Reactivity of [ReOCl3(PPh3)2] towards substituted anilines

Reactivity of [ReOCl3(PPh3)2] towards substituted anilines

The reactivity of [ReOCl3(PPh3)2] towards o‐toluidine, m‐toluidine, o‐fluoroaniline, m‐fluoroaniline, p‐bromoaniline, p‐chloroaniline and p‐anisidine was examined and novel rhenium(V) imido complexes [Re(NC6H4R)Cl3(PPh3)2] (R=o‐Me, m‐Me, o‐F, m‐F, p‐Cl, p‐Br, p‐OMe) were obtained. The resulting prod...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2024-04, Vol.650 (7), p.n/a
Hauptverfasser: Cvetković, Olivera, Theiner, Johannes, Wolff, Mariusz J., Hultzsch, Kai C.
Format: Artikel
Sprache:eng
Schlagworte:
Aniline
aniline derivatives
Anisidine
Chemical analysis
Crystallography
imido complexes
Infrared spectroscopy
Mass spectrometry
NMR
Nuclear magnetic resonance
Rhenium
Toluidine
X-ray diffraction
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container_title Zeitschrift für anorganische und allgemeine Chemie (1950)
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creator Cvetković, Olivera
Theiner, Johannes
Wolff, Mariusz J.
Hultzsch, Kai C.
description The reactivity of [ReOCl3(PPh3)2] towards o‐toluidine, m‐toluidine, o‐fluoroaniline, m‐fluoroaniline, p‐bromoaniline, p‐chloroaniline and p‐anisidine was examined and novel rhenium(V) imido complexes [Re(NC6H4R)Cl3(PPh3)2] (R=o‐Me, m‐Me, o‐F, m‐F, p‐Cl, p‐Br, p‐OMe) were obtained. The resulting products were characterized by elemental analysis, electrospray ionization high‐resolution mass spectrometry (ESI‐HRMS), 1H, 13C{1H}, 19F and 31P{1H} NMR, FT‐IR spectroscopy, and X‐ray crystallography. For m‐toluidine, m‐fluroaniline and p‐chloroaniline, the rhenium(V) imido‐amino mononuclear [Re(NC6H4R)Cl3(H2NC6H4R)(PPh3)] (R=m‐F, p‐Cl) complexes and the binuclear [{Re(m‐NC6H4Me)Cl2(m‐H2NC6H4Me)(PPh3)}2O] complex were isolated as side products and characterized by X‐ray crystallography. All six‐coordinate rhenium(V) complexes display distorted octahedral coordination geometry.
doi_str_mv 10.1002/zaac.202400007
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subjects Aniline
aniline derivatives
Anisidine
Chemical analysis
Crystallography
imido complexes
Infrared spectroscopy
Mass spectrometry
NMR
Nuclear magnetic resonance
Rhenium
Toluidine
X-ray diffraction
title Reactivity of [ReOCl3(PPh3)2] towards substituted anilines
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