The positive difference effect and anomalous hydrogen evolution on the anodically polarized Mg surface in alkaline NH4+ containing solutions
The difference effect and hydrogen evolution behavior of pure Mg in alkaline NH 4 + containing solutions are systematically investigated. The Mg electrode exhibits a positive difference effect, rather the traditional negative difference effect, with the anomalous hydrogen evolution in the alkaline 0...
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| Veröffentlicht in: | Journal of materials science 2024-05, Vol.59 (19), p.8535-8555 |
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| creator | Liao, Xingpeng Sun, Can Huang, Jialuo Xiao, Bo Ying, Tao Cao, Fuyong |
| description | The difference effect and hydrogen evolution behavior of pure Mg in alkaline NH
4
+
containing solutions are systematically investigated. The Mg electrode exhibits a positive difference effect, rather the traditional negative difference effect, with the anomalous hydrogen evolution in the alkaline 0.1 M (NH
4
)
2
SO
4
, 0.1 M NH
4
HCO
3
and 0.05 M (NH
4
)
2
CO
3
solutions. This is primarily attributed to the corrosion product film dissolution effect of NH
4
+
and the formation of the black corrosion products. The hydrogen evolution kinetics with the difference effects are deduced and explained by the prevailing incomplete film Mg
+
mechanism and enhanced catalytic activity mechanism.
Graphical abstract |
| doi_str_mv | 10.1007/s10853-024-09716-z |
| format | Article |
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4
+
containing solutions are systematically investigated. The Mg electrode exhibits a positive difference effect, rather the traditional negative difference effect, with the anomalous hydrogen evolution in the alkaline 0.1 M (NH
4
)
2
SO
4
, 0.1 M NH
4
HCO
3
and 0.05 M (NH
4
)
2
CO
3
solutions. This is primarily attributed to the corrosion product film dissolution effect of NH
4
+
and the formation of the black corrosion products. The hydrogen evolution kinetics with the difference effects are deduced and explained by the prevailing incomplete film Mg
+
mechanism and enhanced catalytic activity mechanism.
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4
+
containing solutions are systematically investigated. The Mg electrode exhibits a positive difference effect, rather the traditional negative difference effect, with the anomalous hydrogen evolution in the alkaline 0.1 M (NH
4
)
2
SO
4
, 0.1 M NH
4
HCO
3
and 0.05 M (NH
4
)
2
CO
3
solutions. This is primarily attributed to the corrosion product film dissolution effect of NH
4
+
and the formation of the black corrosion products. The hydrogen evolution kinetics with the difference effects are deduced and explained by the prevailing incomplete film Mg
+
mechanism and enhanced catalytic activity mechanism.
Graphical abstract</description><subject>Ammonium sulfate</subject><subject>Anodic polarization</subject><subject>Aqueous solutions</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Corrosion</subject><subject>Corrosion effects</subject><subject>Corrosion products</subject><subject>Crystallography and Scattering Methods</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Engineering</subject><subject>Hydrogen</subject><subject>Hydrogen evolution</subject><subject>Investigations</subject><subject>Materials Science</subject><subject>Metals & Corrosion</subject><subject>Pollutants</subject><subject>Polymer Sciences</subject><subject>Solid