1,3‐Dipolar Cycloaddition of Polycyclic Aromatic Azomethine Ylides and Alkynylbenziodoxoles for Synthesis of Functional Dibenzoullazines

Comprehensive Summary A new family of dibenzoullazine derivatives was synthesized through 1,3‐dipolar cycloaddition of polycyclic aromatic azomethine ylides with alkynylbenziodoxoles followed by oxidation. The benziodoxole moiety in the resulting products was used as a versatile linchpin for the syn...

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Veröffentlicht in:Chinese journal of chemistry 2024-05, Vol.42 (10), p.1079-1083
Hauptverfasser: Han, Hui, Goh, Glen Wee Zhuan, Li, Yongxin, Yoshikai, Naohiko, Ito, Shingo
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container_end_page 1083
container_issue 10
container_start_page 1079
container_title Chinese journal of chemistry
container_volume 42
creator Han, Hui
Goh, Glen Wee Zhuan
Li, Yongxin
Yoshikai, Naohiko
Ito, Shingo
description Comprehensive Summary A new family of dibenzoullazine derivatives was synthesized through 1,3‐dipolar cycloaddition of polycyclic aromatic azomethine ylides with alkynylbenziodoxoles followed by oxidation. The benziodoxole moiety in the resulting products was used as a versatile linchpin for the synthesis of structurally diverse functional dibenzoullazines that are difficult to access by other synthetic methods. A new family of dibenzoullazine derivatives was synthesized through 1,3‐dipolar cycloaddition of polycyclic aromatic azomethine ylides with alkynylbenziodoxoles followed by oxidation. The benziodoxole moiety in the resulting products was used as a versatile linchpin for the synthesis of structurally diverse functional dibenzoullazines that are difficult to access by other synthetic methods.
doi_str_mv 10.1002/cjoc.202300637
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source Wiley Online Library - AutoHoldings Journals
subjects Azomethine ylides
Cycloaddition
Dibenzoullazine
Hypervalent compounds
Nitrogen heterocycles
Oxidation
Synthesis
title 1,3‐Dipolar Cycloaddition of Polycyclic Aromatic Azomethine Ylides and Alkynylbenziodoxoles for Synthesis of Functional Dibenzoullazines
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