Comparative analysis on corrosion behavior of lightweight and dense mullite–corundum refractories: Role of Si‐rich phase

The corrosion resistance of lightweight and dense mullite–corundum refractories to cement materials was examined. The specimens following static crucible treatment were investigated using phase analysis, microstructure, and thermodynamic simulation. The results reveal that diffusion of the silica‐ri...

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Veröffentlicht in:International journal of applied ceramic technology 2024-05, Vol.21 (3), p.2377-2390
Hauptverfasser: Liu, Yuchi, Gao, Yunqin, Yin, Hongfeng, Xin, Yalou, Tang, Yun, Yuan, Hudie, Sun, Kewei
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container_issue 3
container_start_page 2377
container_title International journal of applied ceramic technology
container_volume 21
creator Liu, Yuchi
Gao, Yunqin
Yin, Hongfeng
Xin, Yalou
Tang, Yun
Yuan, Hudie
Sun, Kewei
description The corrosion resistance of lightweight and dense mullite–corundum refractories to cement materials was examined. The specimens following static crucible treatment were investigated using phase analysis, microstructure, and thermodynamic simulation. The results reveal that diffusion of the silica‐rich phase enhances alumina saturation solubility in the slag, reducing the corrosion resistance of the mullite–corundum refractories. The large proportion of closed pores and the continuous net‐like structure of anorthite created by the corrosion reaction in the matrix, on the other hand, prevent further slag penetration into the lightweight mullite–corundum refractories. As a result, the presence of the silica‐rich phase assures better slag penetration resistance of lightweight mullite–corundum refractories.
doi_str_mv 10.1111/ijac.14697
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subjects Anorthite
Calcium aluminum silicates
cement material
Corrosion resistance
Corundum
Kirkendall effect
Lightweight
lightweight mullite–corundum refractory
Mullite
Penetration
Penetration resistance
Siliceous refractories
Silicon dioxide
Slag
thermodynamic simulation
title Comparative analysis on corrosion behavior of lightweight and dense mullite–corundum refractories: Role of Si‐rich phase
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