Nickel Nanoparticle-Directed Flow Synthesis of Biodiesel from Waste Cooking Oil
Geopolitical turmoil and energy security drive the global demand of renewable fuel for affordable transportation purpose. Developing countries are divesting conventional agrarian products and simultaneously investing on biodiesel research to capture a significant renewable market share. The most pro...
Gespeichert in:
| Veröffentlicht in: | Waste and biomass valorization 2024-03, Vol.15 (3), p.1391-1402 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1402 |
|---|---|
| container_issue | 3 |
| container_start_page | 1391 |
| container_title | Waste and biomass valorization |
| container_volume | 15 |
| creator | Shukla, Raman Jaiswal, Pooja Maharana, Ashutosh Panda, Debashis Biswas, Koushik Guha |
| description | Geopolitical turmoil and energy security drive the global demand of renewable fuel for affordable transportation purpose. Developing countries are divesting conventional agrarian products and simultaneously investing on biodiesel research to capture a significant renewable market share. The most promising features of biodiesel that are nothing, but methyl/ethyl esters of fatty acids are considered as clean fuel due to reduced CO
2
emission, less toxic, and biodegradable as well. Earlier the synthesis of biodiesel from fatty acids are performed by energy-intensive batch processes. In this work, we have designed a helical-straight-helical (HSH) glass reactor of one meter length with 5 mm internal diameter for flow synthesis of biodiesel. Transesterification reaction has been performed carried in a HSH flow reactor for conversion of waste cooking oil and crude palm oil to biodiesel. Magnetic Nickel nanoparticle has been utilized in presence alkali KOH as well for catalytic conversion of fatty acids. Progress of reaction has been visualized by capturing images at different zones of reactor. Biodiesel production has been optimized by varying the flow-rate and molar ratio between methanol and oil. In continuous synthesis at an oil flow rate of 350 µL/min, 12:1 molar ratio and 70 °C temperature we have achieved 82% conversion for waste cooking oil and 92% for crude palm oil to biodiesel. Biodiesel obtained has also been characterized from its properties like density, kinematic viscosity, calorific value, and acid value from both the feedstock and was found in the range of ASTM standards.
Graphical Abstract |
| doi_str_mv | 10.1007/s12649-023-02221-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2973435267</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2973435267</sourcerecordid><originalsourceid>FETCH-LOGICAL-c270t-18dc20a2e2d6883ce2db5c4b3fb5b9e1eca989b0ece6ea024f9559567d60b9b33</originalsourceid><addsrcrecordid>eNp9kMtOwzAQRS0EElXpD7CyxDrgRxzHSyhPqWoXgGBnOc6kuE3jYqdC_XsMQbBjMbqzuGdGOgidUnJOCZEXkbIiVxlhPA1jNBMHaERLKTNWiNfD3z2nx2gS44oQwigtGZcjtJg7u4YWz03ntyb0zraQXbsAtoca37b-Az_uu_4NoovYN_jK-dpBTEQT_Aa_mNgDnnq_dt0SL1x7go4a00aY_OQYPd_ePE3vs9ni7mF6Ocssk6TPaFlbRgwDVhdlyW3KSti84k0lKgUUrFGlqghYKMAQljdKCCUKWRekUhXnY3Q23N0G_76D2OuV34UuvdRMSZ5zwQqZWmxo2eBjDNDobXAbE_aaEv3lTg_udHKnv91pkSA-QDGVuyWEv9P_UJ-tW3GA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2973435267</pqid></control><display><type>article</type><title>Nickel Nanoparticle-Directed Flow Synthesis of Biodiesel from Waste Cooking Oil</title><source>SpringerLink Journals</source><creator>Shukla, Raman ; Jaiswal, Pooja ; Maharana, Ashutosh ; Panda, Debashis ; Biswas, Koushik Guha</creator><creatorcontrib>Shukla, Raman ; Jaiswal, Pooja ; Maharana, Ashutosh ; Panda, Debashis ; Biswas, Koushik Guha</creatorcontrib><description>Geopolitical turmoil and energy security drive the global demand of renewable fuel for affordable transportation purpose. Developing countries are divesting conventional agrarian products and simultaneously investing on biodiesel research to capture a significant renewable market share. The most promising features of biodiesel that are nothing, but methyl/ethyl esters of fatty acids are considered as clean fuel due to reduced CO
2
emission, less toxic, and biodegradable as well. Earlier the synthesis of biodiesel from fatty acids are performed by energy-intensive batch processes. In this work, we have designed a helical-straight-helical (HSH) glass reactor of one meter length with 5 mm internal diameter for flow synthesis of biodiesel. Transesterification reaction has been performed carried in a HSH flow reactor for conversion of waste cooking oil and crude palm oil to biodiesel. Magnetic Nickel nanoparticle has been utilized in presence alkali KOH as well for catalytic conversion of fatty acids. Progress of reaction has been visualized by capturing images at different zones of reactor. Biodiesel production has been optimized by varying the flow-rate and molar ratio between methanol and oil. In continuous synthesis at an oil flow rate of 350 µL/min, 12:1 molar ratio and 70 °C temperature we have achieved 82% conversion for waste cooking oil and 92% for crude palm oil to biodiesel. Biodiesel obtained has also been characterized from its properties like density, kinematic viscosity, calorific value, and acid value from both the feedstock and was found in the range of ASTM standards.
