Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion
New crystalline pseudo-polymer complex [Au{S 2 CN(CH 2 ) 6 } 2 ] 4 [Ag 5 Cl 9 ] ( I ) was obtained by binding gold(III) with silver(I) hexamethylenedithiocarbamate from an AuCl 3 /2.5 M NaCl solution. Complex I was isolated in a preparative yield and structurally characterized. The X-ray diffraction...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2024, Vol.50 (1), p.21-32 |
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| creator | Korneeva, E. V. Loseva, O. V. Smolentsev, A. I. Ivanov, A. V. |
| description | New crystalline pseudo-polymer complex [Au{S
2
CN(CH
2
)
6
}
2
]
4
[Ag
5
Cl
9
] (
I
) was obtained by binding gold(III) with silver(I) hexamethylenedithiocarbamate from an AuCl
3
/2.5 M NaCl solution. Complex
I
was isolated in a preparative yield and structurally characterized. The X-ray diffraction (XRD) data (CIF file CCDC no. 2205197) show that the isomeric cations of [Au{S
2
CN(CH
2
)
6
}
2
]
+
(
A
: 2
B
:
C
) and complicated pentanuclear anion [Ag
5
Cl
9
]
4–
are the main structural units of the compound. The supramolecular self-organization of the ionic structural units in complex
I
occurs due to multiple secondary interactions Cl···S and Ag···S, hydrogen bonds C–H···Cl, and anagostic interactions C–H···Ag, resulting in the formation of the 3D pseudo-polymer framework. The thermal behavior of complex
I
is studied by simultaneous thermal analysis to find that the thermolysis of the double Au(III)–Ag(I) compound is accompanied by the quantitative regeneration of the bound metals under comparatively mild conditions. |
| doi_str_mv | 10.1134/S1070328423600572 |
| format | Article |
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2
CN(CH
2
)
6
}
2
]
4
[Ag
5
Cl
9
] (
I
) was obtained by binding gold(III) with silver(I) hexamethylenedithiocarbamate from an AuCl
3
/2.5 M NaCl solution. Complex
I
was isolated in a preparative yield and structurally characterized. The X-ray diffraction (XRD) data (CIF file CCDC no. 2205197) show that the isomeric cations of [Au{S
2
CN(CH
2
)
6
}
2
]
+
(
A
: 2
B
:
C
) and complicated pentanuclear anion [Ag
5
Cl
9
]
4–
are the main structural units of the compound. The supramolecular self-organization of the ionic structural units in complex
I
occurs due to multiple secondary interactions Cl···S and Ag···S, hydrogen bonds C–H···Cl, and anagostic interactions C–H···Ag, resulting in the formation of the 3D pseudo-polymer framework. The thermal behavior of complex
I
is studied by simultaneous thermal analysis to find that the thermolysis of the double Au(III)–Ag(I) compound is accompanied by the quantitative regeneration of the bound metals under comparatively mild conditions.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328423600572</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Chemistry ; Chemistry and Materials Science ; Hydrogen bonds ; Inorganic Chemistry ; Physical Chemistry ; Polymers ; Silver ; Thermal analysis ; Thermodynamic properties</subject><ispartof>Russian journal of coordination chemistry, 2024, Vol.50 (1), p.21-32</ispartof><rights>Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 1, pp. 21–32. © Pleiades Publishing, Ltd., 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-c441a5c3ae56b9dcbb5962418e7b4927b598644fd34ba255b7fecd251eac896d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328423600572$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328423600572$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Korneeva, E. V.</creatorcontrib><creatorcontrib>Loseva, O. V.</creatorcontrib><creatorcontrib>Smolentsev, A. I.</creatorcontrib><creatorcontrib>Ivanov, A. V.</creatorcontrib><title>Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>New crystalline pseudo-polymer complex [Au{S
2
CN(CH
2
)
6
}
2
]
4
[Ag
5
Cl
9
] (
I
) was obtained by binding gold(III) with silver(I) hexamethylenedithiocarbamate from an AuCl
3
/2.5 M NaCl solution. Complex
I
was isolated in a preparative yield and structurally characterized. The X-ray diffraction (XRD) data (CIF file CCDC no. 2205197) show that the isomeric cations of [Au{S
2
CN(CH
2
)
6
}
2
]
+
(
A
: 2
B
:
C
) and complicated pentanuclear anion [Ag
5
Cl
9
]
4–
