Effect of zirconium on the corrosion behavior of FeAl40Ti3B intermetallic compounds for use in solar water heaters
This study aims to investigate the influence of zirconium addition on the corrosion behavior of the FeAl 40 Ti 3 B intermetallic alloy, which was synthesized in an arc furnace under argon atmosphere at 950 °C for 2 h and subsequently annealed for 168 h at 500 °C in quartz capsules. Electrochemical t...
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| Veröffentlicht in: | Journal of applied electrochemistry 2024-06, Vol.54 (6), p.1267-1277 |
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| creator | Metidji, Nadia Younes, Abderrahmane Allou, Djilali Dilmi, Nacer |
| description | This study aims to investigate the influence of zirconium addition on the corrosion behavior of the FeAl
40
Ti
3
B intermetallic alloy, which was synthesized in an arc furnace under argon atmosphere at 950 °C for 2 h and subsequently annealed for 168 h at 500 °C in quartz capsules. Electrochemical techniques, specifically potentiodynamic polarization curves and electrochemical impedance spectroscopy measurements (EIS), were employed to assess the corrosion characteristics. The study also delves into the morphological and phase composition changes through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses. The addition of zirconium to the FeAlTiB alloy led to the formation of zirconium carbide (ZrC) and other phases, including the Laves phase (Fe,Al)
2
Zr. The electrochemical behavior in a 0.5 M H
2
SO
4
solution revealed significant improvements in the corrosion potential (
E
corr
), current density (
i
corr
), and corrosion rate after the addition of Zr to FeAl
40
Ti
3
B. While the corrosion rate for the unalloyed alloy was primarily diffusion-controlled, the alloy with Zr exhibited charge transfer control. Observations via SEM confirmed the occurrence of pitting corrosion in the FeAl
40
Ti
3
B alloy, but the addition of zirconium substantially enhanced its corrosion resistance. These findings shed light on the positive impact of zirconium addition on the corrosion resistance of the FeAl
40
Ti
3
B alloy, offering valuable insights for potential industrial applications.
Graphical abstract |
| doi_str_mv | 10.1007/s10800-023-02033-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3050543870</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3050543870</sourcerecordid><originalsourceid>FETCH-LOGICAL-c270t-735e05b3ca370fa4fa640d9b9a4ecf49a88f836c2419e0a942841180802f41773</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKt_wFPA8-rkY5vssZa2CgUvFbyFNE1syu6mJruK_npTV_DmIQxhnneGeRC6JnBLAMRdIiABCqAsP2Cs4CdoREpBCymZPEUjAEoKWZGXc3SR0h4AKjrhIxTnzlnT4eDwl48mtL5vcGhxt7PYhBhD8vm3sTv97kM8Ygs7rTmsPbvHvu1sbGyn69qbjDeH0LfbhF0m-2RzH6dQ64g_dAbxzh5LukRnTtfJXv3WMXpezNezh2L1tHycTVeFoQK6QrDSQrlhRjMBTnOnJxy21abS3BrHKy2lk2xiKCeVBV1xKjkhMnugjhMh2BjdDHMPMbz1NnVqH_rY5pWKQQklZ1JApuhAmXxritapQ_SNjp-KgDq6VYNbld2qH7eK5xAbQinD7auNf6P_SX0DyvB8LA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3050543870</pqid></control><display><type>article</type><title>Effect of zirconium on the corrosion behavior of FeAl40Ti3B intermetallic compounds for use in solar water heaters</title><source>SpringerLink Journals - AutoHoldings</source><creator>Metidji, Nadia ; Younes, Abderrahmane ; Allou, Djilali ; Dilmi, Nacer</creator><creatorcontrib>Metidji, Nadia ; Younes, Abderrahmane ; Allou, Djilali ; Dilmi, Nacer</creatorcontrib><description>This study aims to investigate the influence of zirconium addition on the corrosion behavior of the FeAl
40
Ti
3
B intermetallic alloy, which was synthesized in an arc furnace under argon atmosphere at 950 °C for 2 h and subsequently annealed for 168 h at 500 °C in quartz capsules. Electrochemical techniques, specifically potentiodynamic polarization curves and electrochemical impedance spectroscopy measurements (EIS), were employed to assess the corrosion characteristics. The study also delves into the morphological and phase composition changes through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses. The addition of zirconium to the FeAlTiB alloy led to the formation of zirconium carbide (ZrC) and other phases, including the Laves phase (Fe,Al)
2
Zr. The electrochemical behavior in a 0.5 M H
2
SO
4
solution revealed significant improvements in the corrosion potential (
E
corr
), current density (
i
corr
), and corrosion rate after the addition of Zr to FeAl
40
Ti
3
B. While the corrosion rate for the unalloyed alloy was primarily diffusion-controlled, the alloy with Zr exhibited charge transfer control. Observations via SEM confirmed the occurrence of pitting corrosion in the FeAl
40
Ti
3
B alloy, but the addition of zirconium substantially enhanced its corrosion resistance. These findings shed light on the positive impact of zirconium addition on the corrosion resistance of the FeAl
40
Ti
3
B alloy, offering valuable insights for potential industrial applications.
