Polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode
Zn metal anode suffers from dendrite issues and passive byproducts, which severely plagues the practical application of aqueous Zn metal batteries. Herein, a polyzwitterionic cross-linked double network hydrogel electrolyte composed of physical crosslinking (hyaluronic acid) and chemical crosslinkin...
Gespeichert in:
| Veröffentlicht in: | Nano research 2024-06, Vol.17 (6), p.5278-5287 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5287 |
|---|---|
| container_issue | 6 |
| container_start_page | 5278 |
| container_title | Nano research |
| container_volume | 17 |
| creator | Shi, Mengyu Zhang, Junlong Tang, Guochuan Wang, Ben Wang, Sen Ren, Xiaoxian Li, Guojie Chen, Weihua Liu, Chuntai Shen, Changyu |
| description | Zn metal anode suffers from dendrite issues and passive byproducts, which severely plagues the practical application of aqueous Zn metal batteries. Herein, a polyzwitterionic cross-linked double network hydrogel electrolyte composed of physical crosslinking (hyaluronic acid) and chemical crosslinking (synthetic zwitterionic monomer copolymerized with acrylamide) is introduced to overcome these obstacles. On the one hand, highly hydrophilic physical network provides an energy dissipation channel to buffer stress and builds a H
2
O-poor interface to avoid side reactions. On the other hand, the charged groups (sulfonic and imidazolyl) in chemical crosslinking structure build anion/cation transport channels to boost ions’ kinetics migration and regulate the typical solvent structure [Zn(H
2
O)
6
]
2+
to R-SO
3
−
[Zn(H
2
O)
4
]
2+
, with uniform electric field distribution and significant resistance to dendrites and parasitic reactions. Based on the above functions, the symmetric zinc cell exhibits superior cycle stability for more than 420 h at a high current density of 5 mA·cm
−2
, and Zn∥MnO
2
full cell has a reversible specific capacity of 150 mAh·g
−1
after 1000 cycles at 2 C with this hydrogel electrolyte. Furthermore, the pouch cell delivers impressive flexibility and cyclability for energy-storage applications. |
| doi_str_mv | 10.1007/s12274-024-6525-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3054659827</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3054659827</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-39f58041b335afd7e28df28adaf05534dced55582a538dd5a5ed5d58e9e6178b3</originalsourceid><addsrcrecordid>eNp1kE9PwzAMxSMEEmPwAbhF4hxI0rpNj2jin4QEB7hwidLG7bqVZiSZpvHpyRiIE77Ylt7vWX6EnAt-KTgvr4KQsswZlzkrQAKDAzIRVaUYT3X4OwuZH5OTEBacF1LkakL0sxu2n5s-RvS9G_uGNt6FwIZ-XKKl1q3rAemIceP8ks631rsOB4oDNtEnNCLF0dRJ3tF5381ZiGZHvI3UjM7iKTlqzRDw7KdPyevtzcvsnj0-3T3Mrh9ZIwsVWVa1oHgu6iwD09oSpbKtVMaalgNkuW3QAoCSBjJlLRhIuwWFFRaiVHU2JRd735V3H2sMUS_c2o_ppM445AVUSpZJJfaq7yc9tnrl-3fjt1pwvctR73PUKUe9y1FDYuSeCUk7duj_nP-HvgCxd3eN</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3054659827</pqid></control><display><type>article</type><title>Polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode</title><source>SpringerLink Journals - AutoHoldings</source><creator>Shi, Mengyu ; Zhang, Junlong ; Tang, Guochuan ; Wang, Ben ; Wang, Sen ; Ren, Xiaoxian ; Li, Guojie ; Chen, Weihua ; Liu, Chuntai ; Shen, Changyu</creator><creatorcontrib>Shi, Mengyu ; Zhang, Junlong ; Tang, Guochuan ; Wang, Ben ; Wang, Sen ; Ren, Xiaoxian ; Li, Guojie ; Chen, Weihua ; Liu, Chuntai ; Shen, Changyu</creatorcontrib><description>Zn metal anode suffers from dendrite issues and passive byproducts, which severely plagues the practical application of aqueous Zn metal batteries. Herein, a polyzwitterionic cross-linked double network hydrogel electrolyte composed of physical crosslinking (hyaluronic acid) and chemical crosslinking (synthetic zwitterionic monomer copolymerized with acrylamide) is introduced to overcome these obstacles. On the one hand, highly hydrophilic physical network provides an energy dissipation channel to buffer stress and builds a H
2
O-poor interface to avoid side reactions. On the other hand, the charged groups (sulfonic and imidazolyl) in chemical crosslinking structure build anion/cation transport channels to boost ions’ kinetics migration and regulate the typical solvent structure [Zn(H
2
O)
6
]
2+
to R-SO
3
−
[Zn(H
2
O)
4
]
2+
, with uniform electric field distribution and significant resistance to dendrites and parasitic reactions. Based on the above functions, the symmetric zinc cell exhibits superior cycle stability for more than 420 h at a high current density of 5 mA·cm
−2
, and Zn∥MnO
2
full cell has a reversible specific capacity of 150 mAh·g
−1