Graphical Abstract</description><identifier>ISSN: 1877-2641</identifier><identifier>EISSN: 1877-265X</identifier><identifier>DOI: 10.1007/s12649-023-02221-5</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Batch processes ; Batch processing ; Biodegradation ; Biodiesel fuels ; Biofuels ; Calorific value ; Carbon dioxide ; Carbon dioxide emissions ; Catalytic converters ; Chemical synthesis ; Clean fuels ; Cooking ; Cooking oils ; Developing countries ; Diesel ; Energy security ; Engineering ; Environment ; Environmental Engineering/Biotechnology ; Esters ; Ethyl esters ; Fatty acids ; Flow rates ; Industrial Pollution Prevention ; Kinematic viscosity ; Kinematics ; LDCs ; Nanoparticles ; Nickel ; Oil wastes ; Original Paper ; Palm oil ; Reactors ; Renewable and Green Energy ; Renewable fuels ; Transesterification ; Waste Management/Waste Technology</subject><ispartof>Waste and biomass valorization, 2024-03, Vol.15 (3), p.1391-1402</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-18dc20a2e2d6883ce2db5c4b3fb5b9e1eca989b0ece6ea024f9559567d60b9b33</cites><orcidid>0000-0002-2333-3735 ; 0000-0001-9081-3627</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12649-023-02221-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12649-023-02221-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Shukla, Raman</creatorcontrib><creatorcontrib>Jaiswal, Pooja</creatorcontrib><creatorcontrib>Maharana, Ashutosh</creatorcontrib><creatorcontrib>Panda, Debashis</creatorcontrib><creatorcontrib>Biswas, Koushik Guha</creatorcontrib><title>Nickel Nanoparticle-Directed Flow Synthesis of Biodiesel from Waste Cooking Oil</title><title>Waste and biomass valorization</title><addtitle>Waste Biomass Valor</addtitle><description>Geopolitical turmoil and energy security drive the global demand of renewable fuel for affordable transportation purpose. Developing countries are divesting conventional agrarian products and simultaneously investing on biodiesel research to capture a significant renewable market share. The most promising features of biodiesel that are nothing, but methyl/ethyl esters of fatty acids are considered as clean fuel due to reduced CO
2
emission, less toxic, and biodegradable as well. Earlier the synthesis of biodiesel from fatty acids are performed by energy-intensive batch processes. In this work, we have designed a helical-straight-helical (HSH) glass reactor of one meter length with 5 mm internal diameter for flow synthesis of biodiesel. Transesterification reaction has been performed carried in a HSH flow reactor for conversion of waste cooking oil and crude palm oil to biodiesel. Magnetic Nickel nanoparticle has been utilized in presence alkali KOH as well for catalytic conversion of fatty acids. Progress of reaction has been visualized by capturing images at different zones of reactor. Biodiesel production has been optimized by varying the flow-rate and molar ratio between methanol and oil. In continuous synthesis at an oil flow rate of 350 µL/min, 12:1 molar ratio and 70 °C temperature we have achieved 82% conversion for waste cooking oil and 92% for crude palm oil to biodiesel. Biodiesel obtained has also been characterized from its properties like density, kinematic viscosity, calorific value, and acid value from both the feedstock and was found in the range of ASTM standards.
