Thermofrost-Resistant Poly[dimethyl(methylbenzyl)siloxanes]: Synthesis and Properties
A series of poly[dimethyl(methylbenzyl)siloxanes] with different content of the methylbenzylsiloxane fragments have been synthesized. Structure of the polymers has been confirmed by means of 1 Н and 29 Si NMR spectroscopy. Thermal properties of the polymers have been investigated by means of differe...
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| Veröffentlicht in: | Polymer science. Series B 2023-12, Vol.65 (6), p.812-820 |
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| container_title | Polymer science. Series B |
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| creator | Olenich, E. A. Gorodov, V. V. Milenin, S. A. Cherkaev, G. V. Khanin, D. A. Buzin, M. I. Muzafarov, A. M. |
| description | A series of poly[dimethyl(methylbenzyl)siloxanes] with different content of the methylbenzylsiloxane fragments have been synthesized. Structure of the polymers has been confirmed by means of
1
Н and
29
Si NMR spectroscopy. Thermal properties of the polymers have been investigated by means of differential scanning calorimetry and thermogravimetric analysis. It has been found that the copolymer crystallization is suppressed at the content of the methylbenzylsiloxane fragments on the copolymer of 3 mol % and higher, while the glass transition temperature is only insignificantly shifted towards the positive range. The copolymers have exhibited high temperature resistance and can be used over a wide temperature range. |
| doi_str_mv | 10.1134/S1560090424600050 |
| format | Article |
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1
Н and
29
Si NMR spectroscopy. Thermal properties of the polymers have been investigated by means of differential scanning calorimetry and thermogravimetric analysis. It has been found that the copolymer crystallization is suppressed at the content of the methylbenzylsiloxane fragments on the copolymer of 3 mol % and higher, while the glass transition temperature is only insignificantly shifted towards the positive range. The copolymers have exhibited high temperature resistance and can be used over a wide temperature range.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090424600050</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Copolymers ; Crystallization ; Fragments ; Functional Polymers ; Glass transition temperature ; High temperature ; NMR spectroscopy ; Polymer Sciences ; Polymers ; Siloxanes ; Thermodynamic properties ; Thermogravimetric analysis</subject><ispartof>Polymer science. Series B, 2023-12, Vol.65 (6), p.812-820</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 1560-0904, Polymer Science, Series B, 2023, Vol. 65, No. 6, pp. 812–820. © Pleiades Publishing, Ltd., 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-f2d1df89a506ea63fe95cb751d2793ab729b14d8a1926af8e1354f09d605debb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1560090424600050$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1560090424600050$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Olenich, E. A.</creatorcontrib><creatorcontrib>Gorodov, V. V.</creatorcontrib><creatorcontrib>Milenin, S. A.</creatorcontrib><creatorcontrib>Cherkaev, G. V.</creatorcontrib><creatorcontrib>Khanin, D. A.</creatorcontrib><creatorcontrib>Buzin, M. I.</creatorcontrib><creatorcontrib>Muzafarov, A. M.</creatorcontrib><title>Thermofrost-Resistant Poly[dimethyl(methylbenzyl)siloxanes]: Synthesis and Properties</title><title>Polymer science. Series B</title><addtitle>Polym. Sci. Ser. B</addtitle><description>A series of poly[dimethyl(methylbenzyl)siloxanes] with different content of the methylbenzylsiloxane fragments have been synthesized. Structure of the polymers has been confirmed by means of
1
Н and
29
