Union is strength: π-π stacking interactions are capable of preventing solid-state racemization of tris-chelate complexes

The first reliable observation of desolvation- and temperature-induced solid-phase racemization of the entire tris-chelates complex is reported. The capability of π-π stacking interactions to prevent such processes was revealed for the first time. The first reliable observation of the solid-phase ra...

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Veröffentlicht in:	CrystEngComm 2024-03, Vol.26 (12), p.1677-1682
Hauptverfasser:	Gavrikov, Andrey V, Ilyukhin, Andrey B
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelates Racemization Solid phases
Online-Zugang:	Volltext
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