Enhancing anticorrosive performance of epoxy‐based ZnO nanocomposite coatings via 3‐(trimethoxysilyl)propyl methacrylate modification
The influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings was investigated, considering its impact on both modified ZnO nanoparticles (NPs) and epoxy resin matrix. FTIR analysis revealed that TMSPM‐modified epoxy resin (mEP) exhibited...
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| Veröffentlicht in: | Journal of applied polymer science 2024-06, Vol.141 (23), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Dam, Xuan Thang Dao, Phi Hung Nguyen, Anh Hiep Pham, Thi Thu Giang Nguyen, Thi Huong Nguyen, Thuy Chinh Ly, Thi Ngoc Lien Thai, Hoang |
| description | The influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings was investigated, considering its impact on both modified ZnO nanoparticles (NPs) and epoxy resin matrix. FTIR analysis revealed that TMSPM‐modified epoxy resin (mEP) exhibited lower hydroxyl group and epoxy group content compared to the initial epoxy resin (EP). Furthermore, the obtained results demonstrated that epoxy‐based coatings incorporating modified ZnO NPs (m‐ZnO NPs) displayed superior mechanical properties compared to those of the sample filled with the unmodified ZnO NPs (u‐ZnO NPs). However, the mechanical properties of epoxy‐based coatings loaded with m‐ZnO NPs were found to be lower than those of coatings comprising mEP resin and m‐ZnO NPs. The arrangement of anticorrosion performance of coatings followed a similar pattern. SEM analysis of the cross‐cut surface revealed better dispersion of m‐ZnO NPs compared to the u‐ZnO NPs, although small gaps were observed among the m‐ZnO NPs and the epoxy matrix. The SEM images of coatings based on mEP and m‐ZnO NPs indicated a tighter structure. This structural characteristic is considered the main reason for the highest anticorrosion performance observed in the investigated coatings incorporating both mEP and m‐ZnO NPs.
In this study, the influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings are investigated, considering its impact on both modified ZnO nanoparticles (m‐ZnO) and epoxy resin (mEP). Incorporating both mEP and m‐ZnO NPs into epoxy matrix significantly enhance the anticorrosion performance of the coatings for the steel substrate. |
| doi_str_mv | 10.1002/app.55466 |
| format | Article |
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In this study, the influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings are investigated, considering its impact on both modified ZnO nanoparticles (m‐ZnO) and epoxy resin (mEP). Incorporating both mEP and m‐ZnO NPs into epoxy matrix significantly enhance the anticorrosion performance of the coatings for the steel substrate.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.55466</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>3‐(Trimethoxysilyl)propyl methacrylate ; anticorrosion performance ; Coatings ; Corrosion prevention ; Epoxy resins ; epoxy‐based coating ; Hydroxyl groups ; Mechanical properties ; Nanocomposites ; Nanoparticles ; Pattern analysis ; Zinc oxide ; ZnO nanocomposite coating</subject><ispartof>Journal of applied polymer science, 2024-06, Vol.141 (23), p.n/a</ispartof><rights>2024 Wiley Periodicals LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2576-75a952e21c1b1f0caa4cbe6f48d182886342d559c904c7c6bf2863c7a16d178c3</cites><orcidid>0000-0002-3301-6194 ; 0000-0001-8016-3835 ; 0000-0002-2534-1712</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.55466$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.55466$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Dam, Xuan Thang</creatorcontrib><creatorcontrib>Dao, Phi Hung</creatorcontrib><creatorcontrib>Nguyen, Anh Hiep</creatorcontrib><creatorcontrib>Pham, Thi Thu Giang</creatorcontrib><creatorcontrib>Nguyen, Thi Huong</creatorcontrib><creatorcontrib>Nguyen, Thuy