are the main structural units of the compound. The supramolecular self-organization of the ionic structural units in complex
I
occurs due to multiple secondary interactions Cl···S and Ag···S, hydrogen bonds C–H···Cl, and anagostic interactions C–H···Ag, resulting in the formation of the 3D pseudo-polymer framework. The thermal behavior of complex
I
is studied by simultaneous thermal analysis to find that the thermolysis of the double Au(III)–Ag(I) compound is accompanied by the quantitative regeneration of the bound metals under comparatively mild conditions.</description><subject>Anions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Hydrogen bonds</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Silver</subject><subject>Thermal analysis</subject><subject>Thermodynamic properties</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kctKw0AUhoMoWKsP4G7AjYLRueayrPHSglghdSUSJslJG5lk6kxTreKT-XKOVnAhruYM__d_cDiet0_wCSGMn6YEh5jRiFMWYCxCuuH1SIAjnzESbbrZxf5Xvu3tWPuIMXFU3PM-0lW7mIGt7TFKu7mRjVZQdEoalIKq_LGZyrZ-lYtat8dItiWazMA0UqEzmMllrQ3SFXIGdK67XIGLDYB_XjfQWtdx4K2FrtT-rVarBgxKdDNX8ILuB91bSpObw2RIj4J3-sDvB1ORqPjhGzG1rdvpt_kGntFkNQeU1moJ5nB0hAatc-96W5VUFvZ-3r53d3kxSYb-9fhqlAyu_YIG0cIvOCdSFEyCCPK4LPJcxAHlJIIw5zEN3TcKOK9KxnNJhcjDCoqSCgKyiOKgZH3vYO2dG_3UgV1kj7ozbjWbMSwojggLqaPImiqMttZAlbkdGmlWGcHZ142yPzdyHbruWMe2UzC_5v9Ln8VHlAQ</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Korneeva, E. V.</creator><creator>Loseva, O. V.</creator><creator>Smolentsev, A. I.</creator><creator>Ivanov, A. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2024</creationdate><title>Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion</title><author>Korneeva, E. V. ; Loseva, O. V. ; Smolentsev, A. I. ; Ivanov, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-c441a5c3ae56b9dcbb5962418e7b4927b598644fd34ba255b7fecd251eac896d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Anions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Hydrogen bonds</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polymers</topic><topic>Silver</topic><topic>Thermal analysis</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Korneeva, E. V.</creatorcontrib><creatorcontrib>Loseva, O. V.</creatorcontrib><creatorcontrib>Smolentsev, A. I.</creatorcontrib><creatorcontrib>Ivanov, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Korneeva, E. V.</au><au>Loseva, O. V.</au><au>Smolentsev, A. I.</au><au>Ivanov, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2024</date><risdate>2024</risdate><volume>50</volume><issue>1</issue><spage>21</spage><epage>32</epage><pages>21-32</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>New crystalline pseudo-polymer complex [Au{S
2
CN(CH
2
)
6
}
2
]
4
[Ag
5
Cl
9
] (
I
) was obtained by binding gold(III) with silver(I) hexamethylenedithiocarbamate from an AuCl
3
/2.5 M NaCl solution. Complex
I
was isolated in a preparative yield and structurally characterized. The X-ray diffraction (XRD) data (CIF file CCDC no. 2205197) show that the isomeric cations of [Au{S
2
CN(CH
2
)
6
}
2
]
+
(
A
: 2
B
:
C
) and complicated pentanuclear anion [Ag
5
Cl
9
]
4–
are the main structural units of the compound. The supramolecular self-organization of the ionic structural units in complex
I
occurs due to multiple secondary interactions Cl···S and Ag···S, hydrogen bonds C–H···Cl, and anagostic interactions C–H···Ag, resulting in the formation of the 3D pseudo-polymer framework. The thermal behavior of complex
I
is studied by simultaneous thermal analysis to find that the thermolysis of the double Au(III)–Ag(I) compound is accompanied by the quantitative regeneration of the bound metals under comparatively mild conditions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328423600572</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Russian journal of coordination chemistry, 2024, Vol.50 (1), p.21-32 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_proquest_journals_3052081372 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Anions Chemistry Chemistry and Materials Science Hydrogen bonds Inorganic Chemistry Physical Chemistry Polymers Silver Thermal analysis Thermodynamic properties |
| title | Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion |
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