Graphical abstract</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-023-02033-4</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Argon ; Charge transfer ; Chemistry ; Chemistry and Materials Science ; Corrosion effects ; Corrosion potential ; Corrosion rate ; Corrosion resistance ; Corrosion tests ; Diffusion rate ; Electric arc furnaces ; Electrochemical analysis ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electrode polarization ; Industrial applications ; Industrial Chemistry/Chemical Engineering ; Intermetallic compounds ; Iron ; Laves phase ; Phase composition ; Physical Chemistry ; Pitting (corrosion) ; Research Article ; Scanning electron microscopy ; Solar heating ; Sulfuric acid ; Water heaters ; Zirconium ; Zirconium carbide</subject><ispartof>Journal of applied electrochemistry, 2024-06, Vol.54 (6), p.1267-1277</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-735e05b3ca370fa4fa640d9b9a4ecf49a88f836c2419e0a942841180802f41773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10800-023-02033-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10800-023-02033-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Metidji, Nadia</creatorcontrib><creatorcontrib>Younes, Abderrahmane</creatorcontrib><creatorcontrib>Allou, Djilali</creatorcontrib><creatorcontrib>Dilmi, Nacer</creatorcontrib><title>Effect of zirconium on the corrosion behavior of FeAl40Ti3B intermetallic compounds for use in solar water heaters</title><title>Journal of applied electrochemistry</title><addtitle>J Appl Electrochem</addtitle><description>This study aims to investigate the influence of zirconium addition on the corrosion behavior of the FeAl
40
Ti
3
B intermetallic alloy, which was synthesized in an arc furnace under argon atmosphere at 950 °C for 2 h and subsequently annealed for 168 h at 500 °C in quartz capsules. Electrochemical techniques, specifically potentiodynamic polarization curves and electrochemical impedance spectroscopy measurements (EIS), were employed to assess the corrosion characteristics. The study also delves into the morphological and phase composition changes through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses. The addition of zirconium to the FeAlTiB alloy led to the formation of zirconium carbide (ZrC) and other phases, including the Laves phase (Fe,Al)
2
Zr. The electrochemical behavior in a 0.5 M H
2
SO
4
solution revealed significant improvements in the corrosion potential (
E
corr
), current density (
i
corr
), and corrosion rate after the addition of Zr to FeAl
40
Ti
3
B. While the corrosion rate for the unalloyed alloy was primarily diffusion-controlled, the alloy with Zr exhibited charge transfer control. Observations via SEM confirmed the occurrence of pitting corrosion in the FeAl
40
Ti
3
B alloy, but the addition of zirconium substantially enhanced its corrosion resistance. These findings shed light on the positive impact of zirconium addition on the corrosion resistance of the FeAl
40
Ti
3
B alloy, offering valuable insights for potential industrial applications.
