Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites
Hybrid organic-inorganic perovskites (HOIPs) occupy a prominent position in the field of materials chemistry due to their attractive optoelectronic properties. While extensive work has been done on the crystalline materials over the past decades, the newly reported glasses formed from HOIPs open up...
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creator | Ye, Chumei Lampronti, Giulio I McHugh, Lauren N Castillo-Blas, Celia Kono, Ayano Chen, Celia Robertson, Georgina P Nagle-Cocco, Liam A. V Xu, Weidong Stranks, Samuel D Martinez, Valentina Brekalo, Ivana Karadeniz, Bahar U arevi, Krunoslav Xue, Wenlong Kolodzeiski, Pascal Das, Chinmoy Chater, Philip Keen, David A Dutton, Siân E Bennett, Thomas D |
description | Hybrid organic-inorganic perovskites (HOIPs) occupy a prominent position in the field of materials chemistry due to their attractive optoelectronic properties. While extensive work has been done on the crystalline materials over the past decades, the newly reported glasses formed from HOIPs open up a new avenue for perovskite research with their unique structures and functionalities. Melt-quenching is the predominant route to glass formation; however, the absence of a stable liquid state prior to thermal decomposition precludes this method for most HOIPs. In this work, we describe the first mechanochemically-induced crystal-glass transformation of HOIPs as a rapid, green and efficient approach for producing glasses. The amorphous phase was formed from the crystalline phase within 10 minutes of ball-milling, and exhibited glass transition behaviour as evidenced by thermal analysis techniques. Time-resolved
in situ
ball-milling with synchrotron powder diffraction was employed to study the microstructural evolution of amorphisation, which showed that the crystallite size reaches a comminution limit before the amorphisation process is complete, indicating that energy may be further accumulated as crystal defects. Total scattering experiments revealed the limited short-range order of amorphous HOIPs, and their optical properties were studied by ultraviolet-visible (UV-vis) spectroscopy and photoluminescence (PL) spectroscopy.
We present the crystal-glass transformation of two-dimensional hybrid organic-inorganic perovskites (HOIPs)
via
ball-milling. |
doi_str_mv | 10.1039/d4sc00905c |
format | Article |
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in situ
ball-milling with synchrotron powder diffraction was employed to study the microstructural evolution of amorphisation, which showed that the crystallite size reaches a comminution limit before the amorphisation process is complete, indicating that energy may be further accumulated as crystal defects. Total scattering experiments revealed the limited short-range order of amorphous HOIPs, and their optical properties were studied by ultraviolet-visible (UV-vis) spectroscopy and photoluminescence (PL) spectroscopy.
We present the crystal-glass transformation of two-dimensional hybrid organic-inorganic perovskites (HOIPs)
via
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in situ
ball-milling with synchrotron powder diffraction was employed to study the microstructural evolution of amorphisation, which showed that the crystallite size reaches a comminution limit before the amorphisation process is complete, indicating that energy may be further accumulated as crystal defects. Total scattering experiments revealed the limited short-range order of amorphous HOIPs, and their optical properties were studied by ultraviolet-visible (UV-vis) spectroscopy and photoluminescence (PL) spectroscopy.
We present the crystal-glass transformation of two-dimensional hybrid organic-inorganic perovskites (HOIPs)
via
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V ; Xu, Weidong ; Stranks, Samuel D ; Martinez, Valentina ; Brekalo, Ivana ; Karadeniz, Bahar ; U arevi, Krunoslav ; Xue, Wenlong ; Kolodzeiski, Pascal ; Das, Chinmoy ; Chater, Philip ; Keen, David A ; Dutton, Siân E ; Bennett, Thomas D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c388t-e36a67b6bb57a1495569de373efc95bea2ec0a41aa27e366e52b5de050d6f6183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Ball milling</topic><topic>Chemistry</topic><topic>Comminution</topic><topic>Crystal defects</topic><topic>Crystallites</topic><topic>Glass formation</topic><topic>Glass transition</topic><topic>Optical properties</topic><topic>Optoelectronics</topic><topic>Perovskites</topic><topic>Photoluminescence</topic><topic>Short range order</topic><topic>Thermal analysis</topic><topic>Thermal decomposition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ye, Chumei</creatorcontrib><creatorcontrib>Lampronti, Giulio I</creatorcontrib><creatorcontrib>McHugh, Lauren N</creatorcontrib><creatorcontrib>Castillo-Blas, Celia</creatorcontrib><creatorcontrib>Kono, Ayano</creatorcontrib><creatorcontrib>Chen, Celia</creatorcontrib><creatorcontrib>Robertson, Georgina P</creatorcontrib><creatorcontrib>Nagle-Cocco, Liam A. 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V</au><au>Xu, Weidong</au><au>Stranks, Samuel D</au><au>Martinez, Valentina</au><au>Brekalo, Ivana</au><au>Karadeniz, Bahar</au><au>U arevi, Krunoslav</au><au>Xue, Wenlong</au><au>Kolodzeiski, Pascal</au><au>Das, Chinmoy</au><au>Chater, Philip</au><au>Keen, David A</au><au>Dutton, Siân E</au><au>Bennett, Thomas D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2024-05-15</date><risdate>2024</risdate><volume>15</volume><issue>19</issue><spage>7198</spage><epage>725</epage><pages>7198-725</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Hybrid organic-inorganic perovskites (HOIPs) occupy a prominent position in the field of materials chemistry due to their attractive optoelectronic properties. While extensive work has been done on the crystalline materials over the past decades, the newly reported glasses formed from HOIPs open up a new avenue for perovskite research with their unique structures and functionalities. Melt-quenching is the predominant route to glass formation; however, the absence of a stable liquid state prior to thermal decomposition precludes this method for most HOIPs. In this work, we describe the first mechanochemically-induced crystal-glass transformation of HOIPs as a rapid, green and efficient approach for producing glasses. The amorphous phase was formed from the crystalline phase within 10 minutes of ball-milling, and exhibited glass transition behaviour as evidenced by thermal analysis techniques. Time-resolved
in situ
ball-milling with synchrotron powder diffraction was employed to study the microstructural evolution of amorphisation, which showed that the crystallite size reaches a comminution limit before the amorphisation process is complete, indicating that energy may be further accumulated as crystal defects. Total scattering experiments revealed the limited short-range order of amorphous HOIPs, and their optical properties were studied by ultraviolet-visible (UV-vis) spectroscopy and photoluminescence (PL) spectroscopy.
We present the crystal-glass transformation of two-dimensional hybrid organic-inorganic perovskites (HOIPs)
via
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subjects | Ball milling Chemistry Comminution Crystal defects Crystallites Glass formation Glass transition Optical properties Optoelectronics Perovskites Photoluminescence Short range order Thermal analysis Thermal decomposition |
title | Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites |
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