Synthesis, Structural, and Photoluminescence Studies of Tb3+ Activated Y2SiO5 Phosphor for Display Devices

The synthesis and luminescence analysis of Tb 3+ -activated phosphors were reported. Y 2 SiO 5 phosphors were synthesized by a modified solid-state reaction method with a variable doping concentration of Tb 3+ ion (0.5–2.5 mol.%). As synthesized, the phosphors were characterized by X-ray diffraction...

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Veröffentlicht in:Journal of applied spectroscopy 2024-03, Vol.91 (1), p.154-158
Hauptverfasser: Mishra, Vikas, Singh, Sudhakar, Dubey, Vikas, Kshatri, Dhirendra Singh, Patharia, Pragati, Dubey, Neha, Rao, M. C.
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container_issue 1
container_start_page 154
container_title Journal of applied spectroscopy
container_volume 91
creator Mishra, Vikas
Singh, Sudhakar
Dubey, Vikas
Kshatri, Dhirendra Singh
Patharia, Pragati
Dubey, Neha
Rao, M. C.
description The synthesis and luminescence analysis of Tb 3+ -activated phosphors were reported. Y 2 SiO 5 phosphors were synthesized by a modified solid-state reaction method with a variable doping concentration of Tb 3+ ion (0.5–2.5 mol.%). As synthesized, the phosphors were characterized by X-ray diffraction (XRD) analysis. The XRD pattern confirmed the monoclinic structure of the prepared phosphor. Scanning electron microscopy and High-Resolution Transmission Electron Microscopy (HRTEM) studies revealed nearly uniform particle size distribution in the prepared phosphors. The photoluminescence excitation spectra of the Y 2 SiO 5 :Tb 3+ (0.5–2.5 mol.%) phosphor displayed one broad, intense peak at 258–277 nm. When excited at the 258 nm wavelength, the phosphors showed emission peaks at 553 nm ( 5 D 4 → 7 F 5 ), 544 nm ( 5 D 4 → 7 F 5 ) and 489 nm ( 5 D 4 → 7 F 6 ). The 1931 CIE ( x , y ) chromaticity coordinates showed the distribution of the spectral region calculated from the photoluminescence emission spectra. The values of x = 0.25 and y = 0.46 were very close to light green emission. Therefore, the prepared phosphor is very useful for light-emitting diode (green component) applications.
doi_str_mv 10.1007/s10812-024-01701-3
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Y 2 SiO 5 phosphors were synthesized by a modified solid-state reaction method with a variable doping concentration of Tb 3+ ion (0.5–2.5 mol.%). As synthesized, the phosphors were characterized by X-ray diffraction (XRD) analysis. The XRD pattern confirmed the monoclinic structure of the prepared phosphor. Scanning electron microscopy and High-Resolution Transmission Electron Microscopy (HRTEM) studies revealed nearly uniform particle size distribution in the prepared phosphors. The photoluminescence excitation spectra of the Y 2 SiO 5 :Tb 3+ (0.5–2.5 mol.%) phosphor displayed one broad, intense peak at 258–277 nm. When excited at the 258 nm wavelength, the phosphors showed emission peaks at 553 nm ( 5 D 4 → 7 F 5 ), 544 nm ( 5 D 4 → 7 F 5 ) and 489 nm ( 5 D 4 → 7 F 6 ). The 1931 CIE ( x , y ) chromaticity coordinates showed the distribution of the spectral region calculated from the photoluminescence emission spectra. 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subjects Analytical Chemistry
Atomic/Molecular Structure and Spectra
Chromaticity
Diffraction patterns
Display devices
Emission spectra
Excitation spectra
High resolution electron microscopy
Light emitting diodes
Mathematical analysis
Microscopy
Particle size distribution
Pattern analysis
Phosphors
Photoluminescence
Physics
Physics and Astronomy
X-ray diffraction
title Synthesis, Structural, and Photoluminescence Studies of Tb3+ Activated Y2SiO5 Phosphor for Display Devices
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