Graphical Abstract</description><subject>Batch processes</subject><subject>Batch processing</subject><subject>Biodegradation</subject><subject>Biodiesel fuels</subject><subject>Biofuels</subject><subject>Calorific value</subject><subject>Carbon dioxide</subject><subject>Carbon dioxide emissions</subject><subject>Catalytic converters</subject><subject>Chemical synthesis</subject><subject>Clean fuels</subject><subject>Cooking</subject><subject>Cooking oils</subject><subject>Developing countries</subject><subject>Diesel</subject><subject>Energy security</subject><subject>Engineering</subject><subject>Environment</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Esters</subject><subject>Ethyl esters</subject><subject>Fatty acids</subject><subject>Flow rates</subject><subject>Industrial Pollution Prevention</subject><subject>Kinematic viscosity</subject><subject>Kinematics</subject><subject>LDCs</subject><subject>Nanoparticles</subject><subject>Nickel</subject><subject>Oil wastes</subject><subject>Original Paper</subject><subject>Palm oil</subject><subject>Reactors</subject><subject>Renewable and Green Energy</subject><subject>Renewable fuels</subject><subject>Transesterification</subject><subject>Waste Management/Waste Technology</subject><issn>1877-2641</issn><issn>1877-265X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EElXpD7CyxDrgRxzHSyhPqWoXgGBnOc6kuE3jYqdC_XsMQbBjMbqzuGdGOgidUnJOCZEXkbIiVxlhPA1jNBMHaERLKTNWiNfD3z2nx2gS44oQwigtGZcjtJg7u4YWz03ntyb0zraQXbsAtoca37b-Az_uu_4NoovYN_jK-dpBTEQT_Aa_mNgDnnq_dt0SL1x7go4a00aY_OQYPd_ePE3vs9ni7mF6Ocssk6TPaFlbRgwDVhdlyW3KSti84k0lKgUUrFGlqghYKMAQljdKCCUKWRekUhXnY3Q23N0G_76D2OuV34UuvdRMSZ5zwQqZWmxo2eBjDNDobXAbE_aaEv3lTg_udHKnv91pkSA-QDGVuyWEv9P_UJ-tW3GA</recordid><startdate>20240301</startdate><enddate>20240301</enddate><creator>Shukla, Raman</creator><creator>Jaiswal, Pooja</creator><creator>Maharana, Ashutosh</creator><creator>Panda, Debashis</creator><creator>Biswas, Koushik Guha</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2333-3735</orcidid><orcidid>https://orcid.org/0000-0001-9081-3627</orcidid></search><sort><creationdate>20240301</creationdate><title>Nickel Nanoparticle-Directed Flow Synthesis of Biodiesel from Waste Cooking Oil</title><author>Shukla, Raman ; Jaiswal, Pooja ; Maharana, Ashutosh ; Panda, Debashis ; Biswas, Koushik Guha</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-18dc20a2e2d6883ce2db5c4b3fb5b9e1eca989b0ece6ea024f9559567d60b9b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Batch processes</topic><topic>Batch processing</topic><topic>Biodegradation</topic><topic>Biodiesel fuels</topic><topic>Biofuels</topic><topic>Calorific value</topic><topic>Carbon dioxide</topic><topic>Carbon dioxide emissions</topic><topic>Catalytic converters</topic><topic>Chemical synthesis</topic><topic>Clean fuels</topic><topic>Cooking</topic><topic>Cooking oils</topic><topic>Developing countries</topic><topic>Diesel</topic><topic>Energy security</topic><topic>Engineering</topic><topic>Environment</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Esters</topic><topic>Ethyl esters</topic><topic>Fatty acids</topic><topic>Flow rates</topic><topic>Industrial Pollution Prevention</topic><topic>Kinematic viscosity</topic><topic>Kinematics</topic><topic>LDCs</topic><topic>Nanoparticles</topic><topic>Nickel</topic><topic>Oil wastes</topic><topic>Original Paper</topic><topic>Palm oil</topic><topic>Reactors</topic><topic>Renewable and Green Energy</topic><topic>Renewable fuels</topic><topic>Transesterification</topic><topic>Waste Management/Waste Technology</topic><toplevel>online_resources</toplevel><creatorcontrib>Shukla, Raman</creatorcontrib><creatorcontrib>Jaiswal, Pooja</creatorcontrib><creatorcontrib>Maharana, Ashutosh</creatorcontrib><creatorcontrib>Panda, Debashis</creatorcontrib><creatorcontrib>Biswas, Koushik Guha</creatorcontrib><collection>CrossRef</collection><jtitle>Waste and biomass