Alkali‐assisted functionalization of hexagonal boron nitride reinforced epoxy composite to improve the thermomechanical and anticorrosion performance for advanced thermal management
A comprehensive methodology for fabricating and characterizing the tetraethyl orthosilicate (TEOS) modified exfoliated boron nitride (eBN) reinforced epoxy resin (EP) composites has been demonstrated. The functionalized eBN was synthesized by solution‐mixing followed by alkali‐assisted hydrothermal...
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| Veröffentlicht in: | Polymer composites 2024-04, Vol.45 (6), p.5643-5655 |
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| creator | Kuila, Chinmoy Maji, Animesh Phadikar, Ujjwal Mallisetty, Phani Kumar Murmu, Naresh Chandra Kuila, Tapas |
| description | A comprehensive methodology for fabricating and characterizing the tetraethyl orthosilicate (TEOS) modified exfoliated boron nitride (eBN) reinforced epoxy resin (EP) composites has been demonstrated. The functionalized eBN was synthesized by solution‐mixing followed by alkali‐assisted hydrothermal reaction. The composites with various filler loadings (0, 5, 10, and 15 wt.%) were fabricated using solution casting method. The fundamental features of the composites were examined through tensile and bending properties, thermal properties, and anticorrosion properties. The synthesized TEOS‐eBN was utilized to improve the dispersibility and compatibility with the EP resin, which played a crucial role in improving the thermal conductivity as well as thermomechanical properties of the composites. The incorporation of filler in the EP matrix improved the thermomechanical as well as anticorrosion properties. The tensile and flexural tests were carried out according to ASTM D‐638 and ASTM‐D790, respectively. We discovered that the 5 wt.% of TEOS‐eBN in EP showed the optimum thermomechanical properties. The tensile strength and Tg were improved by ~74.71 and ~16.8% at 5 wt.% loading. The improved thermomechanical and anticorrosion properties of all the composites showed the potential to be efficient heat‐releasing material for thermal management and coating applications in automotive industries.
Highlights
Tetraethyl orthosilicate (TEOS)‐exfoliated boron nitride (eBN) was synthesized by alkali‐assisted hydrothermal and solution mixing method.
The composite specimens exhibited excellent thermal conductivity.
The thermomechanical and anticorrosion performance were remarkably improved.
Optimal thermomechanical properties were obtained at 5% filler content.
Application of the fabricated TEOS‐eBN/epoxy composites for thermal management and polymer coating in automotive application. |
| doi_str_mv | 10.1002/pc.28154 |
| format | Article |
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Highlights
Tetraethyl orthosilicate (TEOS)‐exfoliated boron nitride (eBN) was synthesized by alkali‐assisted hydrothermal and solution mixing method.
The composite specimens exhibited excellent thermal conductivity.
The thermomechanical and anticorrosion performance were remarkably improved.
Optimal thermomechanical properties were obtained at 5% filler content.
Application of the fabricated TEOS‐eBN/epoxy composites for thermal management and polymer coating in automotive application.</description><identifier>ISSN: 0272-8397</identifier><identifier>EISSN: 1548-0569</identifier><identifier>DOI: 10.1002/pc.28154</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>anticorrosion coating ; Boron ; Boron nitride ; Composite materials ; Corrosion prevention ; epoxy composite ; Epoxy resins ; Fillers ; Heat conductivity ; Heat transfer ; Hydrothermal reactions ; Optimization ; phonon–phonon scattering ; Tensile strength ; Tetraethyl orthosilicate ; Thermal conductivity ; Thermal management ; Thermodynamic properties ; Thermomechanical properties</subject><ispartof>Polymer composites, 2024-04, Vol.45 (6), p.5643-5655</ispartof><rights>2024 Society of Plastics Engineers.