Preparation of a Ce/N-MOF(Fe)@P-C3N4 composite photocatalyst and efficient oxidation of benzene to phenol
The selective photocatalytic oxidation of benzene to phenol under mild conditions is of great significance for the next-generation phenol industry. In this study, a cerium–nitrogen co-doped iron-based metal–organic framework heterogeneous catalyst (Ce/N-MOF(Fe)@P-C3N4) has been synthesized by a one-...
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| Veröffentlicht in: | New journal of chemistry 2024-04, Vol.48 (14), p.6142-6151 |
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| container_title | New journal of chemistry |
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| creator | Wang, Fuying Zhang, Liuxue Liu, Cong Xu, Xuetong Qiao, Jiaolong Xu, Jia Dai, Kefan Wang, Xiulian |
| description | The selective photocatalytic oxidation of benzene to phenol under mild conditions is of great significance for the next-generation phenol industry. In this study, a cerium–nitrogen co-doped iron-based metal–organic framework heterogeneous catalyst (Ce/N-MOF(Fe)@P-C3N4) has been synthesized by a one-step solvothermal method. Under optimized experimental conditions, the synthesized Ce/N-MOF(Fe)@P-C3N4-b photocatalyst showed up to 16.4% yield and 96% selectivity in the direct photocatalytic hydroxylation of benzene to phenol, and the photocatalytic performance did not decrease sharply after five cycles, indicating good stability and reusability. The improved strategy for this catalyst will provide some new insights for the development of more efficient photocatalysts for the direct hydroxylation of benzene to phenol. |
| doi_str_mv | 10.1039/d4nj00192c |
| format | Article |
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In this study, a cerium–nitrogen co-doped iron-based metal–organic framework heterogeneous catalyst (Ce/N-MOF(Fe)@P-C3N4) has been synthesized by a one-step solvothermal method. Under optimized experimental conditions, the synthesized Ce/N-MOF(Fe)@P-C3N4-b photocatalyst showed up to 16.4% yield and 96% selectivity in the direct photocatalytic hydroxylation of benzene to phenol, and the photocatalytic performance did not decrease sharply after five cycles, indicating good stability and reusability. The improved strategy for this catalyst will provide some new insights for the development of more efficient photocatalysts for the direct hydroxylation of benzene to phenol.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d4nj00192c</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Benzene ; Carbon nitride ; Catalysts ; Cerium ; Hydroxylation ; Iron ; Metal-organic frameworks ; Nitrogen ; Oxidation ; Photocatalysis ; Photocatalysts</subject><ispartof>New journal of chemistry, 2024-04, Vol.48 (14), p.6142-6151</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27915,27916</link.rule.ids></links><search><creatorcontrib>Wang, Fuying</creatorcontrib><creatorcontrib>Zhang, Liuxue</creatorcontrib><creatorcontrib>Liu, Cong</creatorcontrib><creatorcontrib>Xu, Xuetong</creatorcontrib><creatorcontrib>Qiao, Jiaolong</creatorcontrib><creatorcontrib>Xu, Jia</creatorcontrib><creatorcontrib>Dai, Kefan</creatorcontrib><creatorcontrib>Wang, Xiulian</creatorcontrib><title>Preparation of a Ce/N-MOF(Fe)@P-C3N4 composite photocatalyst and efficient oxidation of benzene to phenol</title><title>New journal of chemistry</title><description>The selective photocatalytic oxidation of benzene to phenol under mild conditions is of great significance for the next-generation phenol industry. In this study, a cerium–nitrogen co-doped iron-based metal–organic framework heterogeneous catalyst (Ce/N-MOF(Fe)@P-C3N4) has been synthesized by a one-step solvothermal method. Under optimized experimental conditions, the synthesized Ce/N-MOF(Fe)@P-C3N4-b photocatalyst showed up to 16.4% yield and 96% selectivity in the direct photocatalytic hydroxylation of benzene to phenol, and the photocatalytic performance did not decrease sharply after five cycles, indicating good stability and reusability. The improved strategy for this catalyst will provide some new insights for the development of more efficient photocatalysts for the direct hydroxylation of benzene to phenol.