Cellulose/polyester bi-layer functional fabric to develop pesticide-resistant comfortable PPE
Wearing appropriate personal protective equipment (PPE) for spraying pesticides is one of the methods to reduce dermal exposure to toxic pesticides. The main issues with such PPEs are comfortability and durable functionality. These issues were addressed by developing a bi-layer fabric treated with f...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2024-06, Vol.81 (9), p.7833-7853 |
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| creator | Younis, Ayesha Sameen, Aima Iftikhar, Fatima Umair, Muhammad Riaz, Shagufta |
| description | Wearing appropriate personal protective equipment (PPE) for spraying pesticides is one of the methods to reduce dermal exposure to toxic pesticides. The main issues with such PPEs are comfortability and durable functionality. These issues were addressed by developing a bi-layer fabric treated with functionalized iron molybdate (Fe
2
(MoO
4
)
3
) nanoparticles (NPs). Three structures of bi-layer fabrics were developed to get the most comfortable fabric one with an upper layer of cotton (1*1 woven) and an underlayer of polyester (3/1 twill weave). The Fe
2
(MoO
4
)
3
NPs were synthesized and functionalized with two silanes, i.e., Octadecyltrimethoxysilane and 1,2 Bis(triethoxysilyl)ethane. Fourier transform-infrared spectroscopy and thermogravimetric analysis were done to confirm the binding of silanes with NPs. Functionalized Fe
2
(MoO
4
)
3
NPs were coated on selected fabric by dip-dry coating, and surface topography was assessed by Scanning Electron Microscopy (SEM). The water contact angle of 151° was exhibited by modified fabric. The photocatalysis of Benzoepin (C
9
H
6
Cl
6
O
3
S) by Fe
2
(MoO
4
)
3
NPs under visible light was 75%. The UPF values obtained were 55 and 50 before and after washing, respectively. The developed superhydrophobic fabric could be efficiently used for durable pesticide-resistant clothing because the pesticide would not be adsorbed/absorbed by the fabric. If absorbed it could be possibly degraded by Fe
2
(MoO
4
)
3
NPs rescuing the wearer from the hazardous effects of pesticides as well as UV rays.
Graphical abstract |
| doi_str_mv | 10.1007/s00289-023-05071-2 |
| format | Article |
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2
(MoO
4
)
3
) nanoparticles (NPs). Three structures of bi-layer fabrics were developed to get the most comfortable fabric one with an upper layer of cotton (1*1 woven) and an underlayer of polyester (3/1 twill weave). The Fe
2
(MoO
4
)
3
NPs were synthesized and functionalized with two silanes, i.e., Octadecyltrimethoxysilane and 1,2 Bis(triethoxysilyl)ethane. Fourier transform-infrared spectroscopy and thermogravimetric analysis were done to confirm the binding of silanes with NPs. Functionalized Fe
2
(MoO
4
)
3
NPs were coated on selected fabric by dip-dry coating, and surface topography was assessed by Scanning Electron Microscopy (SEM). The water contact angle of 151° was exhibited by modified fabric. The photocatalysis of Benzoepin (C
9
H
6
Cl
6
O
3
S) by Fe
2
(MoO
4
)
3
NPs under visible light was 75%. The UPF values obtained were 55 and 50 before and after washing, respectively. The developed superhydrophobic fabric could be efficiently used for durable pesticide-resistant clothing because the pesticide would not be adsorbed/absorbed by the fabric. If absorbed it could be possibly degraded by Fe
2
(MoO
4
)
3
NPs rescuing the wearer from the hazardous effects of pesticides as well as UV rays.
