Electrospinning and electrospraying of polybutylene succinate/esterified cellulose nanofibril composites
Cellulose nanofibrils (CNF) were esterified using long-chain fatty acid chlorides (octanoyl chloride, lauroyl chloride, and palmitoyl chloride) and composited with a biodegradable polymer, polybutylene succinate (PBS). The composite material was fabricated into nano-scale fibers and films via electr...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2024-06, Vol.81 (8), p.7105-7120 |
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| creator | Kim, Jeong-Ki Bandi, Rajkumar Dadigala, Ramakrishna Han, Song-Yi Van Hai, Le Cho, Seung-Woo Ma, Seo-Young Lee, Da-Young Kwon, Gu-Joong Lee, Seung-Hwan |
| description | Cellulose nanofibrils (CNF) were esterified using long-chain fatty acid chlorides (octanoyl chloride, lauroyl chloride, and palmitoyl chloride) and composited with a biodegradable polymer, polybutylene succinate (PBS). The composite material was fabricated into nano-scale fibers and films via electrospinning and electrospraying processes using chloroform as a solvent. The influence of process conditions, CNF type and CNF amount on morphologies were investigated. The diameter of the electrospun fibers was ranged from 648 to 975 nm and fibers with the lowest diameters were produced at 10% concentration, 15 kV voltage and 30 µL/min flow rate. Further, PBS to CNF ratio of 95/5 and CNF esterified with lauryl chloride produced the best results. Electrospraying was achieved at a concentration of 5% or less and the tensile properties of the resulting electrosprayed films were investigated. The highest increase in tensile strength was observed at a PBS to CNF ratio of 99/1, while the most significant enhancement in elastic modulus occurred at the 95/5 ratio. |
| doi_str_mv | 10.1007/s00289-023-05048-1 |
| format | Article |
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The composite material was fabricated into nano-scale fibers and films via electrospinning and electrospraying processes using chloroform as a solvent. The influence of process conditions, CNF type and CNF amount on morphologies were investigated. The diameter of the electrospun fibers was ranged from 648 to 975 nm and fibers with the lowest diameters were produced at 10% concentration, 15 kV voltage and 30 µL/min flow rate. Further, PBS to CNF ratio of 95/5 and CNF esterified with lauryl chloride produced the best results. Electrospraying was achieved at a concentration of 5% or less and the tensile properties of the resulting electrosprayed films were investigated. The highest increase in tensile strength was observed at a PBS to CNF ratio of 99/1, while the most significant enhancement in elastic modulus occurred at the 95/5 ratio.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-023-05048-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum ; Cellulose ; Cellulose esters ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Chloride ; Chlorides ; Chloroform ; Complex Fluids and Microfluidics ; Composite materials ; Crystal structure ; Electron microscopes ; Electrospinning ; Electrospraying ; Esterification ; Ethanol ; Fatty acids ; Fibers ; Humidity ; Modulus of elasticity ; Morphology ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polybutylenes ; Polymer Sciences ; Polymers ; Soft and Granular Matter ; Tensile properties ; Tensile strength ; Toxicity ; Viscosity</subject><ispartof>Polymer bulletin (Berlin, Germany), 2024-06, Vol.81 (8), p.7105-7120</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c298t-94d0bfc35380622a02776b3dd6b559133de2ffc29826aa0f7ee41d16759226013</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-023-05048-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00289-023-05048-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Kim, Jeong-Ki</creatorcontrib><creatorcontrib>Bandi, Rajkumar</creatorcontrib><creatorcontrib>Dadigala, Ramakrishna</creatorcontrib><creatorcontrib>Han, Song-Yi</creatorcontrib><creatorcontrib>Van Hai, Le</creatorcontrib><creatorcontrib>Cho, Seung-Woo</creatorcontrib><creatorcontrib>Ma, Seo-Young</creatorcontrib><creatorcontrib>Lee, Da-Young</creatorcontrib><creatorcontrib>Kwon, Gu-Joong</creatorcontrib><creatorcontrib>Lee, Seung-Hwan</creatorcontrib><title>Electrospinning and electrospraying of polybutylene succinate/esterified cellulose nanofibril composites</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>Cellulose nanofibrils (CNF) were esterified using long-chain fatty acid chlorides (octanoyl chloride, lauroyl chloride, and palmitoyl chloride) and composited with a biodegradable polymer, polybutylene succinate (PBS). The composite material was fabricated into nano-scale fibers and films via electrospinning and electrospraying processes using chloroform as a solvent. The influence of process conditions, CNF type and CNF amount on morphologies were investigated. The diameter of the electrospun fibers was ranged from 648 to 975 nm and fibers with the lowest diameters were produced at 10% concentration, 15 kV voltage and 30 µL/min flow rate. Further, PBS to CNF ratio of 95/5 and CNF esterified with lauryl chloride produced the best results. Electrospraying was achieved at a concentration of 5% or less and the tensile properties of the resulting electrosprayed films were investigated. The highest increase in tensile strength was observed at a PBS to CNF ratio of 99/1, while the most significant enhancement in elastic modulus occurred at the 95/5 ratio.