanium Titanium compounds
Online-Zugang:	Volltext
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