Effect of NdCl3 on characteristics of micro-arc oxidation coating formed on TC4 alloy

To study the effect of adding NdCl 3 on the characteristics of micro-arc oxidation coating of TC4 titanium alloy, micro-arc oxidation was performed by adding different concentrations of NdCl 3 to the base electrolyte. The changes in the surface morphology, phase composition, abrasion resistance, cor...

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Veröffentlicht in:Journal of materials science 2024-05, Vol.59 (18), p.7931-7944
Hauptverfasser: Yang, Shaolan, Duan, Yanfei, Wang, Ping, Luo, Xu, Zheng, Youping
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container_end_page 7944
container_issue 18
container_start_page 7931
container_title Journal of materials science
container_volume 59
creator Yang, Shaolan
Duan, Yanfei
Wang, Ping
Luo, Xu
Zheng, Youping
description To study the effect of adding NdCl 3 on the characteristics of micro-arc oxidation coating of TC4 titanium alloy, micro-arc oxidation was performed by adding different concentrations of NdCl 3 to the base electrolyte. The changes in the surface morphology, phase composition, abrasion resistance, corrosion resistance and erosion resistance of the MAO coating after the addition of NdCl 3 were investigated, utilizing SEM, XRD, XPS, multifunctional material surface tester, electrochemical workstation and autoclave testing methods. The results showed that adding an appropriate amount of NdCl 3 can increase the oxidation voltage and improved the surface morphology of the coating, and the main constituent phases of the coating were rutile TiO 2 , anatase TiO 2 and Nd 2 O 3 . When the concentration of 0.06 g L −1 was added, the thickness and hardness of the coating reached the maximum value of 25.1 μm and 540 HV, and the roughness and coefficient of friction reached the minimum value of 1.022 μm and 0.281. In addition, the corrosion current density and the corrosion rate reached the minimum value of 5.028 × 10 –9 A cm −2 and 1.673 × 10 –3  mm a −1 . Therefore, the coating had excellent abrasion and wear resistance. The erosion experiments indicated that the titanium alloy substrate and the corrosion rate of the MAO coating increased with the extension of the erosion time, and the addition of NdCl 3 could effectively improve the erosion resistance of the TC4 titanium alloy substrate.
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The changes in the surface morphology, phase composition, abrasion resistance, corrosion resistance and erosion resistance of the MAO coating after the addition of NdCl 3 were investigated, utilizing SEM, XRD, XPS, multifunctional material surface tester, electrochemical workstation and autoclave testing methods. The results showed that adding an appropriate amount of NdCl 3 can increase the oxidation voltage and improved the surface morphology of the coating, and the main constituent phases of the coating were rutile TiO 2 , anatase TiO 2 and Nd 2 O 3 . When the concentration of 0.06 g L −1 was added, the thickness and hardness of the coating reached the maximum value of 25.1 μm and 540 HV, and the roughness and coefficient of friction reached the minimum value of 1.022 μm and 0.281. In addition, the corrosion current density and the corrosion rate reached the minimum value of 5.028 × 10 –9 A cm −2 and 1.673 × 10 –3  mm a −1 . Therefore, the coating had excellent abrasion and wear resistance. 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The changes in the surface morphology, phase composition, abrasion resistance, corrosion resistance and erosion resistance of the MAO coating after the addition of NdCl 3 were investigated, utilizing SEM, XRD, XPS, multifunctional material surface tester, electrochemical workstation and autoclave testing methods. The results showed that adding an appropriate amount of NdCl 3 can increase the oxidation voltage and improved the surface morphology of the coating, and the main constituent phases of the coating were rutile TiO 2 , anatase TiO 2 and Nd 2 O 3 . When the concentration of 0.06 g L −1 was added, the thickness and hardness of the coating reached the maximum value of 25.1 μm and 540 HV, and the roughness and coefficient of friction reached the minimum value of 1.022 μm and 0.281. In addition, the corrosion current density and the corrosion rate reached the minimum value of 5.028 × 10 –9 A cm −2 and 1.673 × 10 –3  mm a −1 . 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The changes in the surface morphology, phase composition, abrasion resistance, corrosion resistance and erosion resistance of the MAO coating after the addition of NdCl 3 were investigated, utilizing SEM, XRD, XPS, multifunctional material surface tester, electrochemical workstation and autoclave testing methods. The results showed that adding an appropriate amount of NdCl 3 can increase the oxidation voltage and improved the surface morphology of the coating, and the main constituent phases of the coating were rutile TiO 2 , anatase TiO 2 and Nd 2 O 3 . When the concentration of 0.06 g L −1 was added, the thickness and hardness of the coating reached the maximum value of 25.1 μm and 540 HV, and the roughness and coefficient of friction reached the minimum value of 1.022 μm and 0.281. In addition, the corrosion current density and the corrosion rate reached the minimum value of 5.028 × 10 –9 A cm −2 and 1.673 × 10 –3  mm a −1 . Therefore, the coating had excellent abrasion and wear resistance. The erosion experiments indicated that the titanium alloy substrate and the corrosion rate of the MAO coating increased with the extension of the erosion time, and the addition of NdCl 3 could effectively improve the erosion resistance of the TC4 titanium alloy substrate.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-024-09640-2</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-1574-9984</orcidid></addata></record>
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subjects Abrasion resistance
Abrasion resistant alloys
Anatase
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Coating
Coefficient of friction
Corrosion
Corrosion currents
Corrosion rate
Corrosion resistance
Crystallography and Scattering Methods
Erosion resistance
Materials Science
Metals & Corrosion
Morphology
Multifunctional materials
Oxidation
Phase composition
Polymer Sciences
Solid Mechanics
Substrates
Titanium alloys
Titanium base alloys
Titanium dioxide
Wear resistance
X ray photoelectron spectroscopy
title Effect of NdCl3 on characteristics of micro-arc oxidation coating formed on TC4 alloy
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