Graphical abstract</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-023-05071-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Bilayers ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Contact angle ; Cotton ; Design ; Ethane ; Fourier transforms ; Hydrophobic surfaces ; Hydrophobicity ; Immersion coating ; Infrared analysis ; Nanoparticles ; Organic Chemistry ; Original Paper ; Personal protective equipment ; Pesticides ; Physical Chemistry ; Polyesters ; Polymer Sciences ; Silanes ; Soft and Granular Matter ; Spraying ; Textiles ; Thermogravimetric analysis</subject><ispartof>Polymer bulletin (Berlin, Germany), 2024-06, Vol.81 (9), p.7833-7853</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c298t-2d3b1b99734eb3b480306d32c26dcd7e44c46c3264e0bb8411e44cee7e4d17af3</cites><orcidid>0000-0003-1213-2281</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-023-05071-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00289-023-05071-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27933,27934,41497,42566,51328</link.rule.ids></links><search><creatorcontrib>Younis, Ayesha</creatorcontrib><creatorcontrib>Sameen, Aima</creatorcontrib><creatorcontrib>Iftikhar, Fatima</creatorcontrib><creatorcontrib>Umair, Muhammad</creatorcontrib><creatorcontrib>Riaz, Shagufta</creatorcontrib><title>Cellulose/polyester bi-layer functional fabric to develop pesticide-resistant comfortable PPE</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>Wearing appropriate personal protective equipment (PPE) for spraying pesticides is one of the methods to reduce dermal exposure to toxic pesticides. The main issues with such PPEs are comfortability and durable functionality. These issues were addressed by developing a bi-layer fabric treated with functionalized iron molybdate (Fe
2
(MoO
4
)
3
) nanoparticles (NPs). Three structures of bi-layer fabrics were developed to get the most comfortable fabric one with an upper layer of cotton (1*1 woven) and an underlayer of polyester (3/1 twill weave). The Fe
2
(MoO
4
)
3
NPs were synthesized and functionalized with two silanes, i.e., Octadecyltrimethoxysilane and 1,2 Bis(triethoxysilyl)ethane. Fourier transform-infrared spectroscopy and thermogravimetric analysis were done to confirm the binding of silanes with NPs. Functionalized Fe
2
(MoO
4
)
3
NPs were coated on selected fabric by dip-dry coating, and surface topography was assessed by Scanning Electron Microscopy (SEM). The water contact angle of 151° was exhibited by modified fabric. The photocatalysis of Benzoepin (C
9
H
6
Cl
6
O
3
S) by Fe
2
(MoO
4
)
3
NPs under visible light was 75%. The UPF values obtained were 55 and 50 before and after washing, respectively. The developed superhydrophobic fabric could be efficiently used for durable pesticide-resistant clothing because the pesticide would not be adsorbed/absorbed by the fabric. If absorbed it could be possibly degraded by Fe
2
(MoO
4
)
3
NPs rescuing the wearer from the hazardous effects of pesticides as well as UV rays.
Graphical abstract</description><subject>Bilayers</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Contact angle</subject><subject>Cotton</subject><subject>Design</subject><subject>Ethane</subject><subject>Fourier transforms</subject><subject>Hydrophobic surfaces</subject><subject>Hydrophobicity</subject><subject>Immersion coating</subject><subject>Infrared analysis</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Personal protective equipment</subject><subject>Pesticides</subject><subject>Physical Chemistry</subject><subject>Polyesters</subject><subject>Polymer Sciences</subject><subject>Silanes</subject><subject>Soft and Granular Matter</subject><subject>Spraying</subject><subject>Textiles</subject><subject>Thermogravimetric analysis</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLxDAUhYMoOI7-AVcF13FuHpO2SxnGBww4C11KaNJb6ZBpatIK8-_NWMGdru7rnMPlI-SawS0DyBcRgBclBS4oLCFnlJ-QGZNCUS5leUpmwHKgUIjynFzEuIM0K8Vm5G2Fzo3OR1z03h0wDhgy01JXHVLTjJ0dWt9VLmsqE1qbDT6r8ROd77M-iVvb1kgDxjYOVTdk1u8bH4bKOMy22_UlOWsqF_Hqp87J6_36ZfVIN88PT6u7DbW8LAbKa2GYKctcSDTCyAIEqFpwy1Vt6xyltFJZwZVEMKaQjB1XiOlSs7xqxJzcTLl98B9j-kvv_BjS21ELWC5Lrgol_1MpJVkiNCd8UtngYwzY6D60-yocNAN9hK0n2DrB1t-wNU8mMZliEnfvGH6j_3B9Aap-gjk</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Younis, Ayesha</creator><creator>Sameen, Aima</creator><creator>Iftikhar, Fatima</creator><creator>Umair, Muhammad</creator><creator>Riaz, Shagufta</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1213-2281</orcidid></search><sort><creationdate>20240601</creationdate><title>Cellulose/polyester