after 1000 cycles at 2 C with this hydrogel electrolyte. Furthermore, the pouch cell delivers impressive flexibility and cyclability for energy-storage applications.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-024-6525-5</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Acrylamide ; Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Chemistry and Materials Science ; Condensed Matter Physics ; Copolymerization ; Crosslinking ; Dendrites ; Electric fields ; Electrolytes ; Energy dissipation ; Energy storage ; Hyaluronic acid ; Hydrogels ; Kinetics ; Manganese dioxide ; Materials Science ; Nanotechnology ; Research Article ; Side reactions ; Specific capacity ; Sulfur trioxide ; Zinc</subject><ispartof>Nano research, 2024-06, Vol.17 (6), p.5278-5287</ispartof><rights>Tsinghua University Press 2024</rights><rights>Tsinghua University Press 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-39f58041b335afd7e28df28adaf05534dced55582a538dd5a5ed5d58e9e6178b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-024-6525-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-024-6525-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Shi, Mengyu</creatorcontrib><creatorcontrib>Zhang, Junlong</creatorcontrib><creatorcontrib>Tang, Guochuan</creatorcontrib><creatorcontrib>Wang, Ben</creatorcontrib><creatorcontrib>Wang, Sen</creatorcontrib><creatorcontrib>Ren, Xiaoxian</creatorcontrib><creatorcontrib>Li, Guojie</creatorcontrib><creatorcontrib>Chen, Weihua</creatorcontrib><creatorcontrib>Liu, Chuntai</creatorcontrib><creatorcontrib>Shen, Changyu</creatorcontrib><title>Polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode</title><title>Nano research</title><addtitle>Nano Res</addtitle><description>Zn metal anode suffers from dendrite issues and passive byproducts, which severely plagues the practical application of aqueous Zn metal batteries. Herein, a polyzwitterionic cross-linked double network hydrogel electrolyte composed of physical crosslinking (hyaluronic acid) and chemical crosslinking (synthetic zwitterionic monomer copolymerized with acrylamide) is introduced to overcome these obstacles. On the one hand, highly hydrophilic physical network provides an energy dissipation channel to buffer stress and builds a H
2
O-poor interface to avoid side reactions. On the other hand, the charged groups (sulfonic and imidazolyl) in chemical crosslinking structure build anion/cation transport channels to boost ions’ kinetics migration and regulate the typical solvent structure [Zn(H
2
O)
6
]
2+
to R-SO
3
−
[Zn(H
2
O)
4
]
2+
, with uniform electric field distribution and significant resistance to dendrites and parasitic reactions. Based on the above functions, the symmetric zinc cell exhibits superior cycle stability for more than 420 h at a high current density of 5 mA·cm
−2
, and Zn∥MnO
2
full cell has a reversible specific capacity of 150 mAh·g
−1
after 1000 cycles at 2 C with this hydrogel electrolyte. Furthermore, the pouch cell delivers impressive flexibility and cyclability for energy-storage applications.</description><subject>Acrylamide</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Copolymerization</subject><subject>Crosslinking</subject><subject>Dendrites</subject><subject>Electric fields</subject><subject>Electrolytes</subject><subject>Energy dissipation</subject><subject>Energy storage</subject><subject>Hyaluronic acid</subject><subject>Hydrogels</subject><subject>Kinetics</subject><subject>Manganese dioxide</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Research Article</subject><subject>Side reactions</subject><subject>Specific capacity</subject><subject>Sulfur trioxide</subject><subject>Zinc</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE9PwzAMxSMEEmPwAbhF4hxI0rpNj2jin4QEB7hwidLG7bqVZiSZpvHpyRiIE77Ylt7vWX6EnAt-KTgvr4KQsswZlzkrQAKDAzIRVaUYT3X4OwuZH5OTEBacF1LkakL0sxu2n5s-RvS9G_uGNt6FwIZ-XKKl1q3rAemIceP8ks631rsOB4oDNtEnNCLF0dRJ3tF5381ZiGZHvI3UjM7iKTlqzRDw7KdPyevtzcvsnj0-3T3Mrh9ZIwsVWVa1oHgu6iwD09oSpbKtVMaalgNkuW3QAoCSBjJlLRhIuwWFFRaiVHU2JRd735V3H2sMUS_c2o_ppM445AVUSpZJJfaq7yc9tnrl-3fjt1pwvctR73PUKUe9y1FDYuSeCUk7duj_nP-HvgCxd3eN</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Shi, Mengyu</creator><creator>Zhang, Junlong</creator><creator>Tang, Guochuan</creator><creator>Wang, Ben</creator><creator>Wang, Sen</creator><creator>Ren, Xiaoxian</creator><creator>Li, Guojie</creator><creator>Chen, Weihua</creator><creator>Liu, Chuntai</creator><creator>Shen, Changyu</creator><general>Tsinghua University Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>K9.</scope><scope>L7M</scope><scope>P64</scope></search><sort><creationdate>20240601</creationdate><title>Polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode</title><author>Shi, Mengyu ; Zhang, Junlong ; Tang, Guochuan ; Wang, Ben ; Wang, Sen ; Ren, Xiaoxian ; Li, Guojie ; Chen, Weihua ; Liu, Chuntai ; Shen, Changyu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-39f58041b335afd7e28df28adaf05534dced55582a538dd5a5ed5d58e9e6178b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Acrylamide</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Biomedicine</topic><topic>Biotechnology</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Copolymerization</topic><topic>Crosslinking</topic><topic>Dendrites</topic><topic>Electric fields</topic><topic>Electrolytes</topic><topic>Energy dissipation</topic><topic>Energy storage</topic><topic>Hyaluronic acid</topic><topic>Hydrogels</topic><topic>Kinetics</topic><topic>Manganese dioxide</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Research Article</topic><topic>Side reactions</topic><topic>Specific capacity</topic><topic>Sulfur trioxide</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shi, Mengyu</creatorcontrib><creatorcontrib>Zhang, Junlong</creatorcontrib><creatorcontrib>Tang, Guochuan</creatorcontrib><creatorcontrib>Wang, Ben</creatorcontrib><creatorcontrib>Wang, Sen</creatorcontrib><creatorcontrib>Ren, Xiaoxian</creatorcontrib><creatorcontrib>Li, Guojie</creatorcontrib><creatorcontrib>Chen, Weihua</creatorcontrib><creatorcontrib>Liu, Chuntai</creatorcontrib><creatorcontrib>Shen, Changyu</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Nano research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shi, Mengyu</au><au>Zhang, Junlong</au><au>Tang, Guochuan</au><au>Wang, Ben</au><au>Wang, Sen</au><au>Ren, Xiaoxian</au><au>Li, Guojie</au><au>Chen, Weihua</au><au>Liu, Chuntai</au><au>Shen, Changyu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>17</volume><issue>6</issue><spage>5278</spage><epage>5287</epage><pages>5278-5287</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>Zn metal anode suffers from dendrite issues and passive byproducts, which severely plagues the practical application of aqueous Zn metal batteries. Herein, a polyzwitterionic cross-linked double network hydrogel electrolyte composed of physical crosslinking (hyaluronic acid) and chemical crosslinking (synthetic zwitterionic monomer copolymerized with acrylamide) is introduced to overcome these obstacles. On the one hand, highly hydrophilic physical network provides an energy dissipation channel to buffer stress and builds a H
2
O-poor interface to avoid side reactions. On the other hand, the charged groups (sulfonic and imidazolyl) in chemical crosslinking structure build anion/cation transport channels to boost ions’ kinetics migration and regulate the typical solvent structure [Zn(H
2
O)
6
]
2+
to R-SO
3
−
[Zn(H
2
O)
4
]
2+
, with uniform electric field distribution and significant resistance to dendrites and parasitic reactions. Based on the above functions, the symmetric zinc cell exhibits superior cycle stability for more than 420 h at a high current density of 5 mA·cm
−2
, and Zn∥MnO
2
full cell has a reversible specific capacity of 150 mAh·g
−1
after 1000 cycles at 2 C with this hydrogel electrolyte. Furthermore, the pouch cell delivers impressive flexibility and cyclability for energy-storage applications.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-024-6525-5</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2024-06, Vol.17 (6), p.5278-5287 |
| issn | 1998-0124 1998-0000 |
| language | eng |
| recordid | cdi_proquest_journals_3054659827 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Acrylamide Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Chemistry and Materials Science Condensed Matter Physics Copolymerization Crosslinking Dendrites Electric fields Electrolytes Energy dissipation Energy storage Hyaluronic acid Hydrogels Kinetics Manganese dioxide Materials Science Nanotechnology Research Article Side reactions Specific capacity Sulfur trioxide Zinc |
| title | Polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T01%3A41%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polyzwitterionic%20cross-linked%20double%20network%20hydrogel%20electrolyte%20enabling%20high-stable%20Zn%20anode&rft.jtitle=Nano%20research&rft.au=Shi,%20Mengyu&rft.date=2024-06-01&rft.volume=17&rft.issue=6&rft.spage=5278&rft.epage=5287&rft.pages=5278-5287&rft.issn=1998-0124&rft.eissn=1998-0000&rft_id=info:doi/10.1007/s12274-024-6525-5&rft_dat=%3Cproquest_cross%3E3054659827%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3054659827&rft_id=info:pmid/&rfr_iscdi=true |