The Green Synthesis of 2‐Pyrrolin‐5‐ones from Bio‐renewable Glyoxal, Diketones and Amines
Described herein is an effective and green reaction between diketones, amines and bio‐renewable glyoxal, affording a wide range of 2‐pyrrolin‐5‐ones and releasing water as the only byproduct. The reaction features step‐economy, high efficiency, mild conditions, broad substrate scope, hazardous waste...
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| Veröffentlicht in: | European journal of organic chemistry 2024-04, Vol.27 (13), p.n/a |
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| container_title | European journal of organic chemistry |
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| creator | Oyejobi, Aanuoluwapo O. Gao, Dandan Wang, Jiahua Tang, Xiang‐Ying Wang, Long |
| description | Described herein is an effective and green reaction between diketones, amines and bio‐renewable glyoxal, affording a wide range of 2‐pyrrolin‐5‐ones and releasing water as the only byproduct. The reaction features step‐economy, high efficiency, mild conditions, broad substrate scope, hazardous waste avoiding and easy scale‐up. The further transformation between the products and aldehydes can be potentially applied for fluorescent dye synthesis.
An efficient and environmentally benign method was developed for the synthesis of 2‐pyrrolin‐5‐ones from dicarbonyl compounds, bio‐renewable glyoxal, and amines. More than 25 new 2‐pyrrolin‐5‐one compounds were synthesized in good to high yields under mild conditions. |
| doi_str_mv | 10.1002/ejoc.202400063 |
| format | Article |
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An efficient and environmentally benign method was developed for the synthesis of 2‐pyrrolin‐5‐ones from dicarbonyl compounds, bio‐renewable glyoxal, and amines. More than 25 new 2‐pyrrolin‐5‐one compounds were synthesized in good to high yields under mild conditions.</description><identifier>ISSN: 1434-193X</identifier><identifier>EISSN: 1099-0690</identifier><identifier>DOI: 10.1002/ejoc.202400063</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>2-pyrrolin-5-ones ; Aldehydes ; Amines ; Diketones ; Fluorescent dyes ; glyoxal ; green synthesis ; Hazardous wastes ; Substrates ; Synthesis</subject><ispartof>European journal of organic chemistry, 2024-04, Vol.27 (13), p.n/a</ispartof><rights>2024 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2723-4f0a7022d90187f790490e407db5f7c5d8ece12f68f7a156caefd46620bb49643</cites><orcidid>0000-0001-6218-7681</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejoc.202400063$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejoc.202400063$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Oyejobi, Aanuoluwapo O.</creatorcontrib><creatorcontrib>Gao, Dandan</creatorcontrib><creatorcontrib>Wang, Jiahua</creatorcontrib><creatorcontrib>Tang, Xiang‐Ying</creatorcontrib><creatorcontrib>Wang, Long</creatorcontrib><title>The Green Synthesis of 2‐Pyrrolin‐5‐ones from Bio‐renewable Glyoxal, Diketones and Amines</title><title>European journal of organic chemistry</title><description>Described herein is an effective and green reaction between diketones, amines and bio‐renewable glyoxal, affording a wide range of 2‐pyrrolin‐5‐ones and releasing water as the only byproduct. The reaction features step‐economy, high efficiency, mild conditions, broad substrate scope, hazardous waste avoiding and easy scale‐up. The further transformation between the products and aldehydes can be potentially applied for fluorescent dye synthesis.