Chinh</creatorcontrib><creatorcontrib>Ly, Thi Ngoc Lien</creatorcontrib><creatorcontrib>Thai, Hoang</creatorcontrib><title>Enhancing anticorrosive performance of epoxy‐based ZnO nanocomposite coatings via 3‐(trimethoxysilyl)propyl methacrylate modification</title><title>Journal of applied polymer science</title><description>The influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings was investigated, considering its impact on both modified ZnO nanoparticles (NPs) and epoxy resin matrix. FTIR analysis revealed that TMSPM‐modified epoxy resin (mEP) exhibited lower hydroxyl group and epoxy group content compared to the initial epoxy resin (EP). Furthermore, the obtained results demonstrated that epoxy‐based coatings incorporating modified ZnO NPs (m‐ZnO NPs) displayed superior mechanical properties compared to those of the sample filled with the unmodified ZnO NPs (u‐ZnO NPs). However, the mechanical properties of epoxy‐based coatings loaded with m‐ZnO NPs were found to be lower than those of coatings comprising mEP resin and m‐ZnO NPs. The arrangement of anticorrosion performance of coatings followed a similar pattern. SEM analysis of the cross‐cut surface revealed better dispersion of m‐ZnO NPs compared to the u‐ZnO NPs, although small gaps were observed among the m‐ZnO NPs and the epoxy matrix. The SEM images of coatings based on mEP and m‐ZnO NPs indicated a tighter structure. This structural characteristic is considered the main reason for the highest anticorrosion performance observed in the investigated coatings incorporating both mEP and m‐ZnO NPs.
In this study, the influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings are investigated, considering its impact on both modified ZnO nanoparticles (m‐ZnO) and epoxy resin (mEP). Incorporating both mEP and m‐ZnO NPs into epoxy matrix significantly enhance the anticorrosion performance of the coatings for the steel substrate.</description><subject>3‐(Trimethoxysilyl)propyl methacrylate</subject><subject>anticorrosion performance</subject><subject>Coatings</subject><subject>Corrosion prevention</subject><subject>Epoxy resins</subject><subject>epoxy‐based coating</subject><subject>Hydroxyl groups</subject><subject>Mechanical properties</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Pattern analysis</subject><subject>Zinc oxide</subject><subject>ZnO nanocomposite coating</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAUhS0EEqUw8AaWWGBIazu2k4xVVX6kSu0AC0vkOA51ldjBTgvZWNl4Rp4El7AyXenc79yfA8AlRhOMEJmKtp0wRjk_AiOMsiSinKTHYBR6OEqzjJ2CM--3CGHMEB-Bz4XZCCO1eYHCdFpa56zXewVb5SrrmtBT0FZQtfa9__74KoRXJXw2K2iEsdI2bcA7BaUVXRji4V4LGAfwunO6Ud0m2Lyu-_qmdbbta3jQhHR9LYKrsaWutAxWa87BSSVqry7-6hg83S4e5_fRcnX3MJ8tI0lYwqOEiYwRRbDEBa6QFILKQvGKpiVOSZrymJKSsUxmiMpE8qIiQZOJwLzESSrjMbga5oaDXnfKd_nW7pwJK_MYMUwxoTQJ1M1AyZCHd6rK2_CPcH2OUX5IOg9J579JB3Y6sG-6Vv3_YD5brwfHD87qhUo</recordid><startdate>20240615</startdate><enddate>20240615</enddate><creator>Dam, Xuan Thang</creator><creator>Dao, Phi Hung</creator><creator>Nguyen, Anh Hiep</creator><creator>Pham, Thi Thu Giang</creator><creator>Nguyen, Thi Huong</creator><creator>Nguyen, Thuy Chinh</creator><creator>Ly, Thi Ngoc Lien</creator><creator>Thai, Hoang</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-3301-6194</orcidid><orcidid>https://orcid.org/0000-0001-8016-3835</orcidid><orcidid>https://orcid.org/0000-0002-2534-1712</orcidid></search><sort><creationdate>20240615</creationdate><title>Enhancing anticorrosive performance of epoxy‐based ZnO nanocomposite coatings via 3‐(trimethoxysilyl)propyl methacrylate modification</title><author>Dam, Xuan Thang ; Dao, Phi Hung ; Nguyen, Anh Hiep ; Pham, Thi Thu Giang ; Nguyen, Thi Huong ; Nguyen, Thuy Chinh ; Ly, Thi Ngoc Lien ; Thai, Hoang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2576-75a952e21c1b1f0caa4cbe6f48d182886342d559c904c7c6bf2863c7a16d178c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>3‐(Trimethoxysilyl)propyl