Graphical abstract</description><subject>Argon</subject><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion effects</subject><subject>Corrosion potential</subject><subject>Corrosion rate</subject><subject>Corrosion resistance</subject><subject>Corrosion tests</subject><subject>Diffusion rate</subject><subject>Electric arc furnaces</subject><subject>Electrochemical analysis</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electrode polarization</subject><subject>Industrial applications</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Intermetallic compounds</subject><subject>Iron</subject><subject>Laves phase</subject><subject>Phase composition</subject><subject>Physical Chemistry</subject><subject>Pitting (corrosion)</subject><subject>Research Article</subject><subject>Scanning electron microscopy</subject><subject>Solar heating</subject><subject>Sulfuric acid</subject><subject>Water heaters</subject><subject>Zirconium</subject><subject>Zirconium carbide</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wFPA8-rkY5vssZa2CgUvFbyFNE1syu6mJruK_npTV_DmIQxhnneGeRC6JnBLAMRdIiABCqAsP2Cs4CdoREpBCymZPEUjAEoKWZGXc3SR0h4AKjrhIxTnzlnT4eDwl48mtL5vcGhxt7PYhBhD8vm3sTv97kM8Ygs7rTmsPbvHvu1sbGyn69qbjDeH0LfbhF0m-2RzH6dQ64g_dAbxzh5LukRnTtfJXv3WMXpezNezh2L1tHycTVeFoQK6QrDSQrlhRjMBTnOnJxy21abS3BrHKy2lk2xiKCeVBV1xKjkhMnugjhMh2BjdDHMPMbz1NnVqH_rY5pWKQQklZ1JApuhAmXxritapQ_SNjp-KgDq6VYNbld2qH7eK5xAbQinD7auNf6P_SX0DyvB8LA</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Metidji, Nadia</creator><creator>Younes, Abderrahmane</creator><creator>Allou, Djilali</creator><creator>Dilmi, Nacer</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240601</creationdate><title>Effect of zirconium on the corrosion behavior of FeAl40Ti3B intermetallic compounds for use in solar water heaters</title><author>Metidji, Nadia ; Younes, Abderrahmane ; Allou, Djilali ; Dilmi, Nacer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-735e05b3ca370fa4fa640d9b9a4ecf49a88f836c2419e0a942841180802f41773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Argon</topic><topic>Charge transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Corrosion effects</topic><topic>Corrosion potential</topic><topic>Corrosion rate</topic><topic>Corrosion resistance</topic><topic>Corrosion tests</topic><topic>Diffusion rate</topic><topic>Electric arc furnaces</topic><topic>Electrochemical analysis</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electrode polarization</topic><topic>Industrial applications</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Intermetallic compounds</topic><topic>Iron</topic><topic>Laves phase</topic><topic>Phase composition</topic><topic>Physical Chemistry</topic><topic>Pitting (corrosion)</topic><topic>Research Article</topic><topic>Scanning electron microscopy</topic><topic>Solar heating</topic><topic>Sulfuric acid</topic><topic>Water heaters</topic><topic>Zirconium</topic><topic>Zirconium carbide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Metidji, Nadia</creatorcontrib><creatorcontrib>Younes, Abderrahmane</creatorcontrib><creatorcontrib>Allou, Djilali</creatorcontrib><creatorcontrib>Dilmi, Nacer</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Metidji, Nadia</au><au>Younes, Abderrahmane</au><au>Allou, Djilali</au><au>Dilmi, Nacer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of zirconium on the corrosion behavior of FeAl40Ti3B intermetallic compounds for use in solar water heaters</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>54</volume><issue>6</issue><spage>1267</spage><epage>1277</epage><pages>1267-1277</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>This study aims to investigate the influence of zirconium addition on the corrosion behavior of the FeAl
40
Ti
3
B intermetallic alloy, which was synthesized in an arc furnace under argon atmosphere at 950 °C for 2 h and subsequently annealed for 168 h at 500 °C in quartz capsules. Electrochemical techniques, specifically potentiodynamic polarization curves and electrochemical impedance spectroscopy measurements (EIS), were employed to assess the corrosion characteristics. The study also delves into the morphological and phase composition changes through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses. The addition of zirconium to the FeAlTiB alloy led to the formation of zirconium carbide (ZrC) and other phases, including the Laves phase (Fe,Al)
2
Zr. The electrochemical behavior in a 0.5 M H
2
SO
4
solution revealed significant improvements in the corrosion potential (
E
corr
), current density (
i
corr
), and corrosion rate after the addition of Zr to FeAl
40
Ti
3
B. While the corrosion rate for the unalloyed alloy was primarily diffusion-controlled, the alloy with Zr exhibited charge transfer control. Observations via SEM confirmed the occurrence of pitting corrosion in the FeAl
40
Ti
3
B alloy, but the addition of zirconium substantially enhanced its corrosion resistance. These findings shed light on the positive impact of zirconium addition on the corrosion resistance of the FeAl
40
Ti
3
B alloy, offering valuable insights for potential industrial applications.
Graphical abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10800-023-02033-4</doi><tpages>11</tpages></addata></record> |
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| identifier | ISSN: 0021-891X |
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| issn | 0021-891X 1572-8838 |
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| subjects | Argon Charge transfer Chemistry Chemistry and Materials Science Corrosion effects Corrosion potential Corrosion rate Corrosion resistance Corrosion tests Diffusion rate Electric arc furnaces Electrochemical analysis Electrochemical impedance spectroscopy Electrochemistry Electrode polarization Industrial applications Industrial Chemistry/Chemical Engineering Intermetallic compounds Iron Laves phase Phase composition Physical Chemistry Pitting (corrosion) Research Article Scanning electron microscopy Solar heating Sulfuric acid Water heaters Zirconium Zirconium carbide |
| title | Effect of zirconium on the corrosion behavior of FeAl40Ti3B intermetallic compounds for use in solar water heaters |
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