Effect of electrode materials and fabrication methods on resistive switching behavior of poly(3-hexylthiophene-2,5-diyl)-based resistive random access memory

We evaluated a simple and economical manufacturing method to fabricate a nonvolatile (NV) memory device, which is a fully vacuum-free solution-processed organic resistive random access memory (RRAM) device. A resistive switching (RS) layer was formed from poly(3-hexylthiophene-2,5-diyl), and top ele...

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Veröffentlicht in:Journal of the Korean Physical Society 2024-05, Vol.84 (10), p.766-771
Hauptverfasser: Nam, Ha Yeon, Ha, Dong Hyeon, Rahmani, Mehr Khalid, Khan, Sobia Ali, Park, Joong Hyeon, Kang, Moon Hee
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container_issue 10
container_start_page 766
container_title Journal of the Korean Physical Society
container_volume 84
creator Nam, Ha Yeon
Ha, Dong Hyeon
Rahmani, Mehr Khalid
Khan, Sobia Ali
Park, Joong Hyeon
Kang, Moon Hee
description We evaluated a simple and economical manufacturing method to fabricate a nonvolatile (NV) memory device, which is a fully vacuum-free solution-processed organic resistive random access memory (RRAM) device. A resistive switching (RS) layer was formed from poly(3-hexylthiophene-2,5-diyl), and top electrodes were formed from solvent-treated poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) and Ag epoxy. For the comparison, organic RRAM with vacuum-evaporated Ag metal top electrode were also fabricated and evaluated the RS behavior depending on the top electrode materials. All the fully vacuum-free processed RRAM devices exhibited NV and bipolar RS behavior with the best ON/OFF ratio of > 10 3 and set voltage of ~ 1 V while the organic RRAM with vacuum-evaporated Ag electrode had the highest ON/OFF ratio > 10 5 and the lowest set voltage of 0.85 V. Although RS behavior of the fully vacuum-free processed RRAM was slightly inferior to the RRAM with vacuum-evaporated electrode, its inferior performance can be compensated from its merits of simple and low-cost fabrication.
doi_str_mv 10.1007/s40042-024-01050-6
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subjects Electric potential
Electrode materials
Electrodes
Evaporation
Mathematical and Computational Physics
Memory devices
Original Article - Condensed Matter
Particle and Nuclear Physics
Physics
Physics and Astronomy
Production methods
Random access memory
Switching
Theoretical
Voltage
title Effect of electrode materials and fabrication methods on resistive switching behavior of poly(3-hexylthiophene-2,5-diyl)-based resistive random access memory
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