Mechanics</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOHDEQRS0UpEyAH8jKEsuoofzo7ullhBKIBGEDa6vGLg-Gxp7Y3Ugz38BHYzJI2UUqq7w495R0Gfsq4EwA9OdFwLJVDUjdwNCLrtkdsIVoe9XoJahPbAEgZSN1Jz6zL6U8AkDbS7Fgr3cPxDephCm8EHfBe8oULXGqPztxjK6-9Ixjmgt_2Lqc1hQ5vaRxnkKKvM5UFZVxweI4bqttxBx25PjNmpc5e6y6EDmOTziGSPz3lf7GbYoThhhiZT5c5ZgdehwLnXzsI3b_88fdxVVzfXv56-L7dWNlD1PjcWWHfkWddRaX1Gqy6AG8tgBIerBOttKjwm5YkRvQLq1ttRfSOlK9GtQRO917Nzn9malM5jHNOdaTRkGrOz1I1VVK7imbUymZvNnk8Ix5awSY99bNvnVTWzd_Wze7GlL7UKlwXFP-p_5P6g25zIpc</recordid><startdate>20240501</startdate><enddate>20240501</enddate><creator>Liao, Xingpeng</creator><creator>Sun, Can</creator><creator>Huang, Jialuo</creator><creator>Xiao, Bo</creator><creator>Ying, Tao</creator><creator>Cao, Fuyong</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-9397-0628</orcidid></search><sort><creationdate>20240501</creationdate><title>The positive difference effect and anomalous hydrogen evolution on the anodically polarized Mg surface in alkaline NH4+ containing solutions</title><author>Liao, Xingpeng ; Sun, Can ; Huang, Jialuo ; Xiao, Bo ; Ying, Tao ; Cao, Fuyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-fabc97be6cdca8e54ecaf00f4c00ae49cd252fa3a69bed9ac8cc54f12cde37393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Ammonium sulfate</topic><topic>Anodic polarization</topic><topic>Aqueous solutions</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Corrosion</topic><topic>Corrosion effects</topic><topic>Corrosion products</topic><topic>Crystallography and Scattering Methods</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Engineering</topic><topic>Hydrogen</topic><topic>Hydrogen evolution</topic><topic>Investigations</topic><topic>Materials Science</topic><topic>Metals & Corrosion</topic><topic>Pollutants</topic><topic>Polymer Sciences</topic><topic>Solid Mechanics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liao, Xingpeng</creatorcontrib><creatorcontrib>Sun, Can</creatorcontrib><creatorcontrib>Huang, Jialuo</creatorcontrib><creatorcontrib>Xiao, Bo</creatorcontrib><creatorcontrib>Ying, Tao</creatorcontrib><creatorcontrib>Cao, Fuyong</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liao, Xingpeng</au><au>Sun, Can</au><au>Huang, Jialuo</au><au>Xiao, Bo</au><au>Ying, Tao</au><au>Cao, Fuyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The positive difference effect and anomalous hydrogen evolution on the anodically polarized Mg surface in alkaline NH4+ containing solutions</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2024-05-01</date><risdate>2024</risdate><volume>59</volume><issue>19</issue><spage>8535</spage><epage>8555</epage><pages>8535-8555</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The difference effect and hydrogen evolution behavior of pure Mg in alkaline NH
4
+
containing solutions are systematically investigated. The Mg electrode exhibits a positive difference effect, rather the traditional negative difference effect, with the anomalous hydrogen evolution in the alkaline 0.1 M (NH
4
)
2
SO
4
, 0.1 M NH
4
HCO
3
and 0.05 M (NH
4
)
2
CO
3
solutions. This is primarily attributed to the corrosion product film dissolution effect of NH
4
+
and the formation of the black corrosion products. The hydrogen evolution kinetics with the difference effects are deduced and explained by the prevailing incomplete film Mg
+
mechanism and enhanced catalytic activity mechanism.
Graphical abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-024-09716-z</doi><tpages>21</tpages><orcidid>https://orcid.org/0000-0001-9397-0628</orcidid></addata></record> |
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| subjects | Ammonium sulfate Anodic polarization Aqueous solutions Catalytic activity Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Corrosion Corrosion effects Corrosion products Crystallography and Scattering Methods Electrodes Electrolytes Engineering Hydrogen Hydrogen evolution Investigations Materials Science Metals & Corrosion Pollutants Polymer Sciences Solid Mechanics |
| title | The positive difference effect and anomalous hydrogen evolution on the anodically polarized Mg surface in alkaline NH4+ containing solutions |
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