Influence of different gamma radiation doses on the physical, chemical and thermal properties of antimicrobial active packaging of poly (butylene adipate co-terephthalate) (PBAT) films additivated with orange essential oil
Gamma radiation is a common sterilization technique utilized in the packaging of raw and processed foods; it acts retarding the microbial growth in packaged foods, however, depending on the dose, the radiation can modify the chemical structure of the polymers in the packaging. In this study, differe...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2024-05, Vol.81 (7), p.6349-6362 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | de Andrade, Michelle Félix Caetano, Viviane Fonseca de Lima Silva, Ivo Diego Azevedo, William Ottoni Barbosa de Almeida, Yêda Medeiros Bastos Vinhas, Glória Maria |
| description | Gamma radiation is a common sterilization technique utilized in the packaging of raw and processed foods; it acts retarding the microbial growth in packaged foods, however, depending on the dose, the radiation can modify the chemical structure of the polymers in the packaging. In this study, different doses of 10, 25 and 50 kGy were applied in PBAT films additivated with orange essential oil, and their physical, chemical and thermal properties were investigated. The results of the principal components analysis of the films showed that the applied doses altered the chemical structures of the films, the DSC of the films showed a reduction of their crystallization temperature and an increase in their enthalpy of fusion, indicating a cross-linking, the TGA of the samples revealed that the material remained stable with the doses applied, additionally, the films became more resistant and rigid without losing their elastic behavior. At last, the analyses presented that the additivated PBAT films did not suffer major modifications in their structure due to irradiation, indicating a good radiolytic stability of the PBAT. |
| doi_str_mv | 10.1007/s00289-023-05005-y |
| format | Article |
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In this study, different doses of 10, 25 and 50 kGy were applied in PBAT films additivated with orange essential oil, and their physical, chemical and thermal properties were investigated. The results of the principal components analysis of the films showed that the applied doses altered the chemical structures of the films, the DSC of the films showed a reduction of their crystallization temperature and an increase in their enthalpy of fusion, indicating a cross-linking, the TGA of the samples revealed that the material remained stable with the doses applied, additionally, the films became more resistant and rigid without losing their elastic behavior. At last, the analyses presented that the additivated PBAT films did not suffer major modifications in their structure due to irradiation, indicating a good radiolytic stability of the PBAT.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-023-05005-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Crosslinking ; Crystallization ; Elasticity ; Enthalpy ; Essential oils ; Food ; Food packaging ; Gamma rays ; Kinematics ; Microorganisms ; Oils & fats ; Organic Chemistry ; Original Paper ; Packaging ; Physical Chemistry ; Polymer Sciences ; Polymers ; Principal components analysis ; Radiation ; Radiation dosage ; Soft and Granular Matter ; Software ; Spectrum analysis ; Sterilization ; Thermodynamic properties ; Variance analysis ; Viscosity</subject><ispartof>Polymer bulletin (Berlin, Germany), 2024-05, Vol.81 (7), p.6349-6362</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c298t-41adfc59d22d3a7e3c8c4ed3be32bca0171375a9b92bf8b69391b92ed8e4c9773</cites><orcidid>0000-0002-4798-1403</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-023-05005-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00289-023-05005-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>de Andrade, Michelle Félix</creatorcontrib><creatorcontrib>Caetano, Viviane Fonseca</creatorcontrib><creatorcontrib>de Lima Silva, Ivo Diego</creatorcontrib><creatorcontrib>Azevedo, William Ottoni Barbosa</creatorcontrib><creatorcontrib>de Almeida, Yêda Medeiros Bastos</creatorcontrib><creatorcontrib>Vinhas, Glória Maria</creatorcontrib><title>Influence of different gamma radiation doses on the physical, chemical and thermal properties of antimicrobial active packaging of poly (butylene adipate co-terephthalate) (PBAT) films additivated with orange essential oil</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>Gamma radiation is a common sterilization technique utilized in the packaging of raw and processed foods; it acts retarding the microbial growth in packaged foods, however, depending on the dose, the radiation can modify the chemical structure of the polymers in the packaging. In this study, different doses of 10, 25 and 50 kGy were applied in PBAT films additivated with orange essential oil, and their physical, chemical and thermal properties were investigated. The results of the principal components analysis of the films showed that the applied doses altered the chemical structures of the films, the DSC of the films showed a reduction of their crystallization temperature and an increase in their enthalpy of fusion, indicating a cross-linking, the TGA of the samples revealed that the material remained stable with the doses applied, additionally, the films became more resistant and rigid without losing their elastic behavior. At last, the analyses presented that the additivated PBAT films did not suffer major modifications in their structure due to irradiation, indicating a good radiolytic stability of the PBAT.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Crosslinking</subject><subject>Crystallization</subject><subject>Elasticity</subject><subject>Enthalpy</subject><subject>Essential oils</subject><subject>Food</subject><subject>Food packaging</subject><subject>Gamma rays</subject><subject>Kinematics</subject><subject>Microorganisms</subject><subject>Oils & fats</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Packaging</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Principal components analysis</subject><subject>Radiation</subject><subject>Radiation dosage</subject><subject>Soft and Granular Matter</subject><subject>Software</subject><subject>Spectrum analysis</subject><subject>Sterilization</subject><subject>Thermodynamic properties</subject><subject>Variance analysis</subject><subject>Viscosity</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFUctu1TAUjBBIXEp_gJUlNq1EwI-8vCwVtJUqlUW7jhz7-MYlsYPtW5Sf7bdwwkViB5Ilj31m5thniuIdox8Zpe2nRCnvZEm5KGlNaV2uL4odq0RT8qqSL4sdZS0taSfk6-JNSo8Uz03DdsXzjbfTAbwGEiwxzlqI4DPZq3lWJCrjVHbBExMSJIIgj0CWcU1Oq-kD0SPMGyLKm60UZ8RLDAvE7DaBxUp2yIlhcBtPZ_eEDkp_V3vn9xtjCdNKzoZDXifwQLDnojIQHcqMj1nGPKoJL87J2bfPF_fnxLppTkgzDr2wYMhPl0cSovJ7IJASfmDrFdz0tnhl1ZTg9M9-Ujx8_XJ_eV3e3l3dXF7clprLLpcVU8bqWhrOjVAtCN3pCowYQPBBKxwWE22t5CD5YLuhkUIyxGA6qLRsW3FSvD_64t9_HCDl_jEcoseWvaACV90w-h8W7yrOWoEsfmThzFKKYPslulnFtWe039Luj2n3mHb_O-1-RZE4ihKScQzxr_U_VL8Ab-6yeQ</recordid><startdate>20240501</startdate><enddate>20240501</enddate><creator>de Andrade, Michelle Félix</creator><creator>Caetano, Viviane Fonseca</creator><creator>de Lima Silva, Ivo Diego</creator><creator>Azevedo, William Ottoni Barbosa</creator><creator>de Almeida, Yêda Medeiros Bastos</creator><creator>Vinhas, Glória Maria</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4798-1403</orcidid></search><sort><creationdate>20240501</creationdate><title>Influence of different gamma radiation doses on the physical, chemical and thermal properties of antimicrobial active packaging of poly (butylene adipate co-terephthalate) (PBAT) films additivated with orange essential oil</title><author>de Andrade, Michelle Félix ; Caetano, Viviane Fonseca ; de Lima Silva, Ivo Diego ; Azevedo, William Ottoni Barbosa ; de Almeida, Yêda Medeiros Bastos ; Vinhas, Glória Maria</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c298t-41adfc59d22d3a7e3c8c4ed3be32bca0171375a9b92bf8b69391b92ed8e4c9773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Crosslinking</topic><topic>Crystallization</topic><topic>Elasticity</topic><topic>Enthalpy</topic><topic>Essential oils</topic><topic>Food</topic><topic>Food packaging</topic><topic>Gamma rays</topic><topic>Kinematics</topic><topic>Microorganisms</topic><topic>Oils & fats</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Packaging</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Principal components analysis</topic><topic>Radiation</topic><topic>Radiation dosage</topic><topic>Soft and Granular Matter</topic><topic>Software</topic><topic>Spectrum analysis</topic><topic>Sterilization</topic><topic>Thermodynamic properties</topic><topic>Variance analysis</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Andrade, Michelle Félix</creatorcontrib><creatorcontrib>Caetano, Viviane Fonseca</creatorcontrib><creatorcontrib>de Lima Silva, Ivo Diego</creatorcontrib><creatorcontrib>Azevedo, William Ottoni Barbosa</creatorcontrib><creatorcontrib>de Almeida, Yêda Medeiros Bastos</creatorcontrib><creatorcontrib>Vinhas, Glória Maria</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Andrade, Michelle Félix</au><au>Caetano, Viviane Fonseca</au><au>de Lima Silva, Ivo Diego</au><au>Azevedo, William Ottoni Barbosa</au><au>de Almeida, Yêda Medeiros Bastos</au><au>Vinhas, Glória Maria</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of different gamma radiation doses on the physical, chemical and thermal properties of antimicrobial active packaging of poly (butylene adipate co-terephthalate) (PBAT) films additivated with orange essential oil</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. 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The results of the principal components analysis of the films showed that the applied doses altered the chemical structures of the films, the DSC of the films showed a reduction of their crystallization temperature and an increase in their enthalpy of fusion, indicating a cross-linking, the TGA of the samples revealed that the material remained stable with the doses applied, additionally, the films became more resistant and rigid without losing their elastic behavior. At last, the analyses presented that the additivated PBAT films did not suffer major modifications in their structure due to irradiation, indicating a good radiolytic stability of the PBAT.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-023-05005-y</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-4798-1403</orcidid></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Crosslinking Crystallization Elasticity Enthalpy Essential oils Food Food packaging Gamma rays Kinematics Microorganisms Oils & fats Organic Chemistry Original Paper Packaging Physical Chemistry Polymer Sciences Polymers Principal components analysis Radiation Radiation dosage Soft and Granular Matter Software Spectrum analysis Sterilization Thermodynamic properties Variance analysis Viscosity |
| title | Influence of different gamma radiation doses on the physical, chemical and thermal properties of antimicrobial active packaging of poly (butylene adipate co-terephthalate) (PBAT) films additivated with orange essential oil |
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