</description><subject>Aluminum</subject><subject>Cellulose</subject><subject>Cellulose esters</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chloride</subject><subject>Chlorides</subject><subject>Chloroform</subject><subject>Complex Fluids and Microfluidics</subject><subject>Composite materials</subject><subject>Crystal structure</subject><subject>Electron microscopes</subject><subject>Electrospinning</subject><subject>Electrospraying</subject><subject>Esterification</subject><subject>Ethanol</subject><subject>Fatty acids</subject><subject>Fibers</subject><subject>Humidity</subject><subject>Modulus of elasticity</subject><subject>Morphology</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polybutylenes</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Soft and Granular Matter</subject><subject>Tensile properties</subject><subject>Tensile strength</subject><subject>Toxicity</subject><subject>Viscosity</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkM1LxDAQxYMouH78A54KnquTpEmboyx-geBFzyFtJ5qlm9SkPex_b9Yq3vQ0zPDem8ePkAsKVxSgvk4ArFElMF6CgKop6QFZ0YrLklWVOiQroDWU0HB1TE5S2kDepaQr8n47YDfFkEbnvfNvhfF9gT-3aHb7W7DFGIZdO0-7AT0Wae46582E15gmjM467IsOh2EeQsLCGx-sa6Mbii5sx5DchOmMHFkzJDz_nqfk9e72Zf1QPj3fP65vnsqOqWYqVdVDazsueAOSMQOsrmXL-162QijKeY_M2r2WSWPA1ogV7amshWJMAuWn5HLJHWP4mHM_vQlz9Pml5iCEAK4U_KdiIlMVWcUWVZdhpIhWj9FtTdxpCnrPXS_cdeauv7jrfQG-mDK-DA_jb_Qfrk-emIbh</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Kim, Jeong-Ki</creator><creator>Bandi, Rajkumar</creator><creator>Dadigala, Ramakrishna</creator><creator>Han, Song-Yi</creator><creator>Van Hai, Le</creator><creator>Cho, Seung-Woo</creator><creator>Ma, Seo-Young</creator><creator>Lee, Da-Young</creator><creator>Kwon, Gu-Joong</creator><creator>Lee, Seung-Hwan</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240601</creationdate><title>Electrospinning and electrospraying of polybutylene succinate/esterified cellulose nanofibril composites</title><author>Kim, Jeong-Ki ; Bandi, Rajkumar ; Dadigala, Ramakrishna ; Han, Song-Yi ; Van Hai, Le ; Cho, Seung-Woo ; Ma, Seo-Young ; Lee, Da-Young ; Kwon, Gu-Joong ; Lee, Seung-Hwan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c298t-94d0bfc35380622a02776b3dd6b559133de2ffc29826aa0f7ee41d16759226013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aluminum</topic><topic>Cellulose</topic><topic>Cellulose esters</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chloride</topic><topic>Chlorides</topic><topic>Chloroform</topic><topic>Complex Fluids and Microfluidics</topic><topic>Composite materials</topic><topic>Crystal structure</topic><topic>Electron microscopes</topic><topic>Electrospinning</topic><topic>Electrospraying</topic><topic>Esterification</topic><topic>Ethanol</topic><topic>Fatty acids</topic><topic>Fibers</topic><topic>Humidity</topic><topic>Modulus of elasticity</topic><topic>Morphology</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polybutylenes</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Soft and Granular Matter</topic><topic>Tensile properties</topic><topic>Tensile strength</topic><topic>Toxicity</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Jeong-Ki</creatorcontrib><creatorcontrib>Bandi, Rajkumar</creatorcontrib><creatorcontrib>Dadigala, Ramakrishna</creatorcontrib><creatorcontrib>Han, Song-Yi</creatorcontrib><creatorcontrib>Van Hai, Le</creatorcontrib><creatorcontrib>Cho, Seung-Woo</creatorcontrib><creatorcontrib>Ma, Seo-Young</creatorcontrib><creatorcontrib>Lee, Da-Young</creatorcontrib><creatorcontrib>Kwon, Gu-Joong</creatorcontrib><creatorcontrib>Lee, Seung-Hwan</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Jeong-Ki</au><au>Bandi, Rajkumar</au><au>Dadigala, Ramakrishna</au><au>Han, Song-Yi</au><au>Van Hai, Le</au><au>Cho, Seung-Woo</au><au>Ma, Seo-Young</au><au>Lee, Da-Young</au><au>Kwon, Gu-Joong</au><au>Lee, Seung-Hwan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrospinning and electrospraying of polybutylene succinate/esterified cellulose nanofibril composites</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>81</volume><issue>8</issue><spage>7105</spage><epage>7120</epage><pages>7105-7120</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>Cellulose nanofibrils (CNF) were esterified using long-chain fatty acid chlorides (octanoyl chloride, lauroyl chloride, and palmitoyl chloride) and composited with a biodegradable polymer, polybutylene succinate (PBS). The composite material was fabricated into nano-scale fibers and films via electrospinning and electrospraying processes using chloroform as a solvent. The influence of process conditions, CNF type and CNF amount on morphologies were investigated. The diameter of the electrospun fibers was ranged from 648 to 975 nm and fibers with the lowest diameters were produced at 10% concentration, 15 kV voltage and 30 µL/min flow rate. Further, PBS to CNF ratio of 95/5 and CNF esterified with lauryl chloride produced the best results. Electrospraying was achieved at a concentration of 5% or less and the tensile properties of the resulting electrosprayed films were investigated. The highest increase in tensile strength was observed at a PBS to CNF ratio of 99/1, while the most significant enhancement in elastic modulus occurred at the 95/5 ratio.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-023-05048-1</doi><tpages>16</tpages></addata></record> |
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| subjects | Aluminum Cellulose Cellulose esters Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chloride Chlorides Chloroform Complex Fluids and Microfluidics Composite materials Crystal structure Electron microscopes Electrospinning Electrospraying Esterification Ethanol Fatty acids Fibers Humidity Modulus of elasticity Morphology Organic Chemistry Original Paper Physical Chemistry Polybutylenes Polymer Sciences Polymers Soft and Granular Matter Tensile properties Tensile strength Toxicity Viscosity |
| title | Electrospinning and electrospraying of polybutylene succinate/esterified cellulose nanofibril composites |
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