valorization</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shukla, Raman</au><au>Jaiswal, Pooja</au><au>Maharana, Ashutosh</au><au>Panda, Debashis</au><au>Biswas, Koushik Guha</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel Nanoparticle-Directed Flow Synthesis of Biodiesel from Waste Cooking Oil</atitle><jtitle>Waste and biomass valorization</jtitle><stitle>Waste Biomass Valor</stitle><date>2024-03-01</date><risdate>2024</risdate><volume>15</volume><issue>3</issue><spage>1391</spage><epage>1402</epage><pages>1391-1402</pages><issn>1877-2641</issn><eissn>1877-265X</eissn><abstract>Geopolitical turmoil and energy security drive the global demand of renewable fuel for affordable transportation purpose. Developing countries are divesting conventional agrarian products and simultaneously investing on biodiesel research to capture a significant renewable market share. The most promising features of biodiesel that are nothing, but methyl/ethyl esters of fatty acids are considered as clean fuel due to reduced CO
2
emission, less toxic, and biodegradable as well. Earlier the synthesis of biodiesel from fatty acids are performed by energy-intensive batch processes. In this work, we have designed a helical-straight-helical (HSH) glass reactor of one meter length with 5 mm internal diameter for flow synthesis of biodiesel. Transesterification reaction has been performed carried in a HSH flow reactor for conversion of waste cooking oil and crude palm oil to biodiesel. Magnetic Nickel nanoparticle has been utilized in presence alkali KOH as well for catalytic conversion of fatty acids. Progress of reaction has been visualized by capturing images at different zones of reactor. Biodiesel production has been optimized by varying the flow-rate and molar ratio between methanol and oil. In continuous synthesis at an oil flow rate of 350 µL/min, 12:1 molar ratio and 70 °C temperature we have achieved 82% conversion for waste cooking oil and 92% for crude palm oil to biodiesel. Biodiesel obtained has also been characterized from its properties like density, kinematic viscosity, calorific value, and acid value from both the feedstock and was found in the range of ASTM standards.
Graphical Abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s12649-023-02221-5</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-2333-3735</orcidid><orcidid>https://orcid.org/0000-0001-9081-3627</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1877-2641 |
| ispartof | Waste and biomass valorization, 2024-03, Vol.15 (3), p.1391-1402 |
| issn | 1877-2641 1877-265X |
| language | eng |
| recordid | cdi_proquest_journals_2973435267 |
| source | SpringerLink Journals |
| subjects | Batch processes Batch processing Biodegradation Biodiesel fuels Biofuels Calorific value Carbon dioxide Carbon dioxide emissions Catalytic converters Chemical synthesis Clean fuels Cooking Cooking oils Developing countries Diesel Energy security Engineering Environment Environmental Engineering/Biotechnology Esters Ethyl esters Fatty acids Flow rates Industrial Pollution Prevention Kinematic viscosity Kinematics LDCs Nanoparticles Nickel Oil wastes Original Paper Palm oil Reactors Renewable and Green Energy Renewable fuels Transesterification Waste Management/Waste Technology |
| title | Nickel Nanoparticle-Directed Flow Synthesis of Biodiesel from Waste Cooking Oil |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T07%3A46%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Nickel%20Nanoparticle-Directed%20Flow%20Synthesis%20of%20Biodiesel%20from%20Waste%20Cooking%20Oil&rft.jtitle=Waste%20and%20biomass%20valorization&rft.au=Shukla,%20Raman&rft.date=2024-03-01&rft.volume=15&rft.issue=3&rft.spage=1391&rft.epage=1402&rft.pages=1391-1402&rft.issn=1877-2641&rft.eissn=1877-265X&rft_id=info:doi/10.1007/s12649-023-02221-5&rft_dat=%3Cproquest_cross%3E2973435267%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2973435267&rft_id=info:pmid/&rfr_iscdi=true |