bi-layer functional fabric to develop pesticide-resistant comfortable PPE</title><author>Younis, Ayesha ; Sameen, Aima ; Iftikhar, Fatima ; Umair, Muhammad ; Riaz, Shagufta</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c298t-2d3b1b99734eb3b480306d32c26dcd7e44c46c3264e0bb8411e44cee7e4d17af3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Bilayers</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Contact angle</topic><topic>Cotton</topic><topic>Design</topic><topic>Ethane</topic><topic>Fourier transforms</topic><topic>Hydrophobic surfaces</topic><topic>Hydrophobicity</topic><topic>Immersion coating</topic><topic>Infrared analysis</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Personal protective equipment</topic><topic>Pesticides</topic><topic>Physical Chemistry</topic><topic>Polyesters</topic><topic>Polymer Sciences</topic><topic>Silanes</topic><topic>Soft and Granular Matter</topic><topic>Spraying</topic><topic>Textiles</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Younis, Ayesha</creatorcontrib><creatorcontrib>Sameen, Aima</creatorcontrib><creatorcontrib>Iftikhar, Fatima</creatorcontrib><creatorcontrib>Umair, Muhammad</creatorcontrib><creatorcontrib>Riaz, Shagufta</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Younis, Ayesha</au><au>Sameen, Aima</au><au>Iftikhar, Fatima</au><au>Umair, Muhammad</au><au>Riaz, Shagufta</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cellulose/polyester bi-layer functional fabric to develop pesticide-resistant comfortable PPE</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>81</volume><issue>9</issue><spage>7833</spage><epage>7853</epage><pages>7833-7853</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>Wearing appropriate personal protective equipment (PPE) for spraying pesticides is one of the methods to reduce dermal exposure to toxic pesticides. The main issues with such PPEs are comfortability and durable functionality. These issues were addressed by developing a bi-layer fabric treated with functionalized iron molybdate (Fe
2
(MoO
4
)
3
) nanoparticles (NPs). Three structures of bi-layer fabrics were developed to get the most comfortable fabric one with an upper layer of cotton (1*1 woven) and an underlayer of polyester (3/1 twill weave). The Fe
2
(MoO
4
)
3
NPs were synthesized and functionalized with two silanes, i.e., Octadecyltrimethoxysilane and 1,2 Bis(triethoxysilyl)ethane. Fourier transform-infrared spectroscopy and thermogravimetric analysis were done to confirm the binding of silanes with NPs. Functionalized Fe
2
(MoO
4
)
3
NPs were coated on selected fabric by dip-dry coating, and surface topography was assessed by Scanning Electron Microscopy (SEM). The water contact angle of 151° was exhibited by modified fabric. The photocatalysis of Benzoepin (C
9
H
6
Cl
6
O
3
S) by Fe
2
(MoO
4
)
3
NPs under visible light was 75%. The UPF values obtained were 55 and 50 before and after washing, respectively. The developed superhydrophobic fabric could be efficiently used for durable pesticide-resistant clothing because the pesticide would not be adsorbed/absorbed by the fabric. If absorbed it could be possibly degraded by Fe
2
(MoO
4
)
3
NPs rescuing the wearer from the hazardous effects of pesticides as well as UV rays.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-023-05071-2</doi><tpages>21</tpages><orcidid>https://orcid.org/0000-0003-1213-2281</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2024-06, Vol.81 (9), p.7833-7853 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_3055926864 |
| source | SpringerNature Journals |
| subjects | Bilayers Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Contact angle Cotton Design Ethane Fourier transforms Hydrophobic surfaces Hydrophobicity Immersion coating Infrared analysis Nanoparticles Organic Chemistry Original Paper Personal protective equipment Pesticides Physical Chemistry Polyesters Polymer Sciences Silanes Soft and Granular Matter Spraying Textiles Thermogravimetric analysis |
| title | Cellulose/polyester bi-layer functional fabric to develop pesticide-resistant comfortable PPE |
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