Anti‐Markovnikov Hydroamination and Hydroalkoxylation of Allylic Alcohols Promoted by a Simple Rare‐Earth Metal Trialkyl Complex

An exclusive anti‐Markovnikov hydroamination as well as hydroalkoxylation of allylic alcohols catalyzed by a simple catalyst Y(CH2SiMe3)3(THF)2 has been developed, providing a variety of γ‐amino and γ‐alkoxy alcohols in good yields under mild conditions. Moreover, this protocol is applied to the syn...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Advanced synthesis & catalysis 2024-03, Vol.366 (6), p.1405-1411
Hauptverfasser:	Zhu, Xiancui, Sun, Jinrong, Wu, Zhixin, Guo, Dianjun, Zhou, Shuangliu, Wang, Shaowu
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols allylic alcohols Catalysts Chemical synthesis hydroalkoxylation hydroamination rare-earth metal catalysts Substrates γ-functionalized alcohols
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!