methacrylate</topic><topic>anticorrosion performance</topic><topic>Coatings</topic><topic>Corrosion prevention</topic><topic>Epoxy resins</topic><topic>epoxy‐based coating</topic><topic>Hydroxyl groups</topic><topic>Mechanical properties</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Pattern analysis</topic><topic>Zinc oxide</topic><topic>ZnO nanocomposite coating</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dam, Xuan Thang</creatorcontrib><creatorcontrib>Dao, Phi Hung</creatorcontrib><creatorcontrib>Nguyen, Anh Hiep</creatorcontrib><creatorcontrib>Pham, Thi Thu Giang</creatorcontrib><creatorcontrib>Nguyen, Thi Huong</creatorcontrib><creatorcontrib>Nguyen, Thuy Chinh</creatorcontrib><creatorcontrib>Ly, Thi Ngoc Lien</creatorcontrib><creatorcontrib>Thai, Hoang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dam, Xuan Thang</au><au>Dao, Phi Hung</au><au>Nguyen, Anh Hiep</au><au>Pham, Thi Thu Giang</au><au>Nguyen, Thi Huong</au><au>Nguyen, Thuy Chinh</au><au>Ly, Thi Ngoc Lien</au><au>Thai, Hoang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancing anticorrosive performance of epoxy‐based ZnO nanocomposite coatings via 3‐(trimethoxysilyl)propyl methacrylate modification</atitle><jtitle>Journal of applied polymer science</jtitle><date>2024-06-15</date><risdate>2024</risdate><volume>141</volume><issue>23</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>The influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings was investigated, considering its impact on both modified ZnO nanoparticles (NPs) and epoxy resin matrix. FTIR analysis revealed that TMSPM‐modified epoxy resin (mEP) exhibited lower hydroxyl group and epoxy group content compared to the initial epoxy resin (EP). Furthermore, the obtained results demonstrated that epoxy‐based coatings incorporating modified ZnO NPs (m‐ZnO NPs) displayed superior mechanical properties compared to those of the sample filled with the unmodified ZnO NPs (u‐ZnO NPs). However, the mechanical properties of epoxy‐based coatings loaded with m‐ZnO NPs were found to be lower than those of coatings comprising mEP resin and m‐ZnO NPs. The arrangement of anticorrosion performance of coatings followed a similar pattern. SEM analysis of the cross‐cut surface revealed better dispersion of m‐ZnO NPs compared to the u‐ZnO NPs, although small gaps were observed among the m‐ZnO NPs and the epoxy matrix. The SEM images of coatings based on mEP and m‐ZnO NPs indicated a tighter structure. This structural characteristic is considered the main reason for the highest anticorrosion performance observed in the investigated coatings incorporating both mEP and m‐ZnO NPs.
In this study, the influence of 3‐(trimethoxysilyl)propyl methacrylate (TMSPM) on the properties of epoxy‐based ZnO nanocomposite coatings are investigated, considering its impact on both modified ZnO nanoparticles (m‐ZnO) and epoxy resin (mEP). Incorporating both mEP and m‐ZnO NPs into epoxy matrix significantly enhance the anticorrosion performance of the coatings for the steel substrate.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.55466</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-3301-6194</orcidid><orcidid>https://orcid.org/0000-0001-8016-3835</orcidid><orcidid>https://orcid.org/0000-0002-2534-1712</orcidid></addata></record> |
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| subjects | 3‐(Trimethoxysilyl)propyl methacrylate anticorrosion performance Coatings Corrosion prevention Epoxy resins epoxy‐based coating Hydroxyl groups Mechanical properties Nanocomposites Nanoparticles Pattern analysis Zinc oxide ZnO nanocomposite coating |
| title | Enhancing anticorrosive performance of epoxy‐based ZnO nanocomposite coatings via 3‐(trimethoxysilyl)propyl methacrylate modification |
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