</description><subject>Benzene</subject><subject>Carbon nitride</subject><subject>Catalysts</subject><subject>Cerium</subject><subject>Hydroxylation</subject><subject>Iron</subject><subject>Metal-organic frameworks</subject><subject>Nitrogen</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo9jj1PwzAYhC0EEqWw8AssscBg6u_EGygigFTaDjBXdvJapAp2iF0J-PUEgZjuhnvuDqFzRq8ZFWbRyrCjlBneHKAZE9oQwzU7nDyTklAl9TE6SeknwwrNZqjbjDDY0eYuBhw9triCxYo8revLGq5uNqQSK4mb-DbE1GXAw2vMsbHZ9p8pYxtaDN53TQch4_jRtf9FDsIXBMA5TgyE2J-iI2_7BGd_Okcv9d1z9UCW6_vH6nZJBlaKTKa7inplhFWOceC0dL4spIWCO66dok2jVStbz5mTqrBCW9cW2hmnqZxYMUcXv73DGN_3kPJ2F_djmCa3ggqqDTclE9_pw1ei</recordid><startdate>20240402</startdate><enddate>20240402</enddate><creator>Wang, Fuying</creator><creator>Zhang, Liuxue</creator><creator>Liu, Cong</creator><creator>Xu, Xuetong</creator><creator>Qiao, Jiaolong</creator><creator>Xu, Jia</creator><creator>Dai, Kefan</creator><creator>Wang, Xiulian</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope></search><sort><creationdate>20240402</creationdate><title>Preparation of a Ce/N-MOF(Fe)@P-C3N4 composite photocatalyst and efficient oxidation of benzene to phenol</title><author>Wang, Fuying ; Zhang, Liuxue ; Liu, Cong ; Xu, Xuetong ; Qiao, Jiaolong ; Xu, Jia ; Dai, Kefan ; Wang, Xiulian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p183t-26150f593a5b12e208bf874ae72b26b50cc65d4df21b457a36abd76b9b6046153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Benzene</topic><topic>Carbon nitride</topic><topic>Catalysts</topic><topic>Cerium</topic><topic>Hydroxylation</topic><topic>Iron</topic><topic>Metal-organic frameworks</topic><topic>Nitrogen</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Fuying</creatorcontrib><creatorcontrib>Zhang, Liuxue</creatorcontrib><creatorcontrib>Liu, Cong</creatorcontrib><creatorcontrib>Xu, Xuetong</creatorcontrib><creatorcontrib>Qiao, Jiaolong</creatorcontrib><creatorcontrib>Xu, Jia</creatorcontrib><creatorcontrib>Dai, Kefan</creatorcontrib><creatorcontrib>Wang, Xiulian</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Fuying</au><au>Zhang, Liuxue</au><au>Liu, Cong</au><au>Xu, Xuetong</au><au>Qiao, Jiaolong</au><au>Xu, Jia</au><au>Dai, Kefan</au><au>Wang, Xiulian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of a Ce/N-MOF(Fe)@P-C3N4 composite photocatalyst and efficient oxidation of benzene to phenol</atitle><jtitle>New journal of chemistry</jtitle><date>2024-04-02</date><risdate>2024</risdate><volume>48</volume><issue>14</issue><spage>6142</spage><epage>6151</epage><pages>6142-6151</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>The selective photocatalytic oxidation of benzene to phenol under mild conditions is of great significance for the next-generation phenol industry. In this study, a cerium–nitrogen co-doped iron-based metal–organic framework heterogeneous catalyst (Ce/N-MOF(Fe)@P-C3N4) has been synthesized by a one-step solvothermal method. Under optimized experimental conditions, the synthesized Ce/N-MOF(Fe)@P-C3N4-b photocatalyst showed up to 16.4% yield and 96% selectivity in the direct photocatalytic hydroxylation of benzene to phenol, and the photocatalytic performance did not decrease sharply after five cycles, indicating good stability and reusability. The improved strategy for this catalyst will provide some new insights for the development of more efficient photocatalysts for the direct hydroxylation of benzene to phenol.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4nj00192c</doi><tpages>10</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Benzene Carbon nitride Catalysts Cerium Hydroxylation Iron Metal-organic frameworks Nitrogen Oxidation Photocatalysis Photocatalysts |
| title | Preparation of a Ce/N-MOF(Fe)@P-C3N4 composite photocatalyst and efficient oxidation of benzene to phenol |
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