Pyrolysis of sargassum in a single mode microwave cavity: use of SiC and biochar as microwave absorbers
This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity. Sargassum permittivities were measured and demonstrate the necessity of using a microwave absorber to help in reaching efficient pyrolysis. Silicon carbide, which is commonly used, and sarg...
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Veröffentlicht in: | Reaction chemistry & engineering 2024-04, Vol.9 (5), p.1235-125 |
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description | This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity. Sargassum permittivities were measured and demonstrate the necessity of using a microwave absorber to help in reaching efficient pyrolysis. Silicon carbide, which is commonly used, and sargassum biochar, which has never been used before as a microwave absorber, were added to the system and their efficiencies were compared. Based on our experimental results, the high permittivity of sargassum biochar makes it a good microwave absorber. In comparison to the silicon carbide derived bio-oil, the sargassum biochar-derived bio-oil is of higher quality due to its lower acidity. Both microwave absorbers produce H
2
and CO rich biogas, but the biogas production is higher when biochar is used as an absorber. A complete analysis of the bio-oil components was done and confirms the less acidic character of the oil produced using biochar and the higher proportion of oxidized compounds produced with SiC.
This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity using char or SiC as microwave absorber. |
doi_str_mv | 10.1039/d3re00523b |
format | Article |
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2
and CO rich biogas, but the biogas production is higher when biochar is used as an absorber. A complete analysis of the bio-oil components was done and confirms the less acidic character of the oil produced using biochar and the higher proportion of oxidized compounds produced with SiC.
This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity using char or SiC as microwave absorber.</description><identifier>ISSN: 2058-9883</identifier><identifier>EISSN: 2058-9883</identifier><identifier>DOI: 10.1039/d3re00523b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Biogas ; Microwave absorbers ; Pyrolysis ; Silicon carbide</subject><ispartof>Reaction chemistry & engineering, 2024-04, Vol.9 (5), p.1235-125</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c240t-33fb428ca1ddbba56fda637933f456949d39a02d65104b4c340b6ac77012c9243</cites><orcidid>0000-0002-3927-5883 ; 0000-0002-6943-4873</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>De La Cruz Iturbides, Randal</creatorcontrib><creatorcontrib>Ubiera, Lilivet</creatorcontrib><creatorcontrib>Jauregui Haza, Ulises</creatorcontrib><creatorcontrib>Polaert, Isabelle</creatorcontrib><title>Pyrolysis of sargassum in a single mode microwave cavity: use of SiC and biochar as microwave absorbers</title><title>Reaction chemistry & engineering</title><description>This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity. Sargassum permittivities were measured and demonstrate the necessity of using a microwave absorber to help in reaching efficient pyrolysis. Silicon carbide, which is commonly used, and sargassum biochar, which has never been used before as a microwave absorber, were added to the system and their efficiencies were compared. Based on our experimental results, the high permittivity of sargassum biochar makes it a good microwave absorber. In comparison to the silicon carbide derived bio-oil, the sargassum biochar-derived bio-oil is of higher quality due to its lower acidity. Both microwave absorbers produce H
2
and CO rich biogas, but the biogas production is higher when biochar is used as an absorber. A complete analysis of the bio-oil components was done and confirms the less acidic character of the oil produced using biochar and the higher proportion of oxidized compounds produced with SiC.
This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity using char or SiC as microwave absorber.</description><subject>Biogas</subject><subject>Microwave absorbers</subject><subject>Pyrolysis</subject><subject>Silicon carbide</subject><issn>2058-9883</issn><issn>2058-9883</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLw0AQgBdRsGgv3oUFb0J09pGXN631AQXFxznMbjZ1S5vUnaaSf29qRXuZGYZvHnyMnQi4EKDyy1IFBxBLZfbYQEKcRXmWqf2d-pANiWYAIBIAlaUDNn3uQjPvyBNvKk4YpkjULrivOXLy9XTu-KIp--BtaL5w7bjFtV91V7wlt5l59SOOdcmNb-wHBo60w6KhJhgX6JgdVDgnN_zNR-z9bvw2eogmT_ePo-tJZKWGVaRUZbTMLIqyNAbjpCoxUWne93Wc5DovVY4gyyQWoI22SoNJ0KYpCGlzqdURO9vuXYbms3W0KmZNG-r-ZKFAZ4nME5H21PmW6v8kCq4qlsEvMHSFgGLjsrhVL-Mflzc9fLqFA9k_7t-1-gaqdXAf</recordid><startdate>20240430</startdate><enddate>20240430</enddate><creator>De La Cruz Iturbides, Randal</creator><creator>Ubiera, Lilivet</creator><creator>Jauregui Haza, Ulises</creator><creator>Polaert, Isabelle</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-3927-5883</orcidid><orcidid>https://orcid.org/0000-0002-6943-4873</orcidid></search><sort><creationdate>20240430</creationdate><title>Pyrolysis of sargassum in a single mode microwave cavity: use of SiC and biochar as microwave absorbers</title><author>De La Cruz Iturbides, Randal ; Ubiera, Lilivet ; Jauregui Haza, Ulises ; Polaert, Isabelle</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-33fb428ca1ddbba56fda637933f456949d39a02d65104b4c340b6ac77012c9243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biogas</topic><topic>Microwave absorbers</topic><topic>Pyrolysis</topic><topic>Silicon carbide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>De La Cruz Iturbides, Randal</creatorcontrib><creatorcontrib>Ubiera, Lilivet</creatorcontrib><creatorcontrib>Jauregui Haza, Ulises</creatorcontrib><creatorcontrib>Polaert, Isabelle</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Reaction chemistry & engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>De La Cruz Iturbides, Randal</au><au>Ubiera, Lilivet</au><au>Jauregui Haza, Ulises</au><au>Polaert, Isabelle</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pyrolysis of sargassum in a single mode microwave cavity: use of SiC and biochar as microwave absorbers</atitle><jtitle>Reaction chemistry & engineering</jtitle><date>2024-04-30</date><risdate>2024</risdate><volume>9</volume><issue>5</issue><spage>1235</spage><epage>125</epage><pages>1235-125</pages><issn>2058-9883</issn><eissn>2058-9883</eissn><abstract>This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity. Sargassum permittivities were measured and demonstrate the necessity of using a microwave absorber to help in reaching efficient pyrolysis. Silicon carbide, which is commonly used, and sargassum biochar, which has never been used before as a microwave absorber, were added to the system and their efficiencies were compared. Based on our experimental results, the high permittivity of sargassum biochar makes it a good microwave absorber. In comparison to the silicon carbide derived bio-oil, the sargassum biochar-derived bio-oil is of higher quality due to its lower acidity. Both microwave absorbers produce H
2
and CO rich biogas, but the biogas production is higher when biochar is used as an absorber. A complete analysis of the bio-oil components was done and confirms the less acidic character of the oil produced using biochar and the higher proportion of oxidized compounds produced with SiC.
This paper examines the feasibility of pyrolyzing the macroalgae sargassum, in a single-mode microwave cavity using char or SiC as microwave absorber.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3re00523b</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0002-3927-5883</orcidid><orcidid>https://orcid.org/0000-0002-6943-4873</orcidid></addata></record> |
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source | Royal Society Of Chemistry Journals 2008- |
subjects | Biogas Microwave absorbers Pyrolysis Silicon carbide |
title | Pyrolysis of sargassum in a single mode microwave cavity: use of SiC and biochar as microwave absorbers |
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