</rights><rights>2024 Society of Plastics Engineers</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2934-5e67c80d041e90d193f0ea5a4e30fa10cd6063195cb49571f7f35b81c921e1b03</citedby><cites>FETCH-LOGICAL-c2934-5e67c80d041e90d193f0ea5a4e30fa10cd6063195cb49571f7f35b81c921e1b03</cites><orcidid>0000-0003-0976-3285 ; 0000-0002-5869-7459</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpc.28154$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpc.28154$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Kuila, Chinmoy</creatorcontrib><creatorcontrib>Maji, Animesh</creatorcontrib><creatorcontrib>Phadikar, Ujjwal</creatorcontrib><creatorcontrib>Mallisetty, Phani Kumar</creatorcontrib><creatorcontrib>Murmu, Naresh Chandra</creatorcontrib><creatorcontrib>Kuila, Tapas</creatorcontrib><title>Alkali‐assisted functionalization of hexagonal boron nitride reinforced epoxy composite to improve the thermomechanical and anticorrosion performance for advanced thermal management</title><title>Polymer composites</title><description>A comprehensive methodology for fabricating and characterizing the tetraethyl orthosilicate (TEOS) modified exfoliated boron nitride (eBN) reinforced epoxy resin (EP) composites has been demonstrated. The functionalized eBN was synthesized by solution‐mixing followed by alkali‐assisted hydrothermal reaction. The composites with various filler loadings (0, 5, 10, and 15 wt.%) were fabricated using solution casting method. The fundamental features of the composites were examined through tensile and bending properties, thermal properties, and anticorrosion properties. The synthesized TEOS‐eBN was utilized to improve the dispersibility and compatibility with the EP resin, which played a crucial role in improving the thermal conductivity as well as thermomechanical properties of the composites. The incorporation of filler in the EP matrix improved the thermomechanical as well as anticorrosion properties. The tensile and flexural tests were carried out according to ASTM D‐638 and ASTM‐D790, respectively. We discovered that the 5 wt.% of TEOS‐eBN in EP showed the optimum thermomechanical properties. The tensile strength and Tg were improved by ~74.71 and ~16.8% at 5 wt.% loading. The improved thermomechanical and anticorrosion properties of all the composites showed the potential to be efficient heat‐releasing material for thermal management and coating applications in automotive industries.
Highlights
Tetraethyl orthosilicate (TEOS)‐exfoliated boron nitride (eBN) was synthesized by alkali‐assisted hydrothermal and solution mixing method.
The composite specimens exhibited excellent thermal conductivity.
The thermomechanical and anticorrosion performance were remarkably improved.
Optimal thermomechanical properties were obtained at 5% filler content.
Application of the fabricated TEOS‐eBN/epoxy composites for thermal management and polymer coating in automotive application.</description><subject>anticorrosion coating</subject><subject>Boron</subject><subject>Boron nitride</subject><subject>Composite materials</subject><subject>Corrosion prevention</subject><subject>epoxy composite</subject><subject>Epoxy resins</subject><subject>Fillers</subject><subject>Heat conductivity</subject><subject>Heat transfer</subject><subject>Hydrothermal reactions</subject><subject>Optimization</subject><subject>phonon–phonon scattering</subject><subject>Tensile strength</subject><subject>Tetraethyl orthosilicate</subject><subject>Thermal conductivity</subject><subject>Thermal management</subject><subject>Thermodynamic properties</subject><subject>Thermomechanical properties</subject><issn>0272-8397</issn><issn>1548-0569</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kU1OwzAQhS0EEqUgcQRLbNik2HF-l1XFn1QJFrCOHGfcujRxsFNoWXEEbsN9OAmThi2LsZ_G33vSeAg552zCGQuvWjUJMx5HB2SEZxawOMkPyYiFaRhkIk-PyYn3KyR5kogR-Z6uX-Ta_Hx-Se-N76CietOoztgG2x-yF9RquoStXPQ9WlqHrcZ0zlRAHZhGW6fQB63d7qiydWu96YB2lpq6dfYN5XJfrrY1qKVsjMIg2VRYnVHWOXRgaAsOs2rZKKAoqKzeel0NXrTgk1xADU13So60XHs4-7vH5Pnm-ml2F8wfbu9n03mgwlxEQQxJqjJWsYhDziqeC81AxjICwbTkTFUJSwTPY1VGeZxynWoRlxlXeciBl0yMycWQi4O8bsB3xcpuHP6DLwQTqWBhkkRIXQ6Uwkm8A120ztTS7QrOin4tRauK_VoQDQb03axh9y9XPM4G_hcbqJQ_</recordid><startdate>20240420</startdate><enddate>20240420</enddate><creator>Kuila, Chinmoy</creator><creator>Maji, Animesh</creator><creator>Phadikar, Ujjwal</creator><creator>Mallisetty, Phani Kumar</creator><creator>Murmu, Naresh Chandra</creator><creator>Kuila, Tapas</creator><general>John Wiley & Sons, Inc</general><general>Blackwell Publishing Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-0976-3285</orcidid><orcidid>https://orcid.org/0000-0002-5869-7459</orcidid></search><sort><creationdate>20240420</creationdate><title>Alkali‐assisted functionalization of hexagonal boron nitride reinforced epoxy composite to improve the thermomechanical and anticorrosion performance for advanced thermal management</title><author>Kuila, Chinmoy ; Maji, Animesh ; Phadikar, Ujjwal ; Mallisetty, Phani Kumar ; Murmu, Naresh Chandra ; Kuila, Tapas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2934-5e67c80d041e90d193f0ea5a4e30fa10cd6063195cb49571f7f35b81c921e1b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>anticorrosion coating</topic><topic>Boron</topic><topic>Boron nitride</topic><topic>Composite materials</topic><topic>Corrosion prevention</topic><topic>epoxy composite</topic><topic>Epoxy resins</topic><topic>Fillers</topic><topic>Heat conductivity</topic><topic>Heat transfer</topic><topic>Hydrothermal reactions</topic><topic>Optimization</topic><topic>phonon–phonon scattering</topic><topic>Tensile strength</topic><topic>Tetraethyl orthosilicate</topic><topic>Thermal conductivity</topic><topic>Thermal management</topic><topic>Thermodynamic properties</topic><topic>Thermomechanical properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kuila, Chinmoy</creatorcontrib><creatorcontrib>Maji, Animesh</creatorcontrib><creatorcontrib>Phadikar, Ujjwal</creatorcontrib><creatorcontrib>Mallisetty, Phani Kumar</creatorcontrib><creatorcontrib>Murmu, Naresh Chandra</creatorcontrib><creatorcontrib>Kuila, Tapas</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer composites</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kuila, Chinmoy</au><au>Maji, Animesh</au><au>Phadikar, Ujjwal</au><au>Mallisetty, Phani Kumar</au><au>Murmu, Naresh Chandra</au><au>Kuila, Tapas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Alkali‐assisted functionalization of hexagonal boron nitride reinforced epoxy composite to improve the thermomechanical and anticorrosion performance for advanced thermal management</atitle><jtitle>Polymer composites</jtitle><date>2024-04-20</date><risdate>2024</risdate><volume>45</volume><issue>6</issue><spage>5643</spage><epage>5655</epage><pages>5643-5655</pages><issn>0272-8397</issn><eissn>1548-0569</eissn><abstract>A comprehensive methodology for fabricating and characterizing the tetraethyl orthosilicate (TEOS) modified exfoliated boron nitride (eBN) reinforced epoxy resin (EP) composites has been demonstrated. The functionalized eBN was synthesized by solution‐mixing followed by alkali‐assisted hydrothermal reaction. The composites with various filler loadings (0, 5, 10, and 15 wt.%) were fabricated using solution casting method. The fundamental features of the composites were examined through tensile and bending properties, thermal properties, and anticorrosion properties. The synthesized TEOS‐eBN was utilized to improve the dispersibility and compatibility with the EP resin, which played a crucial role in improving the thermal conductivity as well as thermomechanical properties of the composites. The incorporation of filler in the EP matrix improved the thermomechanical as well as anticorrosion properties. The tensile and flexural tests were carried out according to ASTM D‐638 and ASTM‐D790, respectively. We discovered that the 5 wt.% of TEOS‐eBN in EP showed the optimum thermomechanical properties. The tensile strength and Tg were improved by ~74.71 and ~16.8% at 5 wt.% loading. The improved thermomechanical and anticorrosion properties of all the composites showed the potential to be efficient heat‐releasing material for thermal management and coating applications in automotive industries.
Highlights
Tetraethyl orthosilicate (TEOS)‐exfoliated boron nitride (eBN) was synthesized by alkali‐assisted hydrothermal and solution mixing method.
The composite specimens exhibited excellent thermal conductivity.
The thermomechanical and anticorrosion performance were remarkably improved.
Optimal thermomechanical properties were obtained at 5% filler content.
Application of the fabricated TEOS‐eBN/epoxy composites for thermal management and polymer coating in automotive application.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/pc.28154</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-0976-3285</orcidid><orcidid>https://orcid.org/0000-0002-5869-7459</orcidid></addata></record> |
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| subjects | anticorrosion coating Boron Boron nitride Composite materials Corrosion prevention epoxy composite Epoxy resins Fillers Heat conductivity Heat transfer Hydrothermal reactions Optimization phonon–phonon scattering Tensile strength Tetraethyl orthosilicate Thermal conductivity Thermal management Thermodynamic properties Thermomechanical properties |
| title | Alkali‐assisted functionalization of hexagonal boron nitride reinforced epoxy composite to improve the thermomechanical and anticorrosion performance for advanced thermal management |
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