Si NMR spectroscopy. Thermal properties of the polymers have been investigated by means of differential scanning calorimetry and thermogravimetric analysis. It has been found that the copolymer crystallization is suppressed at the content of the methylbenzylsiloxane fragments on the copolymer of 3 mol % and higher, while the glass transition temperature is only insignificantly shifted towards the positive range. The copolymers have exhibited high temperature resistance and can be used over a wide temperature range.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymers</subject><subject>Crystallization</subject><subject>Fragments</subject><subject>Functional Polymers</subject><subject>Glass transition temperature</subject><subject>High temperature</subject><subject>NMR spectroscopy</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Siloxanes</subject><subject>Thermodynamic properties</subject><subject>Thermogravimetric analysis</subject><issn>1560-0904</issn><issn>1555-6123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsGg_gLeAFz1Ed3azm6w3Kf6DgsW2J5Gw6c7alDSpu1swfnoTIngQT29gfu8N8wg5A3oFwJPrOQhJqaIJSzqlgh6QEQghYgmMH_azpHG_PyZj7zcdQrniAGpElos1um1jXeND_IK-9EHXIZo1Vftqyi2GdVtdDFJg_dVWl76smk9do3-7ieZtHda9KdK1iWau2aELJfpTcmR15XH8oydkeX-3mDzG0-eHp8ntNF4xmYXYMgPGZkoLKlFLblGJVZEKMCxVXBcpUwUkJtOgmNQ2Q-AisVQZSYXBouAn5HzI3bnmY48-5Jtm7-ruZM5UyqUQKZUdBQO16r70Dm2-c-VWuzYHmvcF5n8K7Dxs8PiOrd_R_Sb_b_oGSPxzYw</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Olenich, E. A.</creator><creator>Gorodov, V. V.</creator><creator>Milenin, S. A.</creator><creator>Cherkaev, G. V.</creator><creator>Khanin, D. A.</creator><creator>Buzin, M. I.</creator><creator>Muzafarov, A. M.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231201</creationdate><title>Thermofrost-Resistant Poly[dimethyl(methylbenzyl)siloxanes]: Synthesis and Properties</title><author>Olenich, E. A. ; Gorodov, V. V. ; Milenin, S. A. ; Cherkaev, G. V. ; Khanin, D. A. ; Buzin, M. I. ; Muzafarov, A. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-f2d1df89a506ea63fe95cb751d2793ab729b14d8a1926af8e1354f09d605debb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymers</topic><topic>Crystallization</topic><topic>Fragments</topic><topic>Functional Polymers</topic><topic>Glass transition temperature</topic><topic>High temperature</topic><topic>NMR spectroscopy</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Siloxanes</topic><topic>Thermodynamic properties</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Olenich, E. A.</creatorcontrib><creatorcontrib>Gorodov, V. V.</creatorcontrib><creatorcontrib>Milenin, S. A.</creatorcontrib><creatorcontrib>Cherkaev, G. V.</creatorcontrib><creatorcontrib>Khanin, D. A.</creatorcontrib><creatorcontrib>Buzin, M. I.</creatorcontrib><creatorcontrib>Muzafarov, A. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer science. Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Olenich, E. A.</au><au>Gorodov, V. V.</au><au>Milenin, S. A.</au><au>Cherkaev, G. V.</au><au>Khanin, D. A.</au><au>Buzin, M. I.</au><au>Muzafarov, A. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermofrost-Resistant Poly[dimethyl(methylbenzyl)siloxanes]: Synthesis and Properties</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>65</volume><issue>6</issue><spage>812</spage><epage>820</epage><pages>812-820</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>A series of poly[dimethyl(methylbenzyl)siloxanes] with different content of the methylbenzylsiloxane fragments have been synthesized. Structure of the polymers has been confirmed by means of
1
Н and
29
Si NMR spectroscopy. Thermal properties of the polymers have been investigated by means of differential scanning calorimetry and thermogravimetric analysis. It has been found that the copolymer crystallization is suppressed at the content of the methylbenzylsiloxane fragments on the copolymer of 3 mol % and higher, while the glass transition temperature is only insignificantly shifted towards the positive range. The copolymers have exhibited high temperature resistance and can be used over a wide temperature range.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1560090424600050</doi><tpages>9</tpages></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Copolymers Crystallization Fragments Functional Polymers Glass transition temperature High temperature NMR spectroscopy Polymer Sciences Polymers Siloxanes Thermodynamic properties Thermogravimetric analysis |
| title | Thermofrost-Resistant Poly[dimethyl(methylbenzyl)siloxanes]: Synthesis and Properties |
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