Boosted solar-driven photocatalysis: silver molybdate/reduced graphene oxide nanocomposites for methylene blue decomposition

In this work, reduced graphene oxide coupled silver molybdate binary nanocomposites (Ag 2 MoO 4 /rGO nanocomposites) have been prepared via ethanolic dispersion method. The crystalline character and surface properties of the developed Ag 2 MoO 4 /rGO nanocomposites were proved by X-ray diffractional...

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Veröffentlicht in:Ionics 2024-03, Vol.30 (3), p.1603-1614
Hauptverfasser: Malathi, A., Priyadharsan, Arumugam, Handayani, Murni, Hasan, Imran, Divya, G., Sivaranjani, K., Sivakumar, S.
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container_end_page 1614
container_issue 3
container_start_page 1603
container_title Ionics
container_volume 30
creator Malathi, A.
Priyadharsan, Arumugam
Handayani, Murni
Hasan, Imran
Divya, G.
Sivaranjani, K.
Sivakumar, S.
description In this work, reduced graphene oxide coupled silver molybdate binary nanocomposites (Ag 2 MoO 4 /rGO nanocomposites) have been prepared via ethanolic dispersion method. The crystalline character and surface properties of the developed Ag 2 MoO 4 /rGO nanocomposites were proved by X-ray diffractional (XRD), scanning electronic microscopic (SEM), and transition emission microscopic (TEM) techniques. Photocatalytic activity was tested by analyzing the degradation of methylene blue dye solution which shows excellent degradation ability. Ultraviolet diffused reflectance spectral analysis (UV-DRS) and photoluminescence analysis (PL) clearly shows the synergetic photocatalytic effect of Ag 2 MoO 4 /rGO nanocomposites. The photocatalytic activity of Ag 2 MoO 4 /rGO binary nanocomposites was compared with bare rGO and Ag 2 MoO 4 in the same experimental conditions. Moreover, the effect of mass ratios of rGO in the Ag 2 MoO 4 /rGO binary nanocomposites on the photocatalytic activity was explored comparatively due to its advanced charge carrier separation and ease of adoption with photocatalysts. The optical properties and experimental results proposed a plausible photocatalytic mechanism for the Ag 2 MoO 4 /rGO binary nanocomposites. The synthetic route is independent of expensive treatments like surfactant-based artificial techniques and post-annealing therapy. Hence, Ag 2 MoO 4 /rGO binary nanocomposites may be applicable for dye effluent treatment.
doi_str_mv 10.1007/s11581-023-05346-8
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subjects Catalytic activity
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Current carriers
Degradation
Dyes
Electrochemistry
Emission analysis
Energy Storage
Graphene
Mass ratios
Methylene blue
Nanocomposites
Optical and Electronic Materials
Optical properties
Photocatalysis
Photoluminescence
Renewable and Green Energy
Spectrum analysis
Surface properties
Ultraviolet reflection
title Boosted solar-driven photocatalysis: silver molybdate/reduced graphene oxide nanocomposites for methylene blue decomposition
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