Non-negligible contribution of high-level volatile sulphur compounds to ozone photochemical formation in an industry zone in the North China Plain
The increasing amount of ozone (O 3 ) pollution in China is attracting extensive scientific attention globally. This study presents direct evidence that high concentrations of volatile sulphur compounds (VSCs) accelerate the photochemical production of O 3 . We analysed three high O 3 cases (Cases I...
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| Veröffentlicht in: | Air quality, atmosphere and health atmosphere and health, 2024-04, Vol.17 (4), p.777-787 |
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| creator | Yang, Xue Hu, Shuhao Zhang, Gen Li, Lingjie Zhao, Shiyang Zhang, Guiqin |
| description | The increasing amount of ozone (O
3
) pollution in China is attracting extensive scientific attention globally. This study presents direct evidence that high concentrations of volatile sulphur compounds (VSCs) accelerate the photochemical production of O
3
. We analysed three high O
3
cases (Cases I, II, and III) in which the O
3
concentrations were high but the compositions of O
3
precursors differed. An analysis of the O
3
precursors and the magnitudes of the associated ROx (ROx = ·OH + ·HO
2
+ ·RO
2
) reactivities amongst three cases revealed that VSCs may play an important role in O
3
production. Case I showed high loadings of VSCs, mainly dimethyl sulphide (DMS), and the simulated diurnal average concentration of radicals and the net O
3
production rate were higher than those in Cases II and III, reflecting the higher photochemical reactivity and oxidation capacity of Case I. Although O
3
was mainly produced from the oxidation of aromatics in all cases, the oxidation of DMS was an important contributor to O
3
formation in Case I (14%) and Case III (25%). The combined analyses indicated the contribution of DMS to O
3
production in industrial areas and suggested the urgent need to measure related VSCs during field campaigns in another atmospheric environment to verify this phenomenon. |
| doi_str_mv | 10.1007/s11869-023-01479-x |
| format | Article |
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3
) pollution in China is attracting extensive scientific attention globally. This study presents direct evidence that high concentrations of volatile sulphur compounds (VSCs) accelerate the photochemical production of O
3
. We analysed three high O
3
cases (Cases I, II, and III) in which the O
3
concentrations were high but the compositions of O
3
precursors differed. An analysis of the O
3
precursors and the magnitudes of the associated ROx (ROx = ·OH + ·HO
2
+ ·RO
2
) reactivities amongst three cases revealed that VSCs may play an important role in O
3
production. Case I showed high loadings of VSCs, mainly dimethyl sulphide (DMS), and the simulated diurnal average concentration of radicals and the net O
3
production rate were higher than those in Cases II and III, reflecting the higher photochemical reactivity and oxidation capacity of Case I. Although O
3
was mainly produced from the oxidation of aromatics in all cases, the oxidation of DMS was an important contributor to O
3
formation in Case I (14%) and Case III (25%). The combined analyses indicated the contribution of DMS to O
3
production in industrial areas and suggested the urgent need to measure related VSCs during field campaigns in another atmospheric environment to verify this phenomenon.</description><identifier>ISSN: 1873-9318</identifier><identifier>EISSN: 1873-9326</identifier><identifier>DOI: 10.1007/s11869-023-01479-x</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Air pollution ; Aromatic compounds ; Atmospheric Protection/Air Quality Control/Air Pollution ; Dimethyl sulfide ; Earth and Environmental Science ; Emissions ; Environment ; Environmental Health ; Health Promotion and Disease Prevention ; Health risks ; Industrial areas ; Oxidation ; Ozone ; Photochemicals ; Precursors ; Sulfides ; Sulfur compounds</subject><ispartof>Air quality, atmosphere and health, 2024-04, Vol.17 (4), p.777-787</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-34f208fb6da50acceb9dd6ec0841e8126f854ece5b77ff92f6e640d88b873a533</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11869-023-01479-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11869-023-01479-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Yang, Xue</creatorcontrib><creatorcontrib>Hu, Shuhao</creatorcontrib><creatorcontrib>Zhang, Gen</creatorcontrib><creatorcontrib>Li, Lingjie</creatorcontrib><creatorcontrib>Zhao, Shiyang</creatorcontrib><creatorcontrib>Zhang, Guiqin</creatorcontrib><title>Non-negligible contribution of high-level volatile sulphur compounds to ozone photochemical formation in an industry zone in the North China Plain</title><title>Air quality, atmosphere and health</title><addtitle>Air Qual Atmos Health</addtitle><description>The increasing amount of ozone (O
3
) pollution in China is attracting extensive scientific attention globally. This study presents direct evidence that high concentrations of volatile sulphur compounds (VSCs) accelerate the photochemical production of O
3
. We analysed three high O
3
cases (Cases I, II, and III) in which the O
3
concentrations were high but the compositions of O
3
precursors differed. An analysis of the O
3
precursors and the magnitudes of the associated ROx (ROx = ·OH + ·HO
2
+ ·RO
2
) reactivities amongst three cases revealed that VSCs may play an important role in O
3
production. Case I showed high loadings of VSCs, mainly dimethyl sulphide (DMS), and the simulated diurnal average concentration of radicals and the net O
3
production rate were higher than those in Cases II and III, reflecting the higher photochemical reactivity and oxidation capacity of Case I. Although O
3
was mainly produced from the oxidation of aromatics in all cases, the oxidation of DMS was an important contributor to O
3
formation in Case I (14%) and Case III (25%). The combined analyses indicated the contribution of DMS to O
3
production in industrial areas and suggested the urgent need to measure related VSCs during field campaigns in another atmospheric environment to verify this phenomenon.</description><subject>Air pollution</subject><subject>Aromatic compounds</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Dimethyl sulfide</subject><subject>Earth and Environmental Science</subject><subject>Emissions</subject><subject>Environment</subject><subject>Environmental Health</subject><subject>Health Promotion and Disease Prevention</subject><subject>Health risks</subject><subject>Industrial areas</subject><subject>Oxidation</subject><subject>Ozone</subject><subject>Photochemicals</subject><subject>Precursors</subject><subject>Sulfides</subject><subject>Sulfur compounds</subject><issn>1873-9318</issn><issn>1873-9326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kMFOHSEUhidNTbTqC7gi6Zr2ADMMs2xu2trEqIu6JgwDdzBcmAJjtI_hE4v3mnbn5nBCvv8_ydc0FwS-EID-ayZE8AEDZRhI2w_48UNzQkTP8MAo__hvJ-K4-ZTzPQCHFvhJ83wdAw5m693Wjd4gHUNJblyLiwFFi2a3nbE3D8ajh-hVcZXJq1_mNVV2t8Q1TBmViOLfGAxa5liins3OaeWRjWmn9k0uIPU6pzWX9IT2bP0rs0HXMZUZbWYXFLr1yoWz5sgqn83523va3P34_ntzia9ufv7afLvCmvZQMGstBWFHPqkOlNZmHKaJGw2iJUYQyq3oWqNNN_a9tQO13PAWJiHGqkJ1jJ02nw-9S4p_VpOLvI9rCvWkZNBRxihwXil6oHSKOSdj5ZLcTqUnSUC-upcH97K6l3v38rGG2CGUKxy2Jv2vfif1AmWsi8g</recordid><startdate>20240401</startdate><enddate>20240401</enddate><creator>Yang, Xue</creator><creator>Hu, Shuhao</creator><creator>Zhang, Gen</creator><creator>Li, Lingjie</creator><creator>Zhao, Shiyang</creator><creator>Zhang, Guiqin</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7T2</scope><scope>7TG</scope><scope>7TV</scope><scope>C1K</scope><scope>K9.</scope><scope>KL.</scope></search><sort><creationdate>20240401</creationdate><title>Non-negligible contribution of high-level volatile sulphur compounds to ozone photochemical formation in an industry zone in the North China Plain</title><author>Yang, Xue ; Hu, Shuhao ; Zhang, Gen ; Li, Lingjie ; Zhao, Shiyang ; Zhang, Guiqin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-34f208fb6da50acceb9dd6ec0841e8126f854ece5b77ff92f6e640d88b873a533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Air pollution</topic><topic>Aromatic compounds</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Dimethyl sulfide</topic><topic>Earth and Environmental Science</topic><topic>Emissions</topic><topic>Environment</topic><topic>Environmental Health</topic><topic>Health Promotion and Disease Prevention</topic><topic>Health risks</topic><topic>Industrial areas</topic><topic>Oxidation</topic><topic>Ozone</topic><topic>Photochemicals</topic><topic>Precursors</topic><topic>Sulfides</topic><topic>Sulfur compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Xue</creatorcontrib><creatorcontrib>Hu, Shuhao</creatorcontrib><creatorcontrib>Zhang, Gen</creatorcontrib><creatorcontrib>Li, Lingjie</creatorcontrib><creatorcontrib>Zhao, Shiyang</creatorcontrib><creatorcontrib>Zhang, Guiqin</creatorcontrib><collection>CrossRef</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Pollution Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><jtitle>Air quality, atmosphere and health</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Xue</au><au>Hu, Shuhao</au><au>Zhang, Gen</au><au>Li, Lingjie</au><au>Zhao, Shiyang</au><au>Zhang, Guiqin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Non-negligible contribution of high-level volatile sulphur compounds to ozone photochemical formation in an industry zone in the North China Plain</atitle><jtitle>Air quality, atmosphere and health</jtitle><stitle>Air Qual Atmos Health</stitle><date>2024-04-01</date><risdate>2024</risdate><volume>17</volume><issue>4</issue><spage>777</spage><epage>787</epage><pages>777-787</pages><issn>1873-9318</issn><eissn>1873-9326</eissn><abstract>The increasing amount of ozone (O
3
) pollution in China is attracting extensive scientific attention globally. This study presents direct evidence that high concentrations of volatile sulphur compounds (VSCs) accelerate the photochemical production of O
3
. We analysed three high O
3
cases (Cases I, II, and III) in which the O
3
concentrations were high but the compositions of O
3
precursors differed. An analysis of the O
3
precursors and the magnitudes of the associated ROx (ROx = ·OH + ·HO
2
+ ·RO
2
) reactivities amongst three cases revealed that VSCs may play an important role in O
3
production. Case I showed high loadings of VSCs, mainly dimethyl sulphide (DMS), and the simulated diurnal average concentration of radicals and the net O
3
production rate were higher than those in Cases II and III, reflecting the higher photochemical reactivity and oxidation capacity of Case I. Although O
3
was mainly produced from the oxidation of aromatics in all cases, the oxidation of DMS was an important contributor to O
3
formation in Case I (14%) and Case III (25%). The combined analyses indicated the contribution of DMS to O
3
production in industrial areas and suggested the urgent need to measure related VSCs during field campaigns in another atmospheric environment to verify this phenomenon.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11869-023-01479-x</doi><tpages>11</tpages></addata></record> |
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| subjects | Air pollution Aromatic compounds Atmospheric Protection/Air Quality Control/Air Pollution Dimethyl sulfide Earth and Environmental Science Emissions Environment Environmental Health Health Promotion and Disease Prevention Health risks Industrial areas Oxidation Ozone Photochemicals Precursors Sulfides Sulfur compounds |
| title | Non-negligible contribution of high-level volatile sulphur compounds to ozone photochemical formation in an industry zone in the North China Plain |
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