An efficient and environmentally benign method was developed for the synthesis of 2‐pyrrolin‐5‐ones from dicarbonyl compounds, bio‐renewable glyoxal, and amines. More than 25 new 2‐pyrrolin‐5‐one compounds were synthesized in good to high yields under mild conditions.</description><subject>2-pyrrolin-5-ones</subject><subject>Aldehydes</subject><subject>Amines</subject><subject>Diketones</subject><subject>Fluorescent dyes</subject><subject>glyoxal</subject><subject>green synthesis</subject><subject>Hazardous wastes</subject><subject>Substrates</subject><subject>Synthesis</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkMFKAzEQhhdRsFavngNe3TrJpsnmWGutSqGCFbwt2d0J3brdaNJS9-Yj-Iw-iakVPXoY8ge-bwb-KDql0KMA7AIXtugxYBwARLIXdSgoFYNQsB8yT3hMVfJ0GB15vwiIEoJ2Ij2bIxk7xIY8tM1qjr7yxBrCPt8_7lvnbF01IfbD2AY9Mc4uyWVlw99hgxud18GvW_um63NyVT3j6pvTTUkGyyrE4-jA6Nrjyc_bjR6vR7PhTTyZjm-Hg0lcMMmSmBvQEhgrFdBUGqmAK0AOssz7Rhb9MsUCKTMiNVLTvig0mpILwSDPuRI86UZnu70vzr6u0a-yhV27JpzMEkhYKqlI00D1dlThrPcOTfbiqqV2bUYh29aYbWvMfmsMgtoJm6rG9h86G91Nh3_uF_8XedM</recordid><startdate>20240402</startdate><enddate>20240402</enddate><creator>Oyejobi, Aanuoluwapo O.</creator><creator>Gao, Dandan</creator><creator>Wang, Jiahua</creator><creator>Tang, Xiang‐Ying</creator><creator>Wang, Long</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6218-7681</orcidid></search><sort><creationdate>20240402</creationdate><title>The Green Synthesis of 2‐Pyrrolin‐5‐ones from Bio‐renewable Glyoxal, Diketones and Amines</title><author>Oyejobi, Aanuoluwapo O. ; Gao, Dandan ; Wang, Jiahua ; Tang, Xiang‐Ying ; Wang, Long</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2723-4f0a7022d90187f790490e407db5f7c5d8ece12f68f7a156caefd46620bb49643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>2-pyrrolin-5-ones</topic><topic>Aldehydes</topic><topic>Amines</topic><topic>Diketones</topic><topic>Fluorescent dyes</topic><topic>glyoxal</topic><topic>green synthesis</topic><topic>Hazardous wastes</topic><topic>Substrates</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oyejobi, Aanuoluwapo O.</creatorcontrib><creatorcontrib>Gao, Dandan</creatorcontrib><creatorcontrib>Wang, Jiahua</creatorcontrib><creatorcontrib>Tang, Xiang‐Ying</creatorcontrib><creatorcontrib>Wang, Long</creatorcontrib><collection>CrossRef</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oyejobi, Aanuoluwapo O.</au><au>Gao, Dandan</au><au>Wang, Jiahua</au><au>Tang, Xiang‐Ying</au><au>Wang, Long</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Green Synthesis of 2‐Pyrrolin‐5‐ones from Bio‐renewable Glyoxal, Diketones and Amines</atitle><jtitle>European journal of organic chemistry</jtitle><date>2024-04-02</date><risdate>2024</risdate><volume>27</volume><issue>13</issue><epage>n/a</epage><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>Described herein is an effective and green reaction between diketones, amines and bio‐renewable glyoxal, affording a wide range of 2‐pyrrolin‐5‐ones and releasing water as the only byproduct. The reaction features step‐economy, high efficiency, mild conditions, broad substrate scope, hazardous waste avoiding and easy scale‐up. The further transformation between the products and aldehydes can be potentially applied for fluorescent dye synthesis.
An efficient and environmentally benign method was developed for the synthesis of 2‐pyrrolin‐5‐ones from dicarbonyl compounds, bio‐renewable glyoxal, and amines. More than 25 new 2‐pyrrolin‐5‐one compounds were synthesized in good to high yields under mild conditions.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ejoc.202400063</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-6218-7681</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | 2-pyrrolin-5-ones Aldehydes Amines Diketones Fluorescent dyes glyoxal green synthesis Hazardous wastes Substrates Synthesis |
| title | The Green Synthesis of 2‐Pyrrolin‐5‐ones from Bio‐renewable Glyoxal, Diketones and Amines |
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