Cyclic Diaryl λ3‐Bromanes as a Precursor for Regiodivergent Alkynylation Reactions

Regiodivergent reactions are a fascinating tool to rapidly access molecular diversity while using identical coupling partners. We have developed a new approach for regiodivergent synthesis using the dual character of hypervalent bromines. In addition to the recently reported reactivity of hypervalen...

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Veröffentlicht in:	Angewandte Chemie 2024-04, Vol.136 (16), p.n/a
Hauptverfasser:	De Abreu, Maxime, Rogge, Torben, Lanzi, Matteo, Saiegh, Tomas J., Houk, Kendall N., Wencel‐Delord, Joanna
Format:	Artikel
Sprache:	eng
Schlagworte:	biaryl-alkyne Bromine Coupling (molecular) hypervalent bromine metal-free alkynylation Metals Precursors regiodivergent alkynylation Regioselectivity Transition metals λ3-bromane
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