Stereodivergent, Kinetically Controlled Isomerization of Terminal Alkenes via Nickel Catalysis

Because internal alkenes are more challenging synthetic targets than terminal alkenes, metal‐catalyzed olefin mono‐transposition (i.e., positional isomerization) approaches have emerged to afford valuable E‐ or Z‐ internal alkenes from their complementary terminal alkene feedstocks. However, the app...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie 2024-05, Vol.136 (21), p.n/a
Hauptverfasser:	Rubel, Camille Z., Ravn, Anne K., Ho, Hang Chi, Yang, Shenghua, Li, Zi‐Qi, Engle, Keary M., Vantourout, Julien C.
Format:	Artikel
Sprache:	eng
Schlagworte:	alkene Alkenes Catalysis Catalysts Isomerization Nickel Protonation Reagents regioselectivity Room temperature Stereochemistry stereoselectivity Substrates Transposition
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!