Study of the Physical and Mechanical Properties and Quality of the FDM Printing of High-Pressure Polyethylene/Al2O3 Nanofiber Nanocomposites
The influence of modified Nafen fibers and the nozzle temperature of a 3D printer on the physical and mechanical properties and printability of high-pressure polyethylene (HPP)/Al 2 O 3 nanofiber (Nafen) nanocomposite is studied. It is found that the modification of HPP with Nafen fibers, as well as...
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Veröffentlicht in: | Nanobiotechnology Reports (Online) 2023-12, Vol.18 (Suppl 1), p.S127-S135 |
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creator | Kondrashov, S. V. Gurov, D. A. Guseva, M. A. Shumskaya, S. A. |
description | The influence of modified Nafen fibers and the nozzle temperature of a 3D printer on the physical and mechanical properties and printability of high-pressure polyethylene (HPP)/Al
2
O
3
nanofiber (Nafen) nanocomposite is studied. It is found that the modification of HPP with Nafen fibers, as well as an increase in the temperature of the nozzle of the 3D printer leads to a decrease in warping of the HPP printed on a “cold” workbench. A change in the structure of thin film samples obtained by fused deposition modeling (FDM) printing with a change in the extrusion temperature and the modification of HPP with Nafen nanofibers is proven. An increase in the nozzle temperature and modification of the polymer matrix leads to an increase in the relaxation time of the material structure, which under conditions of rapid cooling contributes to the implementation of a metastable state characterized by a lower density of the fluctuation network in the amorphous part of the HPP. The relationship between the change in the free volume determining the shrinkage of the material during the FDM process, and the change in the melt cooling viscosity and its relaxation time is shown. |
doi_str_mv | 10.1134/S263516762360075X |
format | Article |
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2
O
3
nanofiber (Nafen) nanocomposite is studied. It is found that the modification of HPP with Nafen fibers, as well as an increase in the temperature of the nozzle of the 3D printer leads to a decrease in warping of the HPP printed on a “cold” workbench. A change in the structure of thin film samples obtained by fused deposition modeling (FDM) printing with a change in the extrusion temperature and the modification of HPP with Nafen nanofibers is proven. An increase in the nozzle temperature and modification of the polymer matrix leads to an increase in the relaxation time of the material structure, which under conditions of rapid cooling contributes to the implementation of a metastable state characterized by a lower density of the fluctuation network in the amorphous part of the HPP. The relationship between the change in the free volume determining the shrinkage of the material during the FDM process, and the change in the melt cooling viscosity and its relaxation time is shown.</description><identifier>ISSN: 2635-1676</identifier><identifier>ISSN: 1995-0780</identifier><identifier>EISSN: 2635-1684</identifier><identifier>EISSN: 1995-0799</identifier><identifier>DOI: 10.1134/S263516762360075X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>3-D printers ; Aluminum oxide ; Bioorganic ; Chemistry and Materials Science ; Cooling ; Fused deposition modeling ; High pressure ; Hybrid Nanomaterials ; Industrial and Production Engineering ; Machines ; Manufacturing ; Materials Science ; Mechanical properties ; Metastable state ; Nanocomposites ; Nanofibers ; Nanotechnology ; Nozzles ; Physical properties ; Polyethylene ; Polyethylenes ; Polymer ; Processes ; Relaxation time ; Thin films ; Three dimensional printing</subject><ispartof>Nanobiotechnology Reports (Online), 2023-12, Vol.18 (Suppl 1), p.S127-S135</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 2635-1676, Nanobiotechnology Reports, 2023, Vol. 18, Suppl. 1, pp. S127–S135. © Pleiades Publishing, Ltd., 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-f1bcc5b6ec159a078e6bc5ffee6e900730e81ac2dcaa81a39c9a538dd8236a7a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S263516762360075X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S263516762360075X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Kondrashov, S. V.</creatorcontrib><creatorcontrib>Gurov, D. A.</creatorcontrib><creatorcontrib>Guseva, M. A.</creatorcontrib><creatorcontrib>Shumskaya, S. A.</creatorcontrib><title>Study of the Physical and Mechanical Properties and Quality of the FDM Printing of High-Pressure Polyethylene/Al2O3 Nanofiber Nanocomposites</title><title>Nanobiotechnology Reports (Online)</title><addtitle>Nanotechnol Russia</addtitle><description>The influence of modified Nafen fibers and the nozzle temperature of a 3D printer on the physical and mechanical properties and printability of high-pressure polyethylene (HPP)/Al
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nanofiber (Nafen) nanocomposite is studied. It is found that the modification of HPP with Nafen fibers, as well as an increase in the temperature of the nozzle of the 3D printer leads to a decrease in warping of the HPP printed on a “cold” workbench. A change in the structure of thin film samples obtained by fused deposition modeling (FDM) printing with a change in the extrusion temperature and the modification of HPP with Nafen nanofibers is proven. An increase in the nozzle temperature and modification of the polymer matrix leads to an increase in the relaxation time of the material structure, which under conditions of rapid cooling contributes to the implementation of a metastable state characterized by a lower density of the fluctuation network in the amorphous part of the HPP. The relationship between the change in the free volume determining the shrinkage of the material during the FDM process, and the change in the melt cooling viscosity and its relaxation time is shown.</description><subject>3-D printers</subject><subject>Aluminum oxide</subject><subject>Bioorganic</subject><subject>Chemistry and Materials Science</subject><subject>Cooling</subject><subject>Fused deposition modeling</subject><subject>High pressure</subject><subject>Hybrid Nanomaterials</subject><subject>Industrial and Production Engineering</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials Science</subject><subject>Mechanical properties</subject><subject>Metastable state</subject><subject>Nanocomposites</subject><subject>Nanofibers</subject><subject>Nanotechnology</subject><subject>Nozzles</subject><subject>Physical properties</subject><subject>Polyethylene</subject><subject>Polyethylenes</subject><subject>Polymer</subject><subject>Processes</subject><subject>Relaxation time</subject><subject>Thin films</subject><subject>Three dimensional printing</subject><issn>2635-1676</issn><issn>1995-0780</issn><issn>2635-1684</issn><issn>1995-0799</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1UEFOwzAQjBBIVKUP4BaJc6gdx05yrAqlSC0tKkjcIsfZNEapXWznkD_waNwWwQFx2tndmVntBME1RrcYk2S8iRmhmKUsJgyhlL6dBYPDKMIsS85_cMoug5G1skQ0IYgxwgbB58Z1VR_qOnQNhOumt1LwNuSqCpcgGq6O7droPRgnwR43zx1vpftRze6WniGVk2p7mM3ltonWBqztjPfUbQ-u6VtQMJ608YqET1zpWpZgjkjo3V5b6cBeBRc1by2MvusweJ3dv0zn0WL18DidLCIRs8xFNS6FoCUDgWnOUZoBKwWtawAGuf-fIMgwF3ElOPeA5CLnlGRVlfl8eMrJMLg5-e6N_ujAuuJdd0b5k0WcpwQnCUupZ-ETSxhtrYG62Bu546YvMCoOuRd_cvea-KSxnqu2YH6d_xd9AdqYhsI</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Kondrashov, S. 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V.</creatorcontrib><creatorcontrib>Gurov, D. A.</creatorcontrib><creatorcontrib>Guseva, M. A.</creatorcontrib><creatorcontrib>Shumskaya, S. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Nanobiotechnology Reports (Online)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kondrashov, S. V.</au><au>Gurov, D. A.</au><au>Guseva, M. A.</au><au>Shumskaya, S. 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2
O
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nanofiber (Nafen) nanocomposite is studied. It is found that the modification of HPP with Nafen fibers, as well as an increase in the temperature of the nozzle of the 3D printer leads to a decrease in warping of the HPP printed on a “cold” workbench. A change in the structure of thin film samples obtained by fused deposition modeling (FDM) printing with a change in the extrusion temperature and the modification of HPP with Nafen nanofibers is proven. An increase in the nozzle temperature and modification of the polymer matrix leads to an increase in the relaxation time of the material structure, which under conditions of rapid cooling contributes to the implementation of a metastable state characterized by a lower density of the fluctuation network in the amorphous part of the HPP. The relationship between the change in the free volume determining the shrinkage of the material during the FDM process, and the change in the melt cooling viscosity and its relaxation time is shown.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S263516762360075X</doi></addata></record> |
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subjects | 3-D printers Aluminum oxide Bioorganic Chemistry and Materials Science Cooling Fused deposition modeling High pressure Hybrid Nanomaterials Industrial and Production Engineering Machines Manufacturing Materials Science Mechanical properties Metastable state Nanocomposites Nanofibers Nanotechnology Nozzles Physical properties Polyethylene Polyethylenes Polymer Processes Relaxation time Thin films Three dimensional printing |
title | Study of the Physical and Mechanical Properties and Quality of the FDM Printing of High-Pressure Polyethylene/Al2O3 Nanofiber Nanocomposites |
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