Mechanistic Insights into Ru‐catalyzed Alkene Epoxidation with Nitrous Oxide as a Terminal Oxidant

Nitrous oxide (N2O) is a greenhouse gas produced in the manufacture of 6,6‐nylon and nitric acid. While an attractive oxidant that releases only N2 as a by‐product, the kinetic stability of N2O typically requires high temperatures and pressures for activation. This work describes initial kinetics of...

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Veröffentlicht in:	European journal of inorganic chemistry 2024-05, Vol.27 (14), p.n/a
Hauptverfasser:	Timokhin, Vitaliy I., David Grigg, R., Schomaker, Jennifer M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Catalysts Disproportionation Epoxidation Greenhouse gases High temperature kinetics Low concentrations N2O Nitric acid Nitrous oxide oxidation Oxidizing agents Oxygen transfer Substrates
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