Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites

Hybrid organic-inorganic perovskites (HOIPs) occupy a prominent position in the field of materials chemistry due to their attractive optoelectronic properties. While extensive work has been done on the crystalline materials over the past decades, the newly reported glasses formed from HOIPs open up...

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Veröffentlicht in:Chemical science (Cambridge) 2024-05, Vol.15 (19), p.7198-725
Hauptverfasser: Ye, Chumei, Lampronti, Giulio I, McHugh, Lauren N, Castillo-Blas, Celia, Kono, Ayano, Chen, Celia, Robertson, Georgina P, Nagle-Cocco, Liam A. V, Xu, Weidong, Stranks, Samuel D, Martinez, Valentina, Brekalo, Ivana, Karadeniz, Bahar, U arevi, Krunoslav, Xue, Wenlong, Kolodzeiski, Pascal, Das, Chinmoy, Chater, Philip, Keen, David A, Dutton, Siân E, Bennett, Thomas D
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container_issue 19
container_start_page 7198
container_title Chemical science (Cambridge)
container_volume 15
creator Ye, Chumei
Lampronti, Giulio I
McHugh, Lauren N
Castillo-Blas, Celia
Kono, Ayano
Chen, Celia
Robertson, Georgina P
Nagle-Cocco, Liam A. V
Xu, Weidong
Stranks, Samuel D
Martinez, Valentina
Brekalo, Ivana
Karadeniz, Bahar
U arevi, Krunoslav
Xue, Wenlong
Kolodzeiski, Pascal
Das, Chinmoy
Chater, Philip
Keen, David A
Dutton, Siân E
Bennett, Thomas D
description Hybrid organic-inorganic perovskites (HOIPs) occupy a prominent position in the field of materials chemistry due to their attractive optoelectronic properties. While extensive work has been done on the crystalline materials over the past decades, the newly reported glasses formed from HOIPs open up a new avenue for perovskite research with their unique structures and functionalities. Melt-quenching is the predominant route to glass formation; however, the absence of a stable liquid state prior to thermal decomposition precludes this method for most HOIPs. In this work, we describe the first mechanochemically-induced crystal-glass transformation of HOIPs as a rapid, green and efficient approach for producing glasses. The amorphous phase was formed from the crystalline phase within 10 minutes of ball-milling, and exhibited glass transition behaviour as evidenced by thermal analysis techniques. Time-resolved in situ ball-milling with synchrotron powder diffraction was employed to study the microstructural evolution of amorphisation, which showed that the crystallite size reaches a comminution limit before the amorphisation process is complete, indicating that energy may be further accumulated as crystal defects. Total scattering experiments revealed the limited short-range order of amorphous HOIPs, and their optical properties were studied by ultraviolet-visible (UV-vis) spectroscopy and photoluminescence (PL) spectroscopy. We present the crystal-glass transformation of two-dimensional hybrid organic-inorganic perovskites (HOIPs) via ball-milling.
doi_str_mv 10.1039/d4sc00905c
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subjects Ball milling
Chemistry
Comminution
Crystal defects
Crystallites
Glass formation
Glass transition
Optical properties
Optoelectronics
Perovskites
Photoluminescence
Short range order
Thermal analysis
Thermal decomposition
title Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites
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