Heterostructure Cu3P−Ni2P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia
Electrochemical nitrate reduction reaction (NO 3 RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for el...
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| Veröffentlicht in: | Nano research 2024-06, Vol.17 (6), p.4872-4881 |
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| creator | Jin, Meng Liu, Jiafang Zhang, Xian Zhang, Shengbo Li, Wenyi Sun, Dianding Zhang, Yunxia Wang, Guozhong Zhang, Haimin |
| description | Electrochemical nitrate reduction reaction (NO
3
RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia (NH
3
) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous Cu
3
P−Ni
2
P/CP−
x
for NO
3
RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the Cu
3
P−Ni
2
P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (
R
NH3
) of 1.9 mmol·h
−1
·cm
−2
, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and
in-situ
spectroscopy characterizations uncover that the formed heterointerface in Cu
3
P−Ni
2
P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway. |
| doi_str_mv | 10.1007/s12274-024-6474-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3054659033</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3054659033</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-923b9ac2d69e0dbaaced27ac27631e148981dcee6d1d0b7d0f6989c7bb4452fd3</originalsourceid><addsrcrecordid>eNp1kLFOwzAQhi0EEqXwAGyWmENtx03iEUVAkSroALPl2JfWVZMU2xla8QDMPCJPgqtQMXHLnXz__5_8IXRNyS0lJJ94yljOE8J4kvE47E_QiApRJCTW6XGmjJ-jC-_XhGSM8mKEPmYQwHU-uF6H3gEu-3Tx_fn1bNliUi6wVkFtdj5g5T001QYMbmJ3qgUMG9DBdQZw3Tm8sstVAnVttYVW747bISBYjVsbnAqAQ4dV03StVZforFYbD1e_fYzeHu5fy1kyf3l8Ku_miU5pFhLB0koozUwmgJhKKQ2G5fEhz1IK8RuioEYDZIYaUuWG1JkohM6rivMpq006RjdD7tZ17z34INdd79p4UqZkyrOpIGkaVXRQ6cjDO6jl1tlGuZ2kRB4gywGyjJDlAbLcRw8bPD5q2yW4v-T_TT8_RoPb</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3054659033</pqid></control><display><type>article</type><title>Heterostructure Cu3P−Ni2P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia</title><source>SpringerNature Journals</source><creator>Jin, Meng ; Liu, Jiafang ; Zhang, Xian ; Zhang, Shengbo ; Li, Wenyi ; Sun, Dianding ; Zhang, Yunxia ; Wang, Guozhong ; Zhang, Haimin</creator><creatorcontrib>Jin, Meng ; Liu, Jiafang ; Zhang, Xian ; Zhang, Shengbo ; Li, Wenyi ; Sun, Dianding ; Zhang, Yunxia ; Wang, Guozhong ; Zhang, Haimin</creatorcontrib><description>Electrochemical nitrate reduction reaction (NO
3
RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia (NH
3
) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous Cu
3
P−Ni
2
P/CP−
x
for NO
3
RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the Cu
3
P−Ni
2
P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (
R
NH3
) of 1.9 mmol·h
−1
·cm
−2
, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and
in-situ
spectroscopy characterizations uncover that the formed heterointerface in Cu
3
P−Ni
2
P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-024-6474-z</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Ammonia ; Anion exchange ; Anion exchanging ; Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Catalysts ; Chemical reactors ; Chemical reduction ; Chemistry and Materials Science ; Condensed Matter Physics ; Copper ; Electrocatalysts ; Electrochemistry ; Electrodes ; Energy ; Heterostructures ; Materials Science ; Membranes ; Nanomaterials ; Nanotechnology ; Nickel ; Nitrate reduction ; Nitrates ; Phosphides ; Research Article ; Rotating disks ; Spectroscopy ; Spectrum analysis</subject><ispartof>Nano research, 2024-06, Vol.17 (6), p.4872-4881</ispartof><rights>Tsinghua University Press 2024</rights><rights>Tsinghua University Press 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-923b9ac2d69e0dbaaced27ac27631e148981dcee6d1d0b7d0f6989c7bb4452fd3</citedby><cites>FETCH-LOGICAL-c316t-923b9ac2d69e0dbaaced27ac27631e148981dcee6d1d0b7d0f6989c7bb4452fd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-024-6474-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-024-6474-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27933,27934,41497,42566,51328</link.rule.ids></links><search><creatorcontrib>Jin, Meng</creatorcontrib><creatorcontrib>Liu, Jiafang</creatorcontrib><creatorcontrib>Zhang, Xian</creatorcontrib><creatorcontrib>Zhang, Shengbo</creatorcontrib><creatorcontrib>Li, Wenyi</creatorcontrib><creatorcontrib>Sun, Dianding</creatorcontrib><creatorcontrib>Zhang, Yunxia</creatorcontrib><creatorcontrib>Wang, Guozhong</creatorcontrib><creatorcontrib>Zhang, Haimin</creatorcontrib><title>Heterostructure Cu3P−Ni2P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia</title><title>Nano research</title><addtitle>Nano Res</addtitle><description>Electrochemical nitrate reduction reaction (NO
3
RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia (NH
3
) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous Cu
3
P−Ni
2
P/CP−
x
for NO
3
RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the Cu
3
P−Ni
2
P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (
R
NH3
) of 1.9 mmol·h
−1
·cm
−2
, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and
in-situ
spectroscopy characterizations uncover that the formed heterointerface in Cu
3
P−Ni
2
P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway.</description><subject>Ammonia</subject><subject>Anion exchange</subject><subject>Anion exchanging</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Catalysts</subject><subject>Chemical reactors</subject><subject>Chemical reduction</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Copper</subject><subject>Electrocatalysts</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Energy</subject><subject>Heterostructures</subject><subject>Materials Science</subject><subject>Membranes</subject><subject>Nanomaterials</subject><subject>Nanotechnology</subject><subject>Nickel</subject><subject>Nitrate reduction</subject><subject>Nitrates</subject><subject>Phosphides</subject><subject>Research Article</subject><subject>Rotating disks</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kLFOwzAQhi0EEqXwAGyWmENtx03iEUVAkSroALPl2JfWVZMU2xla8QDMPCJPgqtQMXHLnXz__5_8IXRNyS0lJJ94yljOE8J4kvE47E_QiApRJCTW6XGmjJ-jC-_XhGSM8mKEPmYQwHU-uF6H3gEu-3Tx_fn1bNliUi6wVkFtdj5g5T001QYMbmJ3qgUMG9DBdQZw3Tm8sstVAnVttYVW747bISBYjVsbnAqAQ4dV03StVZforFYbD1e_fYzeHu5fy1kyf3l8Ku_miU5pFhLB0koozUwmgJhKKQ2G5fEhz1IK8RuioEYDZIYaUuWG1JkohM6rivMpq006RjdD7tZ17z34INdd79p4UqZkyrOpIGkaVXRQ6cjDO6jl1tlGuZ2kRB4gywGyjJDlAbLcRw8bPD5q2yW4v-T_TT8_RoPb</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Jin, Meng</creator><creator>Liu, Jiafang</creator><creator>Zhang, Xian</creator><creator>Zhang, Shengbo</creator><creator>Li, Wenyi</creator><creator>Sun, Dianding</creator><creator>Zhang, Yunxia</creator><creator>Wang, Guozhong</creator><creator>Zhang, Haimin</creator><general>Tsinghua University Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>K9.</scope><scope>L7M</scope><scope>P64</scope></search><sort><creationdate>20240601</creationdate><title>Heterostructure Cu3P−Ni2P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia</title><author>Jin, Meng ; Liu, Jiafang ; Zhang, Xian ; Zhang, Shengbo ; Li, Wenyi ; Sun, Dianding ; Zhang, Yunxia ; Wang, Guozhong ; Zhang, Haimin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-923b9ac2d69e0dbaaced27ac27631e148981dcee6d1d0b7d0f6989c7bb4452fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Ammonia</topic><topic>Anion exchange</topic><topic>Anion exchanging</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Biomedicine</topic><topic>Biotechnology</topic><topic>Catalysts</topic><topic>Chemical reactors</topic><topic>Chemical reduction</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Copper</topic><topic>Electrocatalysts</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Energy</topic><topic>Heterostructures</topic><topic>Materials Science</topic><topic>Membranes</topic><topic>Nanomaterials</topic><topic>Nanotechnology</topic><topic>Nickel</topic><topic>Nitrate reduction</topic><topic>Nitrates</topic><topic>Phosphides</topic><topic>Research Article</topic><topic>Rotating disks</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jin, Meng</creatorcontrib><creatorcontrib>Liu, Jiafang</creatorcontrib><creatorcontrib>Zhang, Xian</creatorcontrib><creatorcontrib>Zhang, Shengbo</creatorcontrib><creatorcontrib>Li, Wenyi</creatorcontrib><creatorcontrib>Sun, Dianding</creatorcontrib><creatorcontrib>Zhang, Yunxia</creatorcontrib><creatorcontrib>Wang, Guozhong</creatorcontrib><creatorcontrib>Zhang, Haimin</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Nano research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jin, Meng</au><au>Liu, Jiafang</au><au>Zhang, Xian</au><au>Zhang, Shengbo</au><au>Li, Wenyi</au><au>Sun, Dianding</au><au>Zhang, Yunxia</au><au>Wang, Guozhong</au><au>Zhang, Haimin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heterostructure Cu3P−Ni2P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>17</volume><issue>6</issue><spage>4872</spage><epage>4881</epage><pages>4872-4881</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>Electrochemical nitrate reduction reaction (NO
3
RR) is a promising means for generating the energy carrier ammonia. Herein, we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal method. The resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia (NH
3
) in three-type electrochemical reactors. In detail, the regulation mechanism of the heterogeneous Cu
3
P−Ni
2
P/CP−
x
for NO
3
RR performance was systematically studied through the H-type cell, rotating disk electrode setup, and membrane-electrode-assemblies (MEA) electrolyzer. As a result, the Cu
3
P−Ni
2
P/CP−0.5 displays the practicability in an MEA system with an anion exchange membrane, affording the largest ammonia yield rate (
R
NH3
) of 1.9 mmol·h
−1
·cm
−2
, exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to date. The theoretical calculations and
in-situ
spectroscopy characterizations uncover that the formed heterointerface in Cu
3
P−Ni
2
P/CP is beneficial for promoting nitrate adsorption, activation, and conversion to ammonia through the successive hydrodeoxygenation pathway.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-024-6474-z</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2024-06, Vol.17 (6), p.4872-4881 |
| issn | 1998-0124 1998-0000 |
| language | eng |
| recordid | cdi_proquest_journals_3054659033 |
| source | SpringerNature Journals |
| subjects | Ammonia Anion exchange Anion exchanging Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Catalysts Chemical reactors Chemical reduction Chemistry and Materials Science Condensed Matter Physics Copper Electrocatalysts Electrochemistry Electrodes Energy Heterostructures Materials Science Membranes Nanomaterials Nanotechnology Nickel Nitrate reduction Nitrates Phosphides Research Article Rotating disks Spectroscopy Spectrum analysis |
| title | Heterostructure Cu3P−Ni2P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia |
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