Diamidophosphine as a Precursor of the Iminophosphonamidinate Ligand in the Yttrium Complex

Diamidophosphine t BuP(NHMes) 2 (H 2 L) is synthesized by the treatment of t BuPCl 2 with two equivalents of KNHMes (Mes is 2,4,6-Me 3 C 6 H 2 ). The reaction of H 2 L with potassium hydride in THF (THF is tetrahydrofuran) affords the anionic form HL − with the hydrogen atom migrating from nitrogen...

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Veröffentlicht in:	Russian journal of coordination chemistry 2024-03, Vol.50 (3), p.203-210
Hauptverfasser:	Konokhova, A. Yu, Afonin, M. Yu, Sukhikh, T. S., Konchenko, S. N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Hydrogen atoms Inorganic Chemistry Ligands NMR Nuclear magnetic resonance Physical Chemistry Potassium hydrides Tetrahydrofuran X-ray diffraction Yttrium
